［原著論文］
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(29) M. Laird, A. van der Lee, D. Dumitrescu, C. Carcel,
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(30) Y. Du, M. Unno, H. Liu, Hybrid Nanoporous Materials
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(32) N. Prigyai, S. Chanmungkalakul, V. Ervithayasuporn, N.
Yodsin, S. Jungsuttiwong, N. Takeda, M. Unno, J. Boonmak, S. Kiatkamjornwong, Lithium-Templated
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(33) R. Kunthom, T. Adachi, Y. Liu, N. Takeda, M. Unno,
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(35) Y. Liu, N. Takeda, A. Ouali, M. Unno, Synthesis,
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Substituted Difluorosilane, Organometallics, 38, 743-747
(2019). IF = 3.80 https://doi.org/10.1021/acs.organomet.8b00896
(37) S. Kondo, Y. Nakadai, M. Unno, Recognition of
dicarboxylates in aqueous acetonitrile by a dinuclear zinc(II)
complex of 2,2'-binaphthalene-based receptor, Supramolecular
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(38) T. Uchida, Y. Egawa, T. Adachi, N. Oguri, M.
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Structures, and Thermal Properties of Symmetric and Janus
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(39) H. Endo, N. Taked M. Unno, Single-step synthesis of
disiloxanetetraols, J.
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(40) C. Weetman, N. Ito, M. Unno, F. Hanusch, S. Inoue,
NHI- and NHC-Supported Al(III)
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(41) Y. Egawa, C. Fukumoto, K. Mikami, N. Takeda, M.
Unno, Synthesis and Characterizations of
The Germathioacid chloride Coordinated by an N-Heterocyclic
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(42) H. Endo, N. Takeda, M. Unno, Stereoisomerization of Cyclic Silanols, Chem. Asian J., 12,
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(43) N. Oguri, Y. Egawa, Y. Kawakami, C. Kobuna, N.
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(2017). IF = 2.00 https://doi.org/10.1002/slct.201700306
(44) Y. Egawa, S. Murakami, N. Takeda, and M. Unno,
Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New
Building Block for Materials, Chem.
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738–739 (2016). IF = 1.36 https://doi.org/10.1246/cl.160272
(45) N. Oguri, Y. Egawa, N. Takeda, and M. Unno,
Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure
Elucidation, Angew.
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(46) N. Takeda, Y. Tanaka, R. Oma, F. Sakakibara, M.
Unno, Activation of C–S Bond by Group 10 Metal Complexes:
Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl
Groups with Group 10 Metal Compounds, Bull. Chem. Soc.
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(47) S. Murakami, Y. Egawa, C. Kuramochi, N. Takeda, and
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野雅史, イ
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トワークポリマー 37,
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(49) K. Kakiage, T. Abe,
M. Yamamura, T. Kyomen, M. Unno, and
M. Hanaya, Effect of the introduction of a CF3 group to a
silyl-anchor azobenzene dye on sensitization property in
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(50) N. Oguri, N. Takeda, and M. Unno, Facile Synthesis
of Cyclic Fluorosiloxanes, Chem.
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(51) H. Endo, and N. Takeda, M. Takanashi, T. Imai, and
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(52) M. Unno, H. Endo, and N. Takeda, Synthesis and
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(53) N. Takeda, T. Tagawa, and M. Unno, Synthesis,
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(54) K. Kakiage, Y. Aoyama, T. Yano, T. Otsuka, T.
Kyomen, M. Unno, and M. Hanaya, An achievement of over 12
percent efficiency in an organic dye-sensitized solar cell, Chem. Commun., 50,
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(55) H. Endo, N. Takeda, and M. Unno, Synthesis
and Properties of Phenylsilsesquioxanes with Ladder and
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(56) R. Yanagisawa, H. Endo, M. Unno, H. Morimoto,
S. Tobishima, Effects of organic silicon compounds as
additives on charge-discharge cycling efficiencies of lithium
in nonaqueous electrolytes for rechargeable lithium cells, J. Power
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(57) S. Kondo, Y. Nakadai, and M. Unno, Pyrophosphate
selective recognition by a Zn2+ complex of a
2,20-binaphthalene derivative bearing
di(2-pyridylmethyl)aminomethyl groups in aqueous solution, RSC Adv., 4,
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(58) K. Kakiage, Y. Aoyama, M. Yamamura, T. Yano, M.
Unno, T. Kyomen, and M. Hanaya, A Novel Alkoxysilyl Azobenzene
Dye Photosensitizer with Alkylamino Group for Dye-Sensitized
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(2014). https://doi.org/10.1007/s12633-013-9174-y
(59) M. Yamamura, S. Kondo, and M. Unno, Ion Pair
Recognition of Ditopic Receptor Bearing Silanol Groups as Anion
Recognition Sites and a 2,2'-Bipyridine Moiety as a
Metal-coordination Site, Tetrahedron
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(60) S. Kondo, N. Watanabe, F. Takahashi, N. Takeda, and
M. Unno, Synthesis
and photophysical properties of 2,2’-binaphthalene-based
receptor bearing trimethylsilyl groups to improve the
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(61) H. Endo and M. Unno, Effective Synthesis and
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(62) K. Kakiage, C. Saito, M. Yamamura, T. Kyomen, M.
