［原著論文］

1.     Y. Liu, N. Yagafarov, K. Shimamura, N. Takeda, M. Unno, A. Ouali, Synthesis of an Azido-Substituted 8-Membered Ring Laddersiloxane and Its Application in Catalysis, Molecules, 30, 373 (2025). 

 

2.     N. Yagafarov, J. Kuang, N. Takeda, Y. Liu, A. Ouali, M. Unno, Synthesis and Thermal Properties of Bio-Based Janus Ring Siloxanes Incorporating Terpenes and Terpenoids, Materials, 17, 5348 (2024). doi: 10.3390/ma17215348 

3.     A. Tuanchai, S. Timjan, N. Tuancharoensri, P. Phimnuan, W. Chartarrayawadee, P. Worajittiphon, Y. Liu, G. M. Ross, C. Viennet, J. Viyoch, H.‐T. Chang, M. Unno, S. Ross, Hybrid nanomaterials of carbon dots of silk sericin and folic acid embedded in bio‐derived poly(lactic acid)/silk sericin nanogels and their incorporation with surface‐porous electrospun fibers of poly(lactide‐co‐glycolide) for potential use as scaffolds in tissue engineering and drug delivery system, Adv. Compos. Hybrid Mater., 7, 206 (2024). http://dx.doi.org/10.1007/s42114-024-01040-z IF=23.2

4.     Z. Zhang, J. J. Rubio Arias, H. Kaehr, Y. Liu, R. Murata, M. Unno, N. Yodsin, P. Pimbaotham, S. Jungsuttiwong, M. Rammo, J. Heo, J. Kim, A. Rebane, R. M. Laine, Conjugation through Si–O–Si bonds, silsesquioxane (SQ) half cage copolymers, extended examples via SiO0.5/SiO1.5 units: multiple emissive states in violation of Kasha's rule, Dalton Trans., 53, 10328–10337 (2024). https://doi.org/10.1039/D4DT00567H IF=4.6

5.     A. Tuanchai, P. Iamphring, P. S. M. Boupan, J. Mikule, J. P. P. Aguilera, P. Worajittiphon, Y. Liu, G. M. Ross, St. Kunc, P. Mikeš, M. Unno, S. Ross, Bilayer Scaffolds of PLLA/PCL/CAB Ternary Blend Films and Curcumin-Incorporated PLGA Electrospun Nanofibers: The Effects of Polymer Compositions and Solvents on Morphology and Molecular Interactions, Polymers, 16, 1679 (2024). https://doi.org/10.3390/polym16121679 IF=4.7

6.     J. J. Rubio Arias, Z. Zhang, M. Takahashi, P. Mahalingam, P. Pimbaotham, N. Yodsin, M. Unno, Y. Liu, S. Jungsuttiwong, J. Azoulay, M. Rammo, A. Rebane, R. M. Laine, Conjugation in polysiloxane copolymers via unexpected Si-O-Si dπ-pπ overlap, a second mechanism?  Polym. J., 52, 577-588 (2024). https://doi.org/10.1038/s41428-024-00899-5 IF=2.8

7.     Q. Wang, M. Unno, H. Liu, Ultrafast and highly selective gold recovery with high capture capacity from electronic waste by upconversion of a silsesquioxane-based hybrid luminescent aerogel, J. Mater. Chem. A, 12, 5679-5691 (2024). https://doi.org/10.1039/D3TA07339D IF=10.7

8.     Y. Liu, M. Tokuda, N. Takeda, A. Ouali, M. Unno, New Janus Tricyclic Laddersiloxanes: Synthesis, Characterization, and Reactivity, Molecules, 28, 5699 (2023). https://doi.org/10.3390/molecules28155699 IF=4.6

9.     Z. Zheng, Y. Liu, N. Takeda, M. Unno, Synthesis and Characterization of Sulfide/Sulfone-Containing 18- 8-18-Membered-Ring Ladder-Type Siloxanes, Dalton Trans., 52, 9737-9743 (2023). https://doi.org/10.1039/D3DT01227A IF=4.0

10. Q. Wang, M. Unno, H. Liu, Dual-Function Near-Infrared Emitting Aerogel-Based Device for Detection and Sunlight-Driven Photodegradation of Antibiotics: Realizing the Processability of Silsesquioxane-Based Fluorescent Porous Materials, Adv. Funct. Mater., 2214875 (2023). https://doi.org/10.1002/adfm.202214875 IF=19.9

11. T. Chaiprasert, S. Chanmungkalakul, Y. Liu, T. Bureerug, K. Silpcharu, M. Unno, L. Xiaogang, V. Ervithayasuporn, Y.-T. Chang, P. Rashatasakhon, Fluorescent Janus ring siloxanes for detection of Au(III) and l-cysteine, Dyes Pigm., 208, 110793 (2023). https://doi.org/10.1016/j.dyepig.2022.110793 IF=4.5

12. S. Kondo, N. Okada, S. Abe, R. Tanaka, M. Yamamura, M. Unno, Anion recognition by silanetriol in acetonitrile, Org. Biomol. Chem., 20, 5925-8931 (2022). https://doi.org/10.1039/D2OB01596J IF=3.2

13. Q. Wang, M. Unno, H. Liu, Organic−Inorganic Hybrid Near- Infrared Emitting Porous Polymer for Detection and Photo-degradation of Antibiotics. ACS Sustainable Chem. Eng., 10, 7309−7320 (2022).　 https://doi.org/10.1021/acssuschemeng.2c00935 IF=9.2

14. M. Laird, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Thiolated Janus silsesquioxane tetrapod: new precursors for functional materials, Molecules, 27, 7680 (2022). https://doi.org/10.3390/molecules27227680 IF=4.9

15. Y. Liu, T. Chaiprasert, A. Ouali, M. Unno, Well-defined cyclic silanol derivatives, Dalton Trans., 51, 4227-4245 (2022). https://doi.org/10.1039/D1DT04270J IF=4.6

16. Y. Liu, K. Koizumi, N. Takeda, M. Unno, A. Ouali, Synthesis of octachloro and octaazido-functionalized T₈ cages and applications to recyclable palladium catalyst, Inorg. Chem., 61, 1495-1503 (2022). https://doi.org/10.1021/acs.inorgchem.1c03209 IF=5.4

17. Y. Liu, M. Katano, P. Yingsukkamol, N. Takeda, M. Unno, A. Ouali, Tricyclic 6-8-6 laddersiloxanes derived from all-cis-tetravinylcyclotetrasiloxanolate: Synthesis, characterization and reactivity, J. Organomet. Chem., 959, 122213 (2022). https://doi.org/10.1016/j.jorganchem.2021.122213 IF=2.3

18. Y. Egawa, C. Kobuna, N. Takeda, M. Unno, Synthesis of Janus cube containing Si–H moieties, Mendeleev Commun., 32, 35–36 (2022). IF=1.8

19. Y. Liu, A, Endo, P. Zhang, A. Takizawa, N. Takeda, A. Ouali, M. Unno, Synthesis, Characterization, and Reaction of Divinyl-substituted Laddersiloxanes, Silicon, 14, 2723-2730 (2022). https://doi.org/10.1007/s12633-021-01068-6  IF = 2.7

20. Y. Liu, M. Kigure, R. Okawa, N. Takeda, M. Unno, A. Ouali, Synthesis and characterization of tetrathiol-substituted double-decker or ladder silsesquioxane nano-cores, Dalton Trans., 50, 3473–3478 (2021). https://doi.org/10.1039/D1DT00042J IF=4.6