Unno, and M. Hanaya, Study of the Chemical Adsorption Property
of Allylsilylazobenzene in the Surface Modification of
Nano-Porous Alumina Membrane, Key
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(63) M. Unno, T. Matsumoto, H. Matsumoto, Nonacyclic
Ladder Silsesquioxanes and Spectral Features of Ladder
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(64) K. Kakiage, M. Yamamura, T. Kyomen, M. Unno, and M.
Hanaya, Adsorption and Sensitizing Properties of Azobenzenes
Having Different Numbers of Silyl-anchor Groups in
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(65) K. Kakiage, T. Tsukahara, T. Kyomen, M. Unno, and
M. Hanaya, Significant Improvement of Photovoltaic Performance
of Dye-sensitized Solar Cells by Using 4-Trimethylsilylpyridine
as Organic Additive to Electrolyte Solution, Chem. Lett., 41, 895-896
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(66) (Selected Paper) S. Kondo, S. Nakajima, and M.
Unno, Ratiometric Fluorescence Detection of Anions by an
Amide-Based Receptor Bearing Pyrenyl Groups, Bull. Chem. Soc.
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(67) S. Kondo, H. Sonoda, T. Katsu, and M. Unno, Improvement of solubility
of 2,2′-binaphthalene derivatives
bearing urea groups as anion receptors and their application to
a chloride selective electrode, Sensors and
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(68) V.
Ervithayasuporn, T. Tomeechai, N. Takeda, M. Unno, A.
Chaiyanurakkul, R. Hamkool, and T. Osotchan, Synthesis and
Characterization of Octakis(3-propyl
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4475–4478 (2011). https://doi.org/10.1021/om200477a
(69) M. Unno, N. Yamashita, and H. Matsumoto, Thermal
Reaction of Octasilacubane with Sulfur, Selenium, and Tellurium:
Formation of Novel Cage Systems, Phosphorus,
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(70) Y. Egawa and M. Unno,
Solvent-free Synthesis of Functional Siloxanes Bearing
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(71) K. Kakiage, M. Yamamura, E. Ido, T. Kyomen, M.
Unno, and M. Hanaya, Reactivity of Alkoxysilyl Compounds:
Chemical Surface Modification of Nano-porous Alumina Membrane
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(72) S. Kondo, T. Takahashi, Y. Takiguchi, and M. Unno,
Synthesis and photophysical properties of a
2,2’-bianthracene-based receptor bearing two aza-15-crown-5
ethers for naked-eye detection of barium ion, Tetrahedron
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(73) S. Kondo, M. Nagamine, S. Karasawa, M. Ishihara, M.
Unno, and Y. Yano, Anion recognition by 2,2’-binaphthalene
derivatives bearing urea and thiourea groups at 8- and
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(2011). https://doi.org/10.1016/j.tet.2010.12.004
(74) N. Takeda, T. Nakamura, A. Imamura, and M. Unno,
Synthesis and reactivities of dihydrosilanes tethered with two
thioether moieties, Heteroatom
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(75) M. Unno, R. Tanaka, D. Obinata, M. Endo, T.
Sakurai, S. Ojima, T. Katayama, K. Fugami, Solvent-free
synthesis of siloxanes and their usage as potential
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(76) R. Tanaka, S. Kowase, and M. Unno,
Chiral Cyclotrisiloxanes, Dalton
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(77) N. Takeda, D. Watanabe, T. Nakamura, and M. Unno,
Synthesis and Complexation of New Tripodal Tetradentate Ligand,
Silyl Ligand Tethered with Three Thioether Moieties, Organometallics, 29,
2839-2841 (2010). https://doi.org/10.1021/om100255p
(78) S. Kondo, Y. Kobayashi, and M. Unno, Anion
Recognition by D-Ribose-based Receptors, Tetrahedron
Lett., 51,
2512–2514 (2010). https://doi.org/10.1016/j.tetlet.2010.03.001
(79) M. Unno, R. Tanaka, D. Obinata, M. Endo, T.
Sakurai, S. Ojima, T. Katayama, and K. Fugami, Solvent-free
Synthesis of Siloxanes and Their Usage as Potential
Cross-Coupling Reagents, Key.
Eng. Mater., 459,
43–47 (2010). https://doi.org/10.4028/www.scientific.net/KEM.459.43
(80) N. Takeda, Y. Tanaka, F. Sakakibara, and M. Unno, Synthesis and
Structure of Group 10 Metal Complexes with New Tripodal
Tetradentate Ligand Bearing One Phosphine and Three Thioether
Moieties, Bull.
Chem. Soc. Jpn., 83,
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(81) K. Kakiage, M. Yamamura, E. Fujimura, T. Kyomen, M.
Unno and M. Hanaya, High
Performance of Si–O–Ti Bonds
for Anchoring Sensitizing Dyes on TiO2 Electrodes in
Dye-sensitized Solar Cells Evidenced by Using
Alkoxysilylazobenzenes, Chem.
Lett., 39, 260–262
(2010). https://doi.org/10.1246/cl.2010.260
(82) K. Kakiage, T. Kyomen, M. Unno, and M. Hanaya,
Molecular-selective Adsorption Property of Chemically Surface
Modified Nanoporous Alumina Membrane by Di(1-naphthyl)silanediol
to Anthracenes, Appl.