21. M. Laird, C. Totée, P. Gaveau, G. Silly, A. Van der Lee, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Functionalised polyhedral oligomeric silsesquioxane with encapsulated fluoride – first observation of fluxional Si⋯F interactions in POSS, Dalton Trans., 50, 81–89 (2021). IF=4.2 https://doi.org/10.1039/D0DT03057K

22. Q. Wang, M. Unno, H. Liu, Silsesquioxane-Based Triphenylamine-Linked Fluorescent Porous Polymer for Dyes Adsorption and Nitro-Aromatics Detection, Materials, 14, 3851 (2021). IF=3.7 https://doi.org/10.3390/ma14143851

23. T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Vinyl-Functionalized Janus Ring Siloxane: Potential Precursors to Hybrid Functional Materials, Materials,14, 2014 (2021). IF=3.7 https://doi.org/10.3390/ma14082014

24. J. Guan, Z. Sun, R. Ansari, Y. Liu, A. Endo, M. Unno, A. Ouali, S. Mahbub, J. C. Furgal, N. Yodsin, S. Jungsuttiwong, D. Hashemi, J. Kieffer, and R. M. Laine, Conjugated Copolymers That Shouldn’t Be, Angew. Chem. Int. Ed. 60, 11115–11119 (2021). IF=16.8 https://doi.org/10.1002/anie.202014932

25.  M. Laird, P. Gaveau, P. Trens, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Post-synthesis modification of functionalised polyhedral oligomeric silsesquioxanes with encapsulated fluoride – enhancing reactivity of T₈-F POSS for materials synthesis, New J. Chem., 45,　4227–4235 (2021). https://doi.org/10.1039/d0nj06008a IF = 3.9

26. T. Chaiprasert, Y. Liu, P. Intaraprecha, R. Kunthom, N. Takeda, M. Unno, Synthesis of tricyclic laddersiloxane with various ring sizes (Bat siloxane), Macromol. Rapid Commun., 42, 2000608 (2021).  https://doi.org/10.1002/marc.202000608 IF = 5.0

27. M. Laird, N. Herrmann, N. Ramsahye, C. Totée, C. Carcel, M. Unno, J. Bartlett, M. Wong Chi Man, Large polyhedral oligomeric silsesquioxane cages – the isolation of functionalized POSS with an unprecedented Si₁₈O₂₇ core, Angew. Chem. Int. Ed., 60, 3022–3027 (2021). IF=16.8 https://doi.org/10.1002/anie.202010458

28. M. Laird, J. Yokoyama, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Sol–gel processing of polyhedral oligomeric silsesquioxanes: nanohybrid materials incorporating T8 and T10 cages, J. Sol-Gel Sci. Tech., 95, 760–770 (2020).  https://doi.org/10.1007/s10971-020-05314-y IF = 2.33

29. T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Janus ring siloxane: a versatile precursor of the extended Janus ring and tricyclic laddersiloxanes, Dalton Trans., 49, 13533–13537 (2020). IF = 4.17 https://doi.org/10.1039/D0DT03045G

30. Y. Liu, M. Kigure, K. Koizumi, N. Takeda, M. Unno, A. Ouali, Synthesis of Tetrachloro, Tetraiodo, and Tetraazido Double-Decker Siloxanes, Inorg. Chem., 59, 15478–15486 (2020). If = 4.83 https://doi.org/10.1021/acs.inorgchem.0c02515

31. M. Laird, A. van der Lee, D. Dumitrescu, C. Carcel, A. Ouali, J. Bartlett, M. Unno, M. Wong Chi Man, Styryl Functionalized Cage Silsesquioxanes as Nano Blocks for 3-D Assembly, Organometallics, 39, 1896–1906 (2020). IF = 3.80  https://dx.doi.org/10.1021/acs.organomet.0c00119

32. Y. Du, M. Unno, H. Liu, Hybrid Nanoporous Materials Derived from Ladder- and Cage-Type Silsesquioxanes for Water Treatment, ACS Appl. Nano Mater., 3, 1535–1541 (2020). IF = 3.94 https://doi.org/10.1021/acsanm.9b02325

33. Y. Liu, K. Onodera, N. Takeda, A. Ouali, M. Unno, Synthesis and Characterization of Functionalizable Silsesquioxanes with Ladder-type Structures, Organometallics, 38, 4173–4176 (2019).  IF = 3.80  https://doi.org/10.1021/acs.organomet.9b00597

34. N. Prigyai, S. Chanmungkalakul, V. Ervithayasuporn, N. Yodsin, S. Jungsuttiwong, N. Takeda, M. Unno, J. Boonmak, S. Kiatkamjornwong, Lithium-Templated Formation of Polyhedral Oligomeric Silsesquioxanes (POSS), Inorg. Chem. 58, 15110–15117 (2019). If = 4.83 https://doi.org/10.1021/acs.inorgchem.9b01836

35. R. Kunthom, T. Adachi, Y. Liu, N. Takeda, M. Unno, R. Tanaka, Synthesis of a "Butterfly Cage" Based on a Double-Decker Silsesquioxane, Chem. Asian J., 14, 4179–4182 (2019). IF = 4.06 https://doi.org/10.1002/asia.201901361

36. R. Kunthom, N. Takeda, M. Unno, Synthesis and Characterization of Unsymmetrical Double-decker Siloxane (Basket Cage), Molecules, 24, 4252 (2019). IF = 3.31  https://doi.org/10.3390/molecules24234252

37. Y. Liu, N. Takeda, A. Ouali, M. Unno, Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes, Inorg. Chem., 58, 4093–4098 (2019). If = 4.83 https://doi.org/10.1021/acs.inorgchem.9b00416

38. T. Tanaka, Y. Hasegawa, T. Kawamori, R. Kunthom, N. Takeda, M. Unno, Synthesis of Double-Decker Silsesquioxanes from Substituted Difluorosilane, Organometallics, 38, 743-747 (2019). IF = 3.80 https://doi.org/10.1021/acs.organomet.8b00896

39. S. Kondo, Y. Nakadai, M. Unno, Recognition of dicarboxylates in aqueous acetonitrile by a dinuclear zinc(II) complex of 2,2'-binaphthalene-based receptor, Supramolecular Chem., 31, 9–18 (2019). IF = 1.35 https://doi.org/10.1080/10610278.2018.1522445

40. T. Uchida, Y. Egawa, T. Adachi, N. Oguri, M. Kobayashi, T. Kudo, N. Takeda, M. Unno, R. Tanaka, Synthesis, Structures, and Thermal Properties of Symmetric and Janus “Lantern Cage” Siloxanes, Chem. Eur. J., 25, 1683 –1686 (2019). IF = 4.86  https://doi.org/10.1002/chem.201805200

41. H. Endo, N. Taked M. Unno, Single-step synthesis of disiloxanetetraols, J. Sol-Gel Sci. Technol., 89, 37–44 (2019).  IF = 2.33  https://doi.org/10.1007/s10971-018-4635-9

42. C. Weetman, N. Ito, M. Unno, F. Hanusch, S. Inoue, NHI- and NHC-Supported Al(III) Hydrides for Amine–Borane Dehydrocoupling Catalysis, Inorganics, 7, 92 (2019).                    https://doi.org/10.3390/inorganics7080092

43. Y. Egawa, C. Fukumoto, K. Mikami, N. Takeda, M. Unno, Synthesis and Characterizations of
The Germathioacid chloride Coordinated by an N-Heterocyclic carbene, Inorganics, 6, 76 (2018). IF = 2.15  https://doi.org/10.3390/inorganics6030076

44. H. Endo, N. Takeda, M. Unno, Stereoisomerization of Cyclic Silanols, Chem. Asian J., 12, 1224–1233 (2017). IF = 4.06  https://doi.org/10.1002/asia.201700125