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(83) S. Chang, T. Matsumoto, H. Matsumoto, and M. Unno,
Synthesis and Characterization of Heptacyclic Laddersiloxanes
and Ladder Polysilsesquioxane, Appl. Organomet.
Chem., 24,
241–246 (2010). https://doi.org/10.1002/aoc.1607
(84) M. Unno, K. Kakiage, M. Yamamura, T. Kogure, T.
Kyomen, and M. Hanaya, Silanol Dyes for Solar Cells: Higher
Efficiency and Significant Durability, Appl. Organomet.
Chem., 24,
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(85) K. Kakiage, T. Kyomen, M. Unno, and M. Hanaya, The
Chemical Adsorption Properties of Silanol to Metal-Oxide Surface
Studied by Using Di(1-naphthyl)silanediol and Nano-porous
Alumina Membranes, Silicon, 1, 191–197
(2009). https://doi.org/10.1007/s12633-009-9027-x
(86) S. Kondo, N. Okada, R. Tanaka, M. Yamamura, and M.
Unno, Anion Recognition by 1,3-Disiloxane-1,1,3,3-tetraols
in Organic Solvents, Tetrahedron
Lett., 50,
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(87) H. Liu, S. Kondo, N. Takeda, and M. Unno, An Efficient Approach to Monophenyl-Functionalized
Octasilsesquioxanes, Eur. J.
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(88) H. Liu, S. Kondo, N. Takeda, and M. Unno, Synthesis
of Octacarboxy Spherosilicate, J. Am. Chem. Soc., 130,
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(89) K. Kakiage, Y. Nakada, T. Kogure, M. Yamamura, T.
Kyomen, M. Unno, and M. Hanaya, Applicability of Silanol to
Sensitizing Dye for Dye-sensitized Solar Cell, Silicon Chem., 3,
303–305 (2008). https://doi.org/10.1007/s11201-008-9032-8
(90) H. Liu, S. Kondo, R. Tanaka, H. Oku, and M. Unno, A
spectroscopic investigation of incompletely condensed polyhedral
oligomeric silsesquioxanes (POSS-mono-ol, POSS-diol and
POSS-triol): Hydrogen-bonded interaction and host–guest complex, J. Organomet.
Chem., 693 1301–1308 (2008). https://doi.org/10.1016/j.jorganchem.2008.01.027
(91) 金澤貴之，味澤俊介，海野雅史，上田浩，"遠隔通信技術を
活用した聴覚障害学生支援―キャンパス間連携入力方式の導入事例から―"，メディ
ア教育研究 (Journal of
Multimedia Aided Education Research), 5, 55-61
(2008). http://www.code.ouj.ac.jp/media/pdf5-2-10/No.10-07tokusyuu06.pdf
(92) S. Kondo, A. Fukuda, T. Yamamura, R. Tanaka, and M.
Unno, Anion Recognition by a Disiloxane-1,3-diol in Organic
Solvents, Tetrahedron.
Lett., 48,
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(93) S. Kondo, T. Hayashi, Y. Sakuno, Y. Takezawa, T. Yokoyama, M. Unno, and Y.
Yano, Synthesis of cyclic bis- and Trismelamine Derivatives and
Their Complexation properties with Barbiturates, Org. Biomol.
Chem., 5,
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(94) M. Endo, T. Sakurai, S. Ojima, T. Katayama, M.
Unno, H. Matsumoto, S. Kowase, H. Sano, M. Kosugi, and K.
Fugami, Novel Pd-Catalyzed Atom-Efficient Cross-Coupling
Reaction by Means of Hexaarylcyclotrisiloxane, SynLett, 5, 749-752
(2007). https://doi.org/10.1055/s-2007-970773
(95) M. Unno, T. Matsumoto, and H. Matsumoto, Synthesis
of Laddersiloxanes by Novel Stereocontrolled Approach, J. Organomet.
Chem., 692,
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(96) S. Kondo, T. Harada, R. Tanaka, and M. Unno, Anion
Recognition by a Silanediol-Based Receptor, Org. Lett., 8, 4621–4624
(2006). https://doi.org/10.1021/ol061822p
(97) M. Unno, H. Murakami, S. Kagawa and H. Matsumoto, Borderline of Hydrogen Bonding by Silanols, Silicon Chem., 3,
195–198 (2005). https://doi.org/10.1007/s11201-006-9021-8
(98) M. Hirotsu, S. Taruno, T. Yoshimura, K. Ueno, M.
Unno, and H. Matsumoto, Synthesis and Structures of the First
Titanium(IV) Complexes with Cyclic Tetrasiloxide Ligands:
Incomplete and Complete Cage Titanosiloxanes, Chem. Lett., 34,
1542–1543 (2005). https://doi.org/10.1246/cl.2005.1542
(99) M. Unno, S. Chang, and H. Matsumoto, cis-trans-cis-Tetrabromotetramethylcyclotetrasiloxane:
a Versatile Precursor of Ladder Silsesquioxanes, Bull. Chem. Soc.
Jpn., 78,
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(100) M. Unno, R. Tanaka, S. Tanaka, T. Takeuchi, S.