45. N. Oguri, Y. Egawa, Y. Kawakami, C. Kobuna, N. Takeda, M. Unno, Unusual Reactions of Cyclic Fluorosiloxanes, ChemistrySelect, 2, 2300–2304 (2017). IF = 2.00  https://doi.org/10.1002/slct.201700306

46. Y. Egawa, S. Murakami, N. Takeda, and M. Unno, Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New Building Block for Materials, Chem. Lett., 45, 738–739 (2016). IF = 1.36 https://doi.org/10.1246/cl.160272

47. N. Oguri, Y. Egawa, N. Takeda, and M. Unno, Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure Elucidation, Angew. Chem. Int. Ed. 55, 9336-9339 (2016). IF=12.96 https://doi.org/10.1002/anie.201602413

48. N. Takeda, Y. Tanaka, R. Oma, F. Sakakibara, M. Unno, Activation of C–S Bond by Group 10 Metal Complexes: Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl Groups with Group 10 Metal Compounds, Bull. Chem. Soc. Jpn., 89, 922-930 (2016). IF = 4.49 https://doi.org/10.1246/bcsj.20160089

49. S. Murakami, Y. Egawa, C. Kuramochi, N. Takeda, and M. Unno, Cyclic Silanols with Long Alkyl Chains, Chem. Lett., 45, 309–311 (2016). https://doi.org/10.1246/cl.151143

50.  川守崇司， 海野雅史, イオン性官能基を持つポリマーを組合せたコアセルベート型ハイドロゲルの特性向上に関する検討, ネットワークポリマー 37, 122-130 (2016).

51.  K. Kakiage, T. Abe, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Effect of the introduction of a CF₃ group to a silyl-anchor azobenzene dye on sensitization property in dye-sensitized solar cells, Key Eng. Mater., 698, 27–31 (2016). https://doi.org/10.4028/www.scientific.net/KEM.698.27

52. N. Oguri, N. Takeda, and M. Unno, Facile Synthesis of Cyclic Fluorosiloxanes, Chem. Lett., 44, 1506–1508 (2015). https://doi.org/10.1246/cl.150692

53. H. Endo, and N. Takeda, M. Takanashi, T. Imai, and M. Unno, Refractive Indices of Silsesquioxanes with Various Structures, Silicon, 7, 127–32 (2015). https://doi.org/10.1007/s12633-014-9239-6

54. M. Unno, H. Endo, and N. Takeda, Synthesis and Structures of Extended Cyclic Siloxanes, Heteroatom Chem. 25, 525–532 (2014). https://doi.org/10.1002/hc.21198

55. N. Takeda, T. Tagawa, and M. Unno, Synthesis, Reactivities, and Coordination Chemistry of Tris(2-​isopropoxyphenyl)​phosphine, Heteroatom Chem. 25, 628–635 (2014). https://doi.org/10.1002/hc.21174

56. K. Kakiage, Y. Aoyama, T. Yano, T. Otsuka, T. Kyomen, M. Unno, and M. Hanaya, An achievement of over 12 percent efficiency in an organic dye-​sensitized solar cell, Chem. Commun., 50, 6379–6381 (2014). https://doi.org/10.1039/c4cc02192d

57. H. Endo, N. Takeda, and M. Unno, Synthesis and Properties of Phenylsilsesquioxanes with Ladder and Double-​Decker Structures, Organometallics, 33, 4148-4151 (2014). https://doi.org/10.1021/om500010y

58. R. Yanagisawa, H. Endo, M. Unno, H. Morimoto, S. Tobishima, Effects of organic silicon compounds as additives on charge-​discharge cycling efficiencies of lithium in nonaqueous electrolytes for rechargeable lithium cells, J. Power Sources, 266, 232–240 (2014). https://doi.org/10.1016/j.jpowsour.2014.05.017

59. S. Kondo, Y. Nakadai, and M. Unno, Pyrophosphate selective recognition by a Zn²⁺ complex of a 2,20-binaphthalene derivative bearing di(2-pyridylmethyl)aminomethyl groups in aqueous solution, RSC Adv., 4, 27140–27145 (2014). https://doi.org/10.1039/c4ra01941e

60. K. Kakiage, Y. Aoyama, M. Yamamura, T. Yano, M. Unno, T. Kyomen, and M. Hanaya, A Novel Alkoxysilyl Azobenzene Dye Photosensitizer with Alkylamino Group for Dye-Sensitized Solar Cells, Silicon, 6, 123–127 (2014). https://doi.org/10.1007/s12633-013-9174-y

61. M. Yamamura, S. Kondo, and M. Unno, Ion Pair Recognition of Ditopic Receptor Bearing Silanol Groups as Anion Recognition Sites and a 2,2'-Bipyridine Moiety as a Metal-coordination Site, Tetrahedron Lett., 55, 646–649 (2014). https://doi.org/10.1016/j.tetlet.2013.11.096

62. S. Kondo, N. Watanabe, F. Takahashi, N. Takeda, and M. Unno, Synthesis and photophysical properties of 2,2’-binaphthalene-based receptor bearing trimethylsilyl groups to improve the solubility, 
J. Incl. Phenom. Macrocycl. Chem., 75, 31-38 (2013). https://doi.org/10.1007/s10847-012-0142-8

63. H. Endo and M. Unno, Effective Synthesis and Isomerization of Cyclotetrasiloxanetetraol, Key Eng. Mater., 534, 66–70 (2013). https://doi.org/10.4028/www.scientific.net/KEM.534.66

64. K. Kakiage, C. Saito, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Study of the Chemical Adsorption Property of Allylsilylazobenzene in the Surface Modification of Nano-Porous Alumina Membrane, Key Eng. Mater., 534, 46–52 (2013). https://doi.org/10.4028/www.scientific.net/KEM.534.46

65. M. Unno, T. Matsumoto, H. Matsumoto, Nonacyclic Ladder Silsesquioxanes and Spectral Features of Ladder Polysilsesquioxanes, Int. J. Polym. Sci., 723892 (2012). https://doi.org/10.1155/2012/723892

66. K. Kakiage, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Adsorption and Sensitizing Properties of Azobenzenes Having Different Numbers of Silyl-anchor Groups in Dye-sensitized Solar Cells, Key Eng. Mater., 497, 61–66 (2012). https://doi.org/10.4028/www.scientific.net/KEM.497.61

67. K. Kakiage, T. Tsukahara, T. Kyomen, M. Unno, and M. Hanaya, Significant Improvement of Photovoltaic Performance of Dye-sensitized Solar Cells by Using 4-Trimethylsilylpyridine as Organic Additive to Electrolyte Solution, Chem. Lett., 41, 895-896 (2012). https://doi.org/10.1246/cl.2012.895

68. (Selected Paper) S. Kondo, S. Nakajima, and M. Unno, Ratiometric Fluorescence Detection of Anions by an Amide-Based Receptor Bearing Pyrenyl Groups, Bull. Chem. Soc. Jpn., 85, 698-700 (2012). https://doi.org/10.1246/bcsj.20120054

69. S. Kondo, H. Sonoda, T. Katsu, and M. Unno, Improvement of solubility of 2,2′-binaphthalene derivatives bearing urea groups as anion receptors and their application to a chloride selective electrode, Sensors and Actuators B, 160, 684–690 (2011). https://doi.org/10.1016/j.snb.2011.08.048

70. V. Ervithayasuporn, T. Tomeechai, N. Takeda, M. Unno, A. Chaiyanurakkul, R. Hamkool, and T. Osotchan, Synthesis and Characterization of Octakis(3-propyl ethanethioate)octasilsesquioxane, Organometallics, 30, 4475–4478 (2011). https://doi.org/10.1021/om200477a