Kyushin, and H. Matsumoto, Oligocyclic Laddersiloxanes:
Alternative Synthesis by Oxidation, Organometallics, 24, 765–768
(2005). https://doi.org/10.1021/om049324c
(101) M. Unno, Y. Kawaguchi, Y. Kishimoto, and H.
Matsumoto, Stereoisomers of
1,3,5,7-Tetrahydroxy-1,3,5,7-tetaisopropylcyclotetrasiloxane:
Synthesis and Structures in the Crystal, J. Am. Chem.
Soc., 127,
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(102) T. Okutsu, K. Isomura, N. Kakinuma, H. Horiuchi, M.
Unno, H. Matsumoto, and H. Hiratsuka, Laser-induced morphology
control and liquid phase epitaxy of dipara-anthracene produced
from photochemical reaction of anthracene, Cryst. Growth Des., 5, 461–465
(2005). https://doi.org/10.1021/cg049816s
(103) M. Unno, Y. Kishimoto, and H. Matsumoto,
Triisopropylcyclotrisiloxanetriol: An Unprecedented Cyclic
Siloxanetriol with Relatively Small Substituents, Organometallics, 23,
6221–6224 (2004). https://doi.org/10.1021/om0494972
(104) K. Negishi, M. Unno, and H. Matsumoto, The
Cyclo[(disilanylene)(butadiyne)]s [(i-Pr)2Si(i-Pr)2SiCºCCºC]n (n = 2–4), Chem. Lett., 33, 430–431
(2004). https://doi.org/10.1246/cl.2004.430
(105) M. Unno, Y. Imai, and H. Matsumoto, Hexakis(2,4,6-triisopropylphenylsilsesquioxane), Silicon Chem., 2, 175–178
(2003). https://doi.org/10.1023/B:SILC.0000046726.90699.41
(106) M. Unno, T. Tanaka, and H. Matsumoto,
Tip-substituted Cage and Cyclic Silanols, J. Organomet.
Chem., 686,
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(107) M. Unno, T. Matsumoto, K. Mochizuki, K. Higuchi, M.
Goto, and H. Matsumoto, Structure and Oxidation of Octakis(tert-butyldimethylsilyl)octasilacubane, J. Organomet.
Chem., 685,
156–161 (2003). https://doi.org/10.1016/S0022-328X(03)00288-2
(108) M. Unno, H.
Masuda, and H. Matsumoto, Photo-initiated Bromination of
Octakis(1,1,2-trimethylpropyl)octasilacubane with
Tetrabromomethane, Silicon
Chem., 1,
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(109) K. Yamada, M. Unno, K. Kobayashi, H. Oku, H.
Yamamura, S. Araki, H. Matsumoto, R. Katakai, and M. Kawai,
Stereochemistry of Protected Ornithine Side Chains of Gramicidin
S Derivatives: X-ray Crystal Structure of the Bis-Boc-tetra-N-methyl
Derivatives of Gramicidin S, J.
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(110) R. Tanaka, S. Kyushin, M. Unno, and H. Matsumoto,
Chiral crystallization of anti-dodecaisopropyltricyclo[4.2.0.02,5]octasilane, Enantiomer, 7, 157–159
(2002). https://doi.org/10.1080/10242430212882
(111) M. Unno, A. Suto, and H. Matsumoto, Pentacyclic
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(112) M. Unno, Y. Kawai, and H. Matsumoto, Synthesis and
Crystal Structures of 2,4,6-Tri-tert-butylphenyltrichlorogermane
and 2,4,6-Tri-tert-butylphenylgermane, Heteroatom Chem., 12, 238–243
(2001). https://doi.org/10.1002/hc.1038
(113) M. Unno, T. Saito, and H. Matsumoto, Synthesis and
Crystal Structures of Silapericyclynes, Bull.
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(114) M. Unno, K. Negishi, and H. Matsumoto, Extended
Silapericyclynes, Chem.
Lett., 30,
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(115) M. Unno, K. Higuchi, K. Furuya, H. Shioyama, S.
Kyushin, M. Goto, and H. Matsumoto, Synthesis, Structure, and Reactions of
Octakis(1,1,2-trimethylpropyl)octagermacubane, Bull. Chem. Soc. Jpn., 73,
2093–2097(2000). https://doi.org/10.1246/bcsj.73.2093
(116) S. Kyushin, A. Meguro, M.
Unno, and H. Matsumoto, Photolysis of anti-Dodecaalkyltricyclo[4.2.0.02,5]octasilane:
Generation and Reactions of Cyclotetrasilene, Chem. Lett., 29,
494–495 (2000).https://doi.org/10.1246/cl.2000.494
(117) H. Horiuchi, Y. Nakano, T.
Matsumoto, M. Unno, H. Matsumoto, and H. Hiratsuka, Electronic
Structure and Photochemical Reaction Intermediates of
Octakis(1,1,2-trimethylpropyl)octasilacubane, Chem. Phys.
Lett., 322, 33–40 (2000). https://doi.org/10.1016/S0009-2614(00)00357-2
(118) M. Unno, K. Takada, and H.
Matsumoto, Formation of Supramolecule by Assembling of Two
Different Silanols, Chem.
Lett., 29,
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(119) M. Unno, A. Suto, K. Takada,
and H. Matsumoto, Synthesis
of Ladder and Cage Silsesquioxanes from
1,2,3,4-Tetrahydroxycyclotetrasiloxane, Bull. Chem. Soc.
Jpn., 73,
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(120) M. Unno, D. Ishii, and H. Matsumoto, Kinetic
Study of Thermal Isomerization of the “Double-decker”-type
Sesquichalcogenides, (Thex2M2E2)2E2 (M=Si, Ge;
E=S, Se), Bull.
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(121) M. Unno, T. Saito, and H. Matsumoto,
Silapericyclyne, (Ph2SiCºC)6:
Spontaneous Conformational Resolution of Boat- and
Chair-'Exploded' Cyclohexane, Chem. Lett., 28,
1235–1236 (1999). https://doi.org/10.1246/cl.1999.1235
(122) R. Tanaka, M. Unno, and H. Matsumoto, Synthesis and
Molecular Structures of Novel Isopropyl-substituted
Oligosilanes, Chem.
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(123) M. Unno, R. Tanaka, S. Kyushin, and H. Matsumoto, Synthesis and Reactions of Hepta-t-butylcyclotetragermane, Phosphorus,
Sulfur, Silicon Relat. Elem., 150/151,
167–176 (1999). https://doi.org/10.1080/10426509908546382
(124) M. Unno, B. A. Shamsul, M. Arai, K. Takada, R.
Tanaka and H. Matsumoto, Synthesis and Characterization of Cage
and Bicyclic Silsesquioxanes via Dehydration of Silanols, Appl. Organomet.
Chem., 13,
303-310 (1999). https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291099-0739%28199904%2913%3A4%3C303%3A%3AAID-AOC846%3E3.0.CO%3B2-%23
(125) M. Unno, K. Takada, and H. Matsumoto, Synthesis,
Structure, and Reaction of the Tetrahydroxycyclotetrasiloxane [(i-Pr)(OH)SiO]4, Chem. Lett., 27, 489–490
(1998). https://doi.org/10.1246/cl.1998.489
(126) M. Unno, H. Masuda, and H. Matsumoto,
1,2,3-Triphenyl-1,2,3-trithexylcyclotrisilanes: Synthesis and
Ring-Opening by Halogens, Bull.
Chem. Soc. Jpn, 70,
2449–2458 (1997). https://doi.org/10.1246/bcsj.71.2449
(127) M. Unno, R. Tanaka, T. Kuribara, M. Saito, and H.
Matsumoto, Synthesis, Structures, and Reactions of
1,2,3-Tris(diethylamino)-1,2,3,4-tetrakis-(1,1,2-trimethylpropyl)cyclotetrasilanes, Bull. Chem. Soc.
Jpn, 70,
2749–2756 (1997). https://doi.org/10.1246/bcsj.70.2749
(128) K. Kobayashi, T. Kato, M. Unno, and S. Masuda,
Asymmetric Synthesis of Organosilicon Compounds Using a C2 Chiral Auxiliary, Bull. Chem. Soc.
Jpn, 70,
1393–1401 (1997). https://doi.org/10.1246/bcsj.70.1393
(129) M. Unno, Y. Kawai, H. Shioyama, and H. Matsumoto,
Syntheses, Structures, and Properties of Tricyclo[5.1.1.13,5]tetrasilachalcogenanes
(Thex2Si2E2)2E2 (E = S, Se) and
Tricyclo[5.1.1.13,5]tetragermachalcogenanes (Thex2Ge2E2)2E2 (E = S, Se), Organometallics, 16,
4428–4434 (1997). https://doi.org/10.1021/om970432r
(130) M. Unno, H. Shioyama, and H. Matsumoto, Synthesis
and Structures of Tetrasilsesquisulfides, Phosphorus,
Sulfur, Silicon Relat. Elem., 120/121,
377–378 (1997). https://doi.org/10.1080/10426509708545556
(131) M. Unno, T. Yokota, and H. Matsumoto,
Oxaoctasilahomocubane and Dioxaoctasilabishomocubane: Novel
Silicon Ring System, J.
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(132) M. Unno, B. A. Shamsul, H. Saito, and H. Matsumoto,
Synthesis of Hexasilsesquioxanes Bearing Bulky Substituents:
Hexakis(1,1,2-trimethylpropylsilsesquioxane) and Hexakis(tert-butylsilsesquioxane), Organometallics, 15,
2413–2414 (1996). https://doi.org/10.1021/om950737a
(133) M. Unno, H. Shioyama, M. Ida, and H. Matsumoto,
Reductive dehalogenation of
4,8-Dihalooctakis(1,1,2-trimethylpropyl)tetracyclo-[3.3.0.02,7.03,6]octasilanes
with Sodium, Organometallics, 14,
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(134) M. Unno, M. Saito, and H. Matsumoto, Synthesis,
Structure, and Properties of Novel Aminodisilanes Bearing Bulky
Substituents:
1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane
and 1,2-di-(tert-butyl)1,1,2,2-tetrakis(diethylamino)disilane, J. Organomet.
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(135) M. Unno, K. Higuchi, M. Ida, H. Shioyama, S.