71. M. Unno, N. Yamashita, and H. Matsumoto, Thermal Reaction of Octasilacubane with Sulfur, Selenium, and Tellurium: Formation of Novel Cage Systems, Phosphorus, Sulfur, Silicon Relat. Elem., 186, 1259–1262 (2011). https://doi.org/10.1080/10426507.2010.525769

72. Y. Egawa and M. Unno, Solvent-free Synthesis of Functional Siloxanes Bearing 4-Trifluoromethylphenyl Group, Key Eng. Mater., 497, 51–54 (2011). https://doi.org/10.4028/www.scientific.net/KEM.497.51

73. K. Kakiage, M. Yamamura, E. Ido, T. Kyomen, M. Unno, and M. Hanaya, Reactivity of Alkoxysilyl Compounds: Chemical Surface Modification of Nano-porous Alumina Membrane Using Alkoxysilylazobenzenes, Appl. Organomet. Chem., 25, 98–104 (2011). https://doi.org/0.1002/aoc.1722

74. S. Kondo, T. Takahashi, Y. Takiguchi, and M. Unno, Synthesis and photophysical properties of a 2,2’-bianthracene-based receptor bearing two aza-15-crown-5 ethers for naked-eye detection of barium ion, Tetrahedron Lett., 52, 453–457 (2011). https://doi.org/10.1016/j.tetlet.2010.11.091

75. S. Kondo, M. Nagamine, S. Karasawa, M. Ishihara, M. Unno, and Y. Yano, Anion recognition by 2,2’-binaphthalene derivatives bearing urea and thiourea groups at 8- and 8’-positions by UV-vis and fluorescence spectroscopies, Tetrahedron, 67, 943-950 (2011). https://doi.org/10.1016/j.tet.2010.12.004

76. N. Takeda, T. Nakamura, A. Imamura, and M. Unno, Synthesis and reactivities of dihydrosilanes tethered with two thioether moieties, Heteroatom Chem. 22, 438–445 (2011). https://doi.org/10.1002/hc.20706

77. M. Unno, R. Tanaka, D. Obinata, M. Endo, T. Sakurai, S. Ojima, T. Katayama, K. Fugami, Solvent-​free synthesis of siloxanes and their usage as potential cross-​coupling reagents, Key Eng. Mater., 459, 43–47 (2011). https://doi.org/10.4028/www.scientific.net/KEM.459.43

78. R. Tanaka, S. Kowase, and M. Unno, Chiral Cyclotrisiloxanes, Dalton Trans., 39, 9235–9237 (2010). https://doi.org/10.1039/C0DT00135J

79. N. Takeda, D. Watanabe, T. Nakamura, and M. Unno, Synthesis and Complexation of New Tripodal Tetradentate Ligand, Silyl Ligand Tethered with Three Thioether Moieties, Organometallics, 29, 2839-2841 (2010). https://doi.org/10.1021/om100255p

80. S. Kondo, Y. Kobayashi, and M. Unno, Anion Recognition by D-Ribose-based Receptors, Tetrahedron Lett., 51, 2512–2514 (2010). https://doi.org/10.1016/j.tetlet.2010.03.001

81. M. Unno, R. Tanaka, D. Obinata, M. Endo, T. Sakurai, S. Ojima, T. Katayama, and K. Fugami, Solvent-free Synthesis of Siloxanes and Their Usage as Potential Cross-Coupling Reagents, Key. Eng. Mater., 459, 43–47 (2010). https://doi.org/10.4028/www.scientific.net/KEM.459.43

82. N. Takeda, Y. Tanaka, F. Sakakibara, and M. Unno, Synthesis and Structure of Group 10 Metal Complexes with New Tripodal Tetradentate Ligand Bearing One Phosphine and Three Thioether Moieties, Bull. Chem. Soc. Jpn., 83, 157–164 (2010). https://doi.org/10.1246/bcsj.20090187

83. K. Kakiage, M. Yamamura, E. Fujimura, T. Kyomen, M. Unno and M. Hanaya, High Performance of Si–O–Ti Bonds for Anchoring Sensitizing Dyes on TiO₂ Electrodes in Dye-sensitized Solar Cells Evidenced by Using Alkoxysilylazobenzenes, Chem. Lett., 39, 260–262 (2010). https://doi.org/10.1246/cl.2010.260

84. K. Kakiage, T. Kyomen, M. Unno, and M. Hanaya, Molecular-selective Adsorption Property of Chemically Surface Modified Nanoporous Alumina Membrane by Di(1-naphthyl)silanediol to Anthracenes, Appl. Organomet. Chem., 24, 198–200 (2010). https://doi.org/10.1002/aoc.1586

85. S. Chang, T. Matsumoto, H. Matsumoto, and M. Unno, Synthesis and Characterization of Heptacyclic Laddersiloxanes and Ladder Polysilsesquioxane, Appl. Organomet. Chem., 24, 241–246 (2010). https://doi.org/10.1002/aoc.1607

86. M. Unno, K. Kakiage, M. Yamamura, T. Kogure, T. Kyomen, and M. Hanaya, Silanol Dyes for Solar Cells: Higher Efficiency and Significant Durability, Appl. Organomet. Chem., 24, 247–250 (2010). https://doi.org/10.1002/aoc.1612

87. K. Kakiage, T. Kyomen, M. Unno, and M. Hanaya, The Chemical Adsorption Properties of Silanol to Metal-Oxide Surface Studied by Using Di(1-naphthyl)silanediol and Nano-porous Alumina Membranes, Silicon, 1, 191–197 (2009). https://doi.org/10.1007/s12633-009-9027-x

88. S. Kondo, N. Okada, R. Tanaka, M. Yamamura, and M. Unno, Anion recognition by 1,3-disiloxane-1,1,3,3-tetraols in organic solvents, Tetrahedron Lett., 50, 2754–2757 (2009). https://doi.org/10.1016/j.tetlet.2009.03.134

89. H. Liu, S. Kondo, N. Takeda, and M. Unno, An Efficient Approach to Monophenyl-Functionalized Octasilsesquioxanes, Eur. J. Inorg. Chem., 5, 1317-1319 (2009). https://doi.org/10.1002/ejic.200900012

90. H. Liu, S. Kondo, N. Takeda, and M. Unno, Synthesis of Octacarboxy Spherosilicate, J. Am. Chem. Soc., 130, 10074–10075 (2008). https://doi.org/10.1021/ja803513n

91. K. Kakiage, Y. Nakada, T. Kogure, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Applicability of Silanol to Sensitizing Dye for Dye-sensitized Solar Cell, Silicon Chem., 3, 303–305 (2008). https://doi.org/10.1007/s11201-008-9032-8

92. H. Liu, S. Kondo, R. Tanaka, H. Oku, and M. Unno, A spectroscopic investigation of incompletely condensed polyhedral oligomeric silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol): Hydrogen-bonded interaction and host–guest complex, J. Organomet. Chem., 693 1301–1308 (2008). https://doi.org/10.1016/j.jorganchem.2008.01.027

93. 金澤貴之，味澤俊介，海野雅史，上田浩，"遠隔通信技術を活用した聴覚障害学生支援―キャンパス間連携入力方式の導入事例から―"，メディア教育研究 (Journal of Multimedia Aided Education Research), 5, 55-61 (2008). http://www.code.ouj.ac.jp/media/pdf5-2-10/No.10-07tokusyuu06.pdf

94. S. Kondo, A. Fukuda, T. Yamamura, R. Tanaka, and M. Unno, Anion Recognition by a Disiloxane-1,3-diol in Organic Solvents, Tetrahedron. Lett., 48, 7946–7949 (2007). https://doi.org/10.1016/j.tetlet.2007.09.067