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Octakis(1,1,2-trimethylpropyl)octasilacubane, Organometallics, 13,
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(136) B. Imperiali, K. L. Shannon, M. Unno, and K. W.
Rickert, A Mechanistic Proposal for Asparagine-Linked
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(137) L. T. Scott and M. Unno, Novel Heterocycles
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(138) R. Okazaki, M. Unno, and N. Inamoto, Estimation of
Bulkiness of a Highly Sterically Demanding
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(1989). https://doi.org/10.1246/cl.1989.791
(139) R. Okazaki, M. Unno, G. Yamamoto, and N. Inamoto, A
Conformational Study on Highly Crowded
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(140) R. Okazaki, M. Unno, and N. Inamoto,
2,4,6-Tris[bis(Trimethylsilyl)methyl]phenyl, a New Sterically
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(141) R. Okazaki, M. Unno, and N. Inamoto, A New Synthesis of 1,3-Thiazine Derivatives Bearing a Dithiolane Ring and Their Reductive Cleavage with Sodium Cyanoborohydride, Heterocycles, 25, 183–190
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[Review, Proceedings]
(1) 刘雨佳, 海野雅史, ヤヌス型シロキサン開発物語, 有機合成化学協会誌, 80, 12,
1126–1135 (2022).
https://doi.org/10.5059/yukigoseikyokaishi.80.1126
(2) 海野雅史, 刘雨佳, シランカップリング剤の歴史, New
Glass, 37, 2, 7–10
(2022).
(3) 海野雅史, シランカプリング剤の基礎とメカニズム, 塗装工学, 57, 4, 138–145
(2022).
(4) 海野雅史, ヤヌスキューブ（ヤヌス分子）の合成と応用展開，ファインケミカル, 48, 3, 38–48
(2019). https://www.cmcbooks.co.jp/products/detail.php?product_id=5607
(5) 海野雅史，シランカップリング剤のメカニズムと将来展開，色材協会誌，88，5，143–147 (2015). https://doi.org/10.4011/shikizai.88.143
(6) M. Unno, A. Suto, and T. Matsumoto,
"Laddersiloxanes— Silsesquioxanes with defined ladder
structure", Russ.
Chem. Rev., 82,
289–302 (2013). https://doi.org/10.1070/RC2013v082n04ABEH004360
(7) 海野雅史, 超分子から構造規制次世代材料まで—シラノールが築く新しい化学—, 有機合成化学協会誌, 69, 413–425
(2011). https://doi.org/10.5059/yukigoseikyokaishi.69.413
(8) 海野雅史,近未来材料のシルセスキオキサン, 化学, 65, 10, 68–69
(2010). https://www.kagakudojin.co.jp/book/b73488.html
(9) 海野雅史, ケイ素化合物の優れた結合能を利用した表面処理ならびに増感色素への応用, ファインケミカル, 39, 3, 5–12
(2010). https://www.cmcbooks.co.jp/products/detail.php?product_id=3528
(10) 海野雅史, 花屋実, ケイ素を利用した新規色素増感太陽電池の設計, ケミカルエンジニヤリング, 53, 9, 687–693
(2008). http://www.kako-sha.co.jp/2008contentschem.htm
(11) M. Unno, Laddersiloxanes: silsesquioxanes with
defined ladder structure. Materials Research Society Symposium
Proceedings 1007-S01-05 (2007),. https://doi.org/10.1557/PROC-1007-S01-05
(12) 海野雅史, シラノールの水素結合を利用したナノサイズ超分子の形成, ナノ学会会報, 5, 47–51
(2007). http://www.ac-square.co.jp/nano/journal_01.html
(13) M. Unno, K. Takada, Y. Kawaguchi, and H. Matsumoto, Supramolecular aggregates of silanols and
solid-state synthesis of siloxanes, Mol. Cryst. Liq. Cryst., 440,
259–264 (2005). https://doi.org/10.1080/15421400590958584
(14) 海野雅史, 松本英之, オクタシラキュバンの化学, 有機合成化学協会誌, 62, 107–115
(2004). https://doi.org/10.5059/yukigoseikyokaishi.62.107
(15) K. Yamada, M. Unno, K. Kobayashi, H. Oku, H.
Yamamura, H. Matsumoto, R. Katakai, and K. Masao,
Stereochemistry of protected ornithine side chains of gramicidin
S derivatives: X-ray crystal structure of N-methylated
derivative of gramicidin, Peptide
Science, 2002, 39th, 305–308 (2003).
(16) 海野雅史, フラーレン化学合成１２年の歩み〜L. T. Scott研究室, ケイ素化学協会誌,
No.16, pp.12-15 (2002).
(17) H. Matsumoto, S. Kyushin, M. Unno, and R. Tanaka,
Synthesis, Structures, and Properties of Ladder Oligosilanes and
Ladder Oligogermanes, J.
Organomet. Chem. 611,
52–63 (2000). https://doi.org/10.1016/S0022-328X(00)00299-0
(18) 海野雅史, 松本英之, ケイ素原子を持つ超分子,科学と工業 (大阪), 74,
489–494 (2000).
(19) 海野雅史, ヘテロ原子化学＋有機金属化学, ケイ素化学協会誌,
No.12, pp.11-14 (2000).
(20) 海野雅史, Tbt基が生まれた頃−When Tbt
was born, ケイ素化学協会誌,
No.11, pp.45-46 (1999).
(21) 海野雅史, 松本英之, シルセスキオキサン類の化学−かご状化合物を中心に, ケイ素化学協会誌,
No.8, pp.16-22 (1997).
［Books］
(1) 海野雅史, 刘雨佳（分担）, シランカップリング剤の加水分解、縮合反応による表面改質（第２章第１１節）“ぬれ性の制御と表面処理・改質技術, 技術情報協会 (2023). ISBN 978-4-86104-977-4
(2) 海野雅史（分担）, シランカップリング剤
の最新技術動向（第６章第１節）次世代シランカップリング剤,シーエムシー出版，pp.216–223 (2020). ISBN 978-4-7813-1520-1
(3) 海野雅史（分担）, シランカップリング剤
の使い方と応用事例（第９章第１節）シルセスキオキサンの種類・構造，合成方法,サ
イエンス&テクノロジー，pp.313–321
(2020). ISBN 978-4-86428-218-5
(4) 海野雅史（分担）, 添加剤の最適使用法
（第８節 シランカップリング剤の種類，反応，使用方法），R&Dリサー
チセンター，pp.129–135 (2020). ISBN 978-4-905507-42-0
(5) M. Unno and H. Endo, “Silanols as Building Blocks
for Nanomaterials” in Novel Nanoscale Hybrid Materials, Ed.
Bhanu P. S. Chauhan, John Wiley & Sons, Inc., New York, pp.
1–31 (2018). https://doi.org/10.1002/9781119156253.ch1
(6) M. Unno and R. Tanaka, “Silanols and
Silsesquioxanes” in Efficient Methods for Preparing Silicon
Compounds, Ed. H. W. Roesky, Academic Press, London, pp. 399–440
(2016). https://doi.org/10.1016/B978-0-12-803530-6.00032-9
(7) シランカップリング剤の使いこなし
ノウハウ集， 第１章「シランカップリング剤の反応メカニズム」，技術情報協会 (2016). ISBN
978-4-86104-610-0
(8) M. Unno, "Substituted Polyhedral Silicon and
Germanium Clusters", in Functional Molecular Silicon Compounds
II, Ed. D. Scheschkewitz, Springer, Heidelberg, pp.49-84 (2014). https://doi.org/10.1007/430_2013_99
(9) 現代ケイ素化学（分担）,第２２章「シリコーンの応用」,吉良満夫,玉尾皓平編,化学同人 pp.349-360（2013）.
(10) シルセスキオキサン材料の化学と応用展開, 伊藤真樹監修, 第
４章「かご型および精密合成ラダーシルセスキオキサン」, シーエムシー出版 pp. 37-48 (2013).
(11) 最強エレメント ケイ素の不思議(分担) , 海
野雅史編, 海
野雅史他著, 上
毛新聞社,pp.9-11, 19-21 (2011).
(12) シランカップリング剤の反応メカニズムと処理条件の最適化, 第１章「シランカップ
リング剤の基本的メカニズム」, 第５章「シランカップ
リング剤への新規機能性の付与」, 技術情報協会pp.1-20, 88-105 (2010).
(13) シルセスキオキサン材料の最新技術と応用, 伊藤真樹監修, 第
４章「かご型および精密合成ラダーシルセスキオキサン」, シーエムシー出版 (2007).
(14) 新時代への視点 −群馬大学研究室から−(分担)，群馬大学地域連携推進室編，上毛新聞社，pp.
186-188 (2006).
(15) M. Unno and H. Matsumoto, "Reactions of
Octasilacubane", in Organosilicon Chemistry VI，Eds. N. Auner and J.
Weis, WILEY-VCH Verlag, Weinheim, pp. 373–380 (2005). https://doi.org/10.1002/9783527618224.ch2c
(16) １０年使える有機スペクトル解析（分担），新津隆士，海野雅史，鍵裕之著，三共出版，第１章，第２章 (2005).
(17) ２１世紀の有機ケイ素化学—機能性物質科学の宝庫（分
担），玉尾皓平監修，シーエムシー（2004）.
(18) プロフェショナル英和辞典スペッドテラ 物質・工学編（分担），堀内克明、蟹江幸博編，小学館 (2004).
(19) キラキラわくわく化学（分担）上毛新聞社，pp.50-53
(2003).
(20) 有機ケイ素材料科学の新展開 (分担)，櫻井英樹監修，シーエム
シー，pp.146-156 (2001)
(21) 化合物の辞典 (分担), 稲
本直樹ら編, 朝
倉書店 (1998).
(22) 気軽に化学 (分担), 上
毛新聞社，pp.168-169,172-173 (1996).
［Patents］
(1) 特願2016-232998、海野雅史、江川泰暢、島田
茂、佐藤一彦、「反応性置換基を有するシルセスキオキサンの製造方法」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成28年11月30日.
(2) 特願2015-204578、海野雅史、江川泰暢、島田
茂、佐藤一彦、「異なる置換基を対面に4つずつ有するかご型シルセスキオキサ
ン」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成27年10月16日.
(3) 特開2014-093158、神谷正人、齋藤平、寺島純平、鳶島真一、森本英行、海野雅史、「リチウムイオン二
次電池」、トヨタ自動車株式会社、国立大学法人群馬大学、平成26年5月19日.