95. S. Kondo, T. Hayashi, Y. Sakuno, Y. Takezawa, T. Yokoyama, M. Unno, and Y. Yano, Synthesis of cyclic bis- and Trismelamine Derivatives and Their Complexation properties with Barbiturates, Org. Biomol. Chem., 5, 907–916 (2007). https://doi.org/10.1039/B615537E

96. M. Endo, T. Sakurai, S. Ojima, T. Katayama, M. Unno, H. Matsumoto, S. Kowase, H. Sano, M. Kosugi, and K. Fugami, Novel Pd-Catalyzed Atom-Efficient Cross-Coupling Reaction by Means of Hexaarylcyclotrisiloxane, SynLett, 5, 749-752 (2007). https://doi.org/10.1055/s-2007-970773

97. M. Unno, T. Matsumoto, and H. Matsumoto, Synthesis of Laddersiloxanes by Novel Stereocontrolled Approach, J. Organomet. Chem., 692, 307–312 (2007). https://doi.org/10.1016/j.jorganchem.2006.08.068

98. S. Kondo, T. Harada, R. Tanaka, and M. Unno, Anion Recognition by a Silanediol-Based Receptor, Org. Lett., 8, 4621–4624 (2006). https://doi.org/10.1021/ol061822p

99. M. Unno, H. Murakami, S. Kagawa and H. Matsumoto, Borderline of Hydrogen Bonding by Silanols, Silicon Chem., 3, 195–198 (2005). https://doi.org/10.1007/s11201-006-9021-8

100.    M. Hirotsu, S. Taruno, T. Yoshimura, K. Ueno, M. Unno, and H. Matsumoto, Synthesis and Structures of the First Titanium(IV) Complexes with Cyclic Tetrasiloxide Ligands: Incomplete and Complete Cage Titanosiloxanes, Chem. Lett., 34, 1542–1543 (2005). https://doi.org/10.1246/cl.2005.1542

101.    M. Unno, S. Chang, and H. Matsumoto, cis-trans-cis-Tetrabromotetramethylcyclotetrasiloxane: a Versatile Precursor of Ladder Silsesquioxanes, Bull. Chem. Soc. Jpn., 78, 1105–1109 (2005). https://doi.org/10.1246/bcsj.78.1105

102.    M. Unno, R. Tanaka, S. Tanaka, T. Takeuchi, S. Kyushin, and H. Matsumoto, Oligocyclic Laddersiloxanes: Alternative Synthesis by Oxidation, Organometallics, 24, 765–768 (2005). https://doi.org/10.1021/om049324c

103.    M. Unno, Y. Kawaguchi, Y. Kishimoto, and H. Matsumoto, Stereoisomers of 1,3,5,7-Tetrahydroxy-1,3,5,7-tetaisopropylcyclotetrasiloxane: Synthesis and Structures in the Crystal, J. Am. Chem. Soc., 127, 2256–2263 (2005). https://doi.org/10.1021/ja043894m

104.    T. Okutsu, K. Isomura, N. Kakinuma, H. Horiuchi, M. Unno, H. Matsumoto, and H. Hiratsuka, Laser-induced morphology control and liquid phase epitaxy of dipara-anthracene produced from photochemical reaction of anthracene, Cryst. Growth Des., 5, 461–465 (2005). https://doi.org/10.1021/cg049816s

105.       M. Unno, Y. Kishimoto, and H. Matsumoto, Triisopropylcyclotrisiloxanetriol: An Unprecedented Cyclic Siloxanetriol with Relatively Small Substituents, Organometallics, 23, 6221–6224 (2004). https://doi.org/10.1021/om0494972

106.       K. Negishi, M. Unno, and H. Matsumoto, The Cyclo[(disilanylene)(butadiyne)]s [(i-Pr)₂Si(i-Pr)₂SiCºCCºC]_n (n = 2–4), Chem. Lett., 33, 430–431 (2004). https://doi.org/10.1246/cl.2004.430

107.       M. Unno, Y. Imai, and H. Matsumoto, Hexakis(2,4,6-triisopropylphenylsilsesquioxane), Silicon Chem., 2, 175–178 (2003). https://doi.org/10.1023/B:SILC.0000046726.90699.41

108.       M. Unno, T. Tanaka, and H. Matsumoto, Tip-substituted Cage and Cyclic Silanols, J. Organomet. Chem., 686, 175–182 (2003). https://doi.org/10.1016/S0022-328X(03)00541-2

109.       M. Unno, T. Matsumoto, K. Mochizuki, K. Higuchi, M. Goto, and H. Matsumoto, Structure and Oxidation of Octakis(tert-butyldimethylsilyl)octasilacubane, J. Organomet. Chem., 685, 156–161 (2003). https://doi.org/10.1016/S0022-328X(03)00288-2

110.       M. Unno, H. Masuda, and H. Matsumoto, Photo-initiated Bromination of Octakis(1,1,2-trimethylpropyl)octasilacubane with Tetrabromomethane, Silicon Chem., 1, 377–381 (2002). https://doi.org/10.1023/B:SILC.0000025578.17683.2a

111.       K. Yamada, M. Unno, K. Kobayashi, H. Oku, H. Yamamura, S. Araki, H. Matsumoto, R. Katakai, and M. Kawai, Stereochemistry of Protected Ornithine Side Chains of Gramicidin S Derivatives: X-ray Crystal Structure of the Bis-Boc-tetra-N-methyl Derivatives of Gramicidin S, J. Am. Chem. Soc., 124, 12684–12688 (2002). https://doi.org/10.1021/ja020307t

112.    R. Tanaka, S. Kyushin, M. Unno, and H. Matsumoto, Chiral crystallization of anti-dodecaisopropyltricyclo[4.2.0.0^2,5]octasilane, Enantiomer, 7, 157–159 (2002). https://doi.org/10.1080/10242430212882

113.       M. Unno, A. Suto, and H. Matsumoto, Pentacyclic Laddersiloxane, J. Am. Chem. Soc., 124, 1574–1575 (2002). https://doi.org/10.1021/ja0173876

114.       M. Unno, Y. Kawai, and H. Matsumoto, Synthesis and Crystal Structures of 2,4,6-Tri-tert-butylphenyltrichlorogermane and 2,4,6-Tri-tert-butylphenylgermane, Heteroatom Chem., 12, 238–243 (2001). https://doi.org/10.1002/hc.1038

115.       M. Unno, T. Saito, and H. Matsumoto, Synthesis and Crystal Structures of Silapericyclynes, Bull. Chem. Soc. Jpn., 74, 2407–2413 (2001). https://doi.org/10.1246/bcsj.74.2407

116.       M. Unno, K. Negishi, and H. Matsumoto, Extended Silapericyclynes, Chem. Lett., 30, 340–341 (2001). https://doi.org/10.1246/cl.2001.340

117.       M. Unno, K. Higuchi, K. Furuya, H. Shioyama, S. Kyushin, M. Goto, and H. Matsumoto, Synthesis, Structure, and Reactions of Octakis(1,1,2-trimethylpropyl)octagermacubane, Bull. Chem. Soc. Jpn., 73, 2093–2097 (2000). https://doi.org/10.1246/bcsj.73.2093

118.    S. Kyushin, A. Meguro, M. Unno, and H. Matsumoto, Photolysis of anti-Dodecaalkyltricyclo[4.2.0.0^2,5]octasilane: Generation and Reactions of Cyclotetrasilene, Chem. Lett., 29, 494–495 (2000). https://doi.org/10.1246/cl.2000.494

119.    H. Horiuchi, Y. Nakano, T. Matsumoto, M. Unno, H. Matsumoto, and H. Hiratsuka, Electronic Structure and Photochemical Reaction Intermediates of Octakis(1,1,2-trimethylpropyl)octasilacubane, Chem. Phys. Lett., 322, 33–40 (2000). https://doi.org/10.1016/S0009-2614(00)00357-2

120.    M. Unno, K. Takada, and H. Matsumoto, Formation of Supramolecule by Assembling of Two Different Silanols, Chem. Lett., 29, 242–243 (2000). https://doi.org/10.1246/cl.2000.242

121.   M. Unno, A. Suto, K. Takada, and H. Matsumoto, Synthesis of Ladder and Cage Silsesquioxanes from 1,2,3,4-Tetrahydroxycyclotetrasiloxane, Bull. Chem. Soc. Jpn., 73, 215–220 (2000). https://doi.org/10.1246/bcsj.73.215

122.   M. Unno, D. Ishii, and H. Matsumoto, Kinetic Study of Thermal Isomerization of the “Double-decker”-type Sesquichalcogenides, (Thex₂M₂E₂)₂E₂ (M=Si, Ge; E=S, Se), Bull. Chem. Soc. Jpn, 72, 2469–2473 (1999). https://doi.org/10.1246/bcsj.72.2469

123.    M. Unno, T. Saito, and H. Matsumoto, Silapericyclyne, (Ph₂SiCºC)₆: Spontaneous Conformational Resolution of Boat- and Chair-'Exploded' Cyclohexane, Chem. Lett., 28, 1235–1236 (1999). https://doi.org/10.1246/cl.1999.1235

124.    R. Tanaka, M. Unno, and H. Matsumoto, Synthesis and Molecular Structures of Novel Isopropyl-substituted Oligosilanes, Chem. Lett., 28, 595–596 (1999). https://doi.org/10.1246/cl.1999.595

125.    M. Unno, R. Tanaka, S. Kyushin, and H. Matsumoto, Synthesis and Reactions of Hepta-t-butylcyclotetragermane, Phosphorus, Sulfur, Silicon Relat. Elem., 150/151, 167–176 (1999). https://doi.org/10.1080/10426509908546382

126.    M. Unno, B. A. Shamsul, M. Arai, K. Takada, R. Tanaka and H. Matsumoto, Synthesis and Characterization of Cage and Bicyclic Silsesquioxanes via Dehydration of Silanols, Appl. Organomet. Chem., 13, 303-310 (1999). https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291099-0739%28199904%2913%3A4%3C303%3A%3AAID-AOC846%3E3.0.CO%3B2-%23

127.    M. Unno, K. Takada, and H. Matsumoto, Synthesis, Structure, and Reaction of the Tetrahydroxycyclotetrasiloxane [(i-Pr)(OH)SiO]₄, Chem. Lett., 27, 489–490 (1998). https://doi.org/10.1246/cl.1998.489

128.    M. Unno, H. Masuda, and H. Matsumoto, 1,2,3-Triphenyl-1,2,3-trithexylcyclotrisilanes: Synthesis and Ring-Opening by Halogens, Bull. Chem. Soc. Jpn, 70, 2449–2458 (1997). https://doi.org/10.1246/bcsj.71.2449

129.    M. Unno, R. Tanaka, T. Kuribara, M. Saito, and H. Matsumoto, Synthesis, Structures, and Reactions of 1,2,3-Tris(diethylamino)-1,2,3,4-tetrakis-(1,1,2-trimethylpropyl)cyclotetrasilanes, Bull. Chem. Soc. Jpn, 70, 2749–2756 (1997). https://doi.org/10.1246/bcsj.70.2749

130.    K. Kobayashi, T. Kato, M. Unno, and S. Masuda, Asymmetric Synthesis of Organosilicon Compounds Using a C₂ Chiral Auxiliary, Bull. Chem. Soc. Jpn, 70, 1393–1401 (1997). https://doi.org/10.1246/bcsj.70.1393

131.    M. Unno, Y. Kawai, H. Shioyama, and H. Matsumoto, Syntheses, Structures, and Properties of Tricyclo[5.1.1.1^3,5]tetrasilachalcogenanes (Thex₂Si₂E₂)₂E₂ (E = S, Se) and Tricyclo[5.1.1.1^3,5]tetragermachalcogenanes (Thex₂Ge₂E₂)₂E₂ (E = S, Se), Organometallics, 16, 4428–4434 (1997). https://doi.org/10.1021/om970432r

132.    M. Unno, H. Shioyama, and H. Matsumoto, Synthesis and Structures of Tetrasilsesquisulfides, Phosphorus, Sulfur, Silicon Relat. Elem., 120/121, 377–378 (1997). https://doi.org/10.1080/10426509708545556

133.    M. Unno, T. Yokota, and H. Matsumoto, Oxaoctasilahomocubane and Dioxaoctasilabishomocubane: Novel Silicon Ring System, J. Organomet. Chem., 521, 409–411 (1996). https://doi.org/10.1016/0022-328X(96)06421-2

134.    M. Unno, B. A. Shamsul, H. Saito, and H. Matsumoto, Synthesis of Hexasilsesquioxanes Bearing Bulky Substituents: Hexakis(1,1,2-trimethylpropylsilsesquioxane) and Hexakis(tert-butylsilsesquioxane), Organometallics, 15, 2413–2414 (1996). https://doi.org/10.1021/om950737a

135.    M. Unno, H. Shioyama, M. Ida, and H. Matsumoto, Reductive dehalogenation of 4,8-Dihalooctakis(1,1,2-trimethylpropyl)tetracyclo-[3.3.0.0^2,7.0^3,6]octasilanes with Sodium, Organometallics, 14, 4004–4009 (1995). https://doi.org/10.1021/om00008a054

136.    M. Unno, M. Saito, and H. Matsumoto, Synthesis, Structure, and Properties of Novel Aminodisilanes Bearing Bulky Substituents: 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane and 1,2-di-(tert-butyl)1,1,2,2-tetrakis(diethylamino)disilane, J. Organomet. Chem., 499, 221–228 (1995). https://doi.org/10.1016/0022-328X(95)00314-G

137.    M. Unno, K. Higuchi, M. Ida, H. Shioyama, S. Kyushin, M. Goto, and H. Matsumoto, Ring-Opening Reaction of Octakis(1,1,2-trimethylpropyl)octasilacubane, Organometallics, 13, 4633–4635 (1994). https://doi.org/10.1021/om00023a075

138.    B. Imperiali, K. L. Shannon, M. Unno, and K. W. Rickert, A Mechanistic Proposal for Asparagine-Linked Glycosylation, J. Am. Chem. Soc., 114, 7944–7945 (1992). https://doi.org/10.1021/ja00046a069

139.    L. T. Scott and M. Unno, Novel Heterocycles Comprising Alternating Phosphorus Atoms and Alkyne Units, J. Am. Chem. Soc., 112, 7823–7825 (1990). https://doi.org/10.1021/ja00177a069

140.    R. Okazaki, M. Unno, and N. Inamoto, Estimation of Bulkiness of a Highly Sterically Demanding 2,4,6-Tris[bis(trimethylsilyl)methyl]-phenyl Group, Chem. Lett., 18, 791–792 (1989). https://doi.org/10.1246/cl.1989.791

141.    R. Okazaki, M. Unno, G. Yamamoto, and N. Inamoto, A Conformational Study on Highly Crowded 1,3,5-Tris[bis(trimethylsilyl)methyl]benzene Derivatives. Chem. Lett. 18, 493–496 (1989). https://doi.org/10.1246/cl.1989.493

142.    R. Okazaki, M. Unno, and N. Inamoto, 2,4,6-Tris[bis(Trimethylsilyl)methyl]phenyl, a New Sterically Demanding Group for Kinetic Stabilization of Unstable Compounds, Chem. Lett., 16, 2293–2294 (1987). https://doi.org/10.1246/cl.1987.2293

143.    R. Okazaki, M. Unno, and N. Inamoto, A New synthesis of 1,3-thiazine derivatives bearing a dithiolane ring and their reductive cleavage with sodium cyanoborohydride, Heterocycles, 25, 183–190 (1987). https://doi.org/10.3987/S-1987-01-0183

 

[Review]

(1)   海野雅史・刘雨佳（分担）, シロキサンポリマーの性質とシランカップリング剤の反応, Material Stage, 24(13), 技術情報協会 (2025).