(4) 特開2014-053097、神谷正人、齋
藤平、鳶島真一、森本英行、海野雅史、「リチウム二次電池およびその製造方法」、国立大学法人群馬大学、トヨタ自動車
株式会社、平成26年3月20日.
(5) 特願2014-76446、海野雅史、佐藤一彦、島田茂、
五十嵐正安、「シロキサン化合物の製造方法」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成26年4月2日.
(6) 特開2013-241497、小熊武美、渡辺淳、海野雅
史、「ポリシルセスキオキサン化合物、光素子封止材及びその用途」、国立大学法人群馬大学、電気化学工業株式会社、平成25年12月5日.
(7) WO 2012137568, M. Hanaya, K. Kakiage,
M. Unno, Y. Aoyama, T. Yano, D. Sawamoto, H. Osada, “Aromatic
amines bearing hydrocarbyloxysilyl groups, supports containing
supported them, and photoelectric converters”, Adeka
Corporation, Oct. 11, 2012.
(8) WO 2012036010, M. Hanaya, K. Kakiage,
M. Unno, T. Yano, K. Akimoto, K. Sakamaki, “Production
of pyridine derivative additive for electrolytic composition
of dye-sensitized solar cell”, Adeka
Corporation, Sep. 5, 2011.
(9) 特開2011-202057、海野雅史、小熊武美、村田
弘、「ポリシルセスキオキサン化合物、光素子封止材及びその用途」、電化化学工業株式会社、国立大学法人群馬大学，平成22年3月26日．
(10) 特開2009-249455（特願2008-097235）、濱田光祥、永井晃、海野雅史、山村正樹、「封止用エポキシ樹脂
成形材料及び電子部品装置」、日立化成工業株式会社、平成21年10月29日.
(11) 特開2009-249312（特願2008-097236）、濱田光祥、永井晃、加藤木茂樹、杜暁黎、海野雅史、「シラン化
合物」、日立化成工業株式会社、平成21年10月29日.
(12) 特開2007-197723（特願2006-356289）、濱田光祥、永井晃、松本英之、海野雅史、「封止用エポキシ樹脂
成形材料及び電子部品装置」、日立化成工業株式会社、平成19年8月9日.
(13) 特開2008-63390（特願2006-240428）、海野雅史，花屋実，「色素増感太陽電池用色素及びこの色素を用
いた光電変換素子並びに色素増感太陽電池」，国立大学法人群馬大学，平成18年9月5日．
(14) 特開2006-016580（特願2004-198515）、濱田光祥、永井晃、松本英之、海野雅史、「接着剤組成物、それ
を用いたフィルム状接着剤及び回路接続材料、並びに回路部材の接続構造及びその製造方法」、日立化成工業株式会社、平成18年1月19日.
(15) 特開2006-016370（特願2004-198509）、佐藤和也、湯佐正己、小林隆伸、藤縄貢、塚越功、松本英之、海
野雅史、「シラン化合物」、日立化成工業株式会社、平成18年1月19日.
(16) 特開2006-016369（特願2004-198508）、佐藤和也、湯佐正己、小林隆伸、藤縄貢、塚越功、松本英之、海
野雅史、「シラン化合物の製造方法及びシラン化合物」、日立化成工業株式会社、平成18年1月19日.
(17) 特開2004-315428（特願2003-111608）、松本英之、海野雅史、田中陵二、「ハロゲン化アリール置換環状
テトラシロキサンの製法」、独立行政法人 科学技術振興機構、2004年11月11日.
新聞発表等
1) 新物質「ヤヌスキューブ」群馬大大学院が新合成法, 日本経済新聞, 2016/05/28.
2) 群馬大が新合成法 新物質「ヤヌスキューブ」, 日本経済新聞, 電
子版, 2016/05/28.
3) エコタイヤの性能向上 化合物の合成法開発, 産
経新聞, 2016/05/28.
4) エコタイヤの性能向上に期待 群大院が「ヤヌスキューブ」合成, 産経新聞電子版, 2016/05/28.
5) エコタイヤの性能向上に期待 群大院が「ヤヌスキューブ」合成法開発,
Yahooニュース, 2016/05/28.
6) ヤヌスキューブ簡便合成法 産総研群馬大 有機ケイ素部材に有用, 化学工業日報, 2016/05/30.
7) ヤヌスキューブの簡易合成法を発見 エコタイヤ性能向上期待, 上
毛新聞, 2016/05/30.
8) ヤヌスキューブ効率的に合成 群馬大と産総研, 日刊工業新聞, 2016/06/02.
9) ヤヌスキューブ 簡便な合成法開発 詳細な分子構造も解明, 桐生タイムス, 2016/06/02.
10) 「究極のエコタイヤ」へ新手法 ヤヌスキューブ材料の化合物合成効率化, 読売新聞, 2016/06/03
11) ヤヌスの立方体, 有機化学美術館・分館, 2016/06/06.
12) カゴ型シルセスキオキサン「ヤヌスキューブ」合成と構造決定,
Chem-Stationスポットライトサーチ, 2016/06/10.
13) ヤヌスキューブ合成 科
学新聞社電子版, 2016/06/17.