(2) 刘雨佳, 海野雅史, ヤヌス型シロキサン開発物語, 有機合成化学協会誌, 80, 12, 1126–1135 (2022). https://doi.org/10.5059/yukigoseikyokaishi.80.1126

(3) 海野雅史, 刘雨佳,  シランカップリング剤の歴史, New Glass, 37, 2, 7–10 (2022).

(4) 海野雅史, シランカプリング剤の基礎とメカニズム, 塗装工学, 57, 4, 138–145 (2022).

(1)   海野雅史, シランカップリング剤の加水分解と脱水縮合反応メカニズム, Material Stage, 19(6), 技術情報協会 (2019).

(5) 海野雅史, ヤヌスキューブ（ヤヌス分子）の合成と応用展開，ファインケミカル, 48, 3, 38–48 (2019). https://www.cmcbooks.co.jp/products/detail.php?product_id=5607

(6) 海野雅史，シランカップリング剤のメカニズムと将来展開，色材協会誌，88，5，143–147 (2015). https://doi.org/10.4011/shikizai.88.143

(7) M. Unno, A. Suto, and T. Matsumoto, "Laddersiloxanes— Silsesquioxanes with defined ladder structure", Russ. Chem. Rev., 82, 289–302 (2013). https://doi.org/10.1070/RC2013v082n04ABEH004360

(8) 海野雅史, 超分子から構造規制次世代材料まで—シラノールが築く新しい化学—, 有機合成化学協会誌, 69, 413–425 (2011). https://doi.org/10.5059/yukigoseikyokaishi.69.413

(9) 海野雅史,近未来材料のシルセスキオキサン, 化学, 65, 10, 68–69 (2010). https://www.kagakudojin.co.jp/book/b73488.html

(10) 海野雅史, ケイ素化合物の優れた結合能を利用した表面処理ならびに増感色素への応用, ファインケミカル, 39, 3, 5–12 (2010). https://www.cmcbooks.co.jp/products/detail.php?product_id=3528

(11) 海野雅史, 花屋実, ケイ素を利用した新規色素増感太陽電池の設計, ケミカルエンジニヤリング, 53, 9, 687–693 (2008). http://www.kako-sha.co.jp/2008contentschem.htm

(12) M. Unno, Laddersiloxanes: silsesquioxanes with defined ladder structure. Materials Research Society Symposium Proceedings 1007-S01-05 (2007),. https://doi.org/10.1557/PROC-1007-S01-05

(13) 海野雅史, シラノールの水素結合を利用したナノサイズ超分子の形成, ナノ学会会報, 5, 47–51 (2007). http://www.ac-square.co.jp/nano/journal_01.html

(14) M. Unno, K. Takada, Y. Kawaguchi, and H. Matsumoto, Supramolecular aggregates of silanols and solid-state synthesis of siloxanes, Mol. Cryst. Liq. Cryst., 440, 259–264 (2005). https://doi.org/10.1080/15421400590958584

(15) 海野雅史, 松本英之, オクタシラキュバンの化学, 有機合成化学協会誌, 62, 107–115 (2004). https://doi.org/10.5059/yukigoseikyokaishi.62.107

(16) K. Yamada, M. Unno, K. Kobayashi, H. Oku, H. Yamamura, H. Matsumoto, R. Katakai, and K. Masao, Stereochemistry of protected ornithine side chains of gramicidin S derivatives: X-ray crystal structure of N-methylated derivative of gramicidin, Peptide Science, 2002, 39th, 305–308 (2003).

(17) 海野雅史, フラーレン化学合成１２年の歩み〜L. T. Scott研究室, ケイ素化学協会誌, No.16, pp.12-15 (2002).

(18) H. Matsumoto, S. Kyushin, M. Unno, and R. Tanaka, Synthesis, Structures, and Properties of Ladder Oligosilanes and Ladder Oligogermanes, J. Organomet. Chem. 611, 52–63 (2000). https://doi.org/10.1016/S0022-328X(00)00299-0

(19) 海野雅史, 松本英之, ケイ素原子を持つ超分子,科学と工業 (大阪), 74, 489–494 (2000).

(20) 海野雅史, ヘテロ原子化学＋有機金属化学, ケイ素化学協会誌, No.12, pp.11-14 (2000).

(21) 海野雅史, Tbt基が生まれた頃−When Tbt was born, ケイ素化学協会誌, No.11, pp.45-46 (1999).

(22) 海野雅史, 松本英之, シルセスキオキサン類の化学−かご状化合物を中心に, ケイ素化学協会誌, No.8, pp.16-22 (1997).

 

［Books］

(1)      海野雅史, 刘雨佳（分担）, シランカップリング剤の加水分解、縮合反応による表面改質（第２章第１１節）“ぬれ性の制御と表面処理・改質技術, 技術情報協会 (2023). ISBN 978-4-86104-977-4

(2)   海野雅史（分担）, シランカップリング剤の最新技術動向（第６章第１節）次世代シランカップリング剤,シーエムシー出版，pp.216–223 (2020). ISBN 978-4-7813-1520-1

(3)   海野雅史（分担）, シランカップリング剤の使い方と応用事例（第９章第１節）シルセスキオキサンの種類・構造，合成方法,サイエンス&テクノロジー，pp.313–321 (2020). ISBN 978-4-86428-218-5

(4)   海野雅史（分担）, 添加剤の最適使用法（第８節　シランカップリング剤の種類，反応，使用方法），R&Dリサーチセンター，pp.129–135 (2020). ISBN 978-4-905507-42-0

(5)         M. Unno and H. Endo, “Silanols as Building Blocks for Nanomaterials” in Novel Nanoscale Hybrid Materials, Ed. Bhanu P. S. Chauhan, John Wiley & Sons, Inc., New York, pp. 1–31 (2018). https://doi.org/10.1002/9781119156253.ch1

(6)         M. Unno and R. Tanaka, “Silanols and Silsesquioxanes” in Efficient Methods for Preparing Silicon Compounds, Ed. H. W. Roesky, Academic Press, London, pp. 399–440 (2016). https://doi.org/10.1016/B978-0-12-803530-6.00032-9

(7)   シランカップリング剤の使いこなし ノウハウ集，　第１章「シランカップリング剤の反応メカニズム」，技術情報協会 (2016). ISBN 978-4-86104-610-0

(8)         M. Unno, "Substituted Polyhedral Silicon and Germanium Clusters", in Functional Molecular Silicon Compounds II, Ed. D. Scheschkewitz, Springer, Heidelberg, pp.49-84 (2014). https://doi.org/10.1007/430_2013_99

(9)   現代ケイ素化学（分担）,第２２章「シリコーンの応用」,吉良満夫,玉尾皓平編,化学同人 pp.349-360（2013）.

(10) シルセスキオキサン材料の化学と応用展開, 伊藤真樹監修, 第４章「かご型および精密合成ラダーシルセスキオキサン」, シーエムシー出版　pp. 37-48 (2013).

(11) 最強エレメント　ケイ素の不思議(分担) , 海野雅史編, 海野雅史他著, 上毛新聞社,pp.9-11, 19-21　(2011).

(12) シランカップリング剤の反応メカニズムと処理条件の最適化, 第１章「シランカップリング剤の基本的メカニズム」, 第５章「シランカップリング剤への新規機能性の付与」, 技術情報協会pp.1-20, 88-105 (2010).

(13) シルセスキオキサン材料の最新技術と応用, 伊藤真樹監修, 第４章「かご型および精密合成ラダーシルセスキオキサン」, シーエムシー出版　(2007).

(14) 新時代への視点　−群馬大学研究室から−(分担)，群馬大学地域連携推進室編，上毛新聞社，pp. 186-188 (2006).

(15)     M. Unno and H. Matsumoto, "Reactions of Octasilacubane", in Organosilicon Chemistry VI，Eds. N. Auner and J. Weis, WILEY-VCH Verlag, Weinheim, pp. 373–380 (2005). https://doi.org/10.1002/9783527618224.ch2c

(16) １０年使える有機スペクトル解析（分担），新津隆士，海野雅史，鍵裕之著，三共出版，第１章，第２章　(2005).

(17) ２１世紀の有機ケイ素化学—機能性物質科学の宝庫（分担），玉尾皓平監修，シーエムシー（2004）.

(18) プロフェショナル英和辞典スペッドテラ　物質・工学編（分担），堀内克明、蟹江幸博編，小学館 (2004).

(19) キラキラわくわく化学（分担）上毛新聞社，pp.50-53 (2003).

(20) 有機ケイ素材料科学の新展開 (分担)，櫻井英樹監修，シーエムシー，pp.146-156 (2001)

(21) 化合物の辞典 (分担), 稲本直樹ら編, 朝倉書店 (1998).

(22) 気軽に化学 (分担), 上毛新聞社，pp.168-169,172-173 (1996).

 

［Patents］

(1) 特願2016-232998、海野雅史、江川泰暢、島田茂、佐藤一彦、「反応性置換基を有するシルセスキオキサンの製造方法」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成28年11月30日.


(2) 特願2015-204578、海野雅史、江川泰暢、島田茂、佐藤一彦、「異なる置換基を対面に4つずつ有するかご型シルセスキオキサン」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成27年10月16日.

(3) 特開2014-093158、神谷正人、齋藤平、寺島純平、鳶島真一、森本英行、海野雅史、「リチウムイオン二次電池」、トヨタ自動車株式会社、国立大学法人群馬大学、平成26年5月19日.

(4) 特開2014-053097、神谷正人、齋藤平、鳶島真一、森本英行、海野雅史、「リチウム二次電池およびその製造方法」、国立大学法人群馬大学、トヨタ自動車株式会社、平成26年3月20日.

(5) 特願2014-76446、海野雅史、佐藤一彦、島田茂、五十嵐正安、「シロキサン化合物の製造方法」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成26年4月2日.

(6) 特開2013-241497、小熊武美、渡辺淳、海野雅史、「ポリシルセスキオキサン化合物、光素子封止材及びその用途」、国立大学法人群馬大学、電気化学工業株式会社、平成25年12月5日.

(7)     WO 2012137568, M. Hanaya, K. Kakiage, M. Unno, Y. Aoyama, T. Yano, D. Sawamoto, H. Osada, “Aromatic amines bearing hydrocarbyloxysilyl groups, supports containing supported them, and photoelectric converters”, Adeka Corporation, Oct. 11, 2012.

(8) WO 2012036010, M. Hanaya, K. Kakiage, M. Unno, T. Yano, K. Akimoto, K. Sakamaki, “Production of pyridine derivative additive for electrolytic composition of dye-​sensitized solar cell”, Adeka Corporation, Sep. 5, 2011.

(9) 特開2011-202057、海野雅史、小熊武美、村田弘、「ポリシルセスキオキサン化合物、光素子封止材及びその用途」、電化化学工業株式会社、国立大学法人群馬大学，平成22年3月26日．

(10) 特開2009-249455（特願2008-097235）、濱田光祥、永井晃、海野雅史、山村正樹、「封止用エポキシ樹脂成形材料及び電子部品装置」、日立化成工業株式会社、平成21年10月29日.

(11) 特開2009-249312（特願2008-097236）、濱田光祥、永井晃、加藤木茂樹、杜暁黎、海野雅史、「シラン化合物」、日立化成工業株式会社、平成21年10月29日.

(12) 特開2007-197723（特願2006-356289）、濱田光祥、永井晃、松本英之、海野雅史、「封止用エポキシ樹脂成形材料及び電子部品装置」、日立化成工業株式会社、平成19年8月9日.

(13) 特開2008-63390（特願2006-240428）、海野雅史，花屋実，「色素増感太陽電池用色素及びこの色素を用いた光電変換素子並びに色素増感太陽電池」，国立大学法人群馬大学，平成18年9月5日．

(14) 特開2006-016580（特願2004-198515）、濱田光祥、永井晃、松本英之、海野雅史、「接着剤組成物、それを用いたフィルム状接着剤及び回路接続材料、並びに回路部材の接続構造及びその製造方法」、日立化成工業株式会社、平成18年1月19日.

(15) 特開2006-016370（特願2004-198509）、佐藤和也、湯佐正己、小林隆伸、藤縄貢、塚越功、松本英之、海野雅史、「シラン化合物」、日立化成工業株式会社、平成18年1月19日.

(16) 特開2006-016369（特願2004-198508）、佐藤和也、湯佐正己、小林隆伸、藤縄貢、塚越功、松本英之、海野雅史、「シラン化合物の製造方法及びシラン化合物」、日立化成工業株式会社、平成18年1月19日.

(17) 特開2004-315428（特願2003-111608）、松本英之、海野雅史、田中陵二、「ハロゲン化アリール置換環状テトラシロキサンの製法」、独立行政法人 科学技術振興機構、2004年11月11日.

 

新聞発表等

1) 新物質「ヤヌスキューブ」群馬大大学院が新合成法, 日本経済新聞, 2016/05/28.

2) 群馬大が新合成法　新物質「ヤヌスキューブ」, 日本経済新聞, 電子版, 2016/05/28.

3) エコタイヤの性能向上　化合物の合成法開発,  産経新聞, 2016/05/28.

4) エコタイヤの性能向上に期待　群大院が「ヤヌスキューブ」合成, 産経新聞電子版, 2016/05/28.

5) エコタイヤの性能向上に期待　群大院が「ヤヌスキューブ」合成法開発, Yahooニュース, 2016/05/28.

6) ヤヌスキューブ簡便合成法　産総研群馬大　有機ケイ素部材に有用, 化学工業日報, 2016/05/30.

7) ヤヌスキューブの簡易合成法を発見　エコタイヤ性能向上期待,    上毛新聞, 2016/05/30.

8) ヤヌスキューブ効率的に合成 群馬大と産総研, 日刊工業新聞, 2016/06/02.

9) ヤヌスキューブ　簡便な合成法開発　詳細な分子構造も解明, 桐生タイムス, 2016/06/02.

10)   「究極のエコタイヤ」へ新手法　ヤヌスキューブ材料の化合物合成効率化, 読売新聞, 2016/06/03

11)   ヤヌスの立方体, 有機化学美術館・分館, 2016/06/06.

12)   カゴ型シルセスキオキサン「ヤヌスキューブ」合成と構造決定, Chem-Stationスポットライトサーチ, 2016/06/10.

13)   ヤヌスキューブ合成     科学新聞社電子版, 2016/06/17.