(1)    Z. Zheng, Y. Liu, N. Takeda, M. Unno, Synthesis and Characterization of Sulfide/Sulfone-Containing 18- 8-18-Membered-Ring Ladder-Type Siloxanes, Dalton Trans., in press (2023).

(2)    Q. Wang, M. Unno, H. Liu, Dual-Function Near-Infrared Emitting Aerogel-Based Device for Detection and Sunlight-Driven Photodegradation of Antibiotics: Realizing the Processability of Silsesquioxane-Based Fluorescent Porous Materials, Adv. Funct. Mater., 2214875 (2023).

(3)    Q. Wang, M. Unno, H. Liu, OrganicInorganic Hybrid Near- Infrared Emitting Porous Polymer for Detection and Photo-degradation of Antibiotics. ACS Sustainable Chem. Eng., 10, 73097320 (2022).

(4)    M. Laird, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Thiolated Janus silsesquioxane tetrapod: new precursors for functional materials, Molecules, 27, 7680 (2022).

(5)    T. Chaiprasert, S. Chanmungkalakul, Y. Liu, T. Bureerug, K. Silpcharu, M. Unno, L. Xiaogang, V. Ervithayasuporn, Y.-T. Chang, P. Rashatasakhon, Fluorescent Janus ring siloxanes for detection of Au(III) and l-cysteine, Dyes Pigm., 208, 110793 (2022).

(6)    Y. Liu, T. Chaiprasert, A. Ouali, M. Unno, Well-defined cyclic silanol derivatives, Dalton Trans., 51, 4227-4245 (2022).

(7)    Y. Liu, K. Koizumi, N. Takeda, M. Unno, A. Ouali, Synthesis of octachloro and octaazido-functionalized T8 cages and applications to recyclable palladium catalyst, Inorg. Chem., 61, 1495-1503 (2022).

(8)    Y. Liu, M. Katano, P. Yingsukkamol, N. Takeda, M. Unno, A. Ouali, Tricyclic 6-8-6 laddersiloxanes derived from all-cis-tetravinylcyclotetrasiloxanolate: Synthesis, characterization and reactivity, J. Organomet. Chem., 959, 122213 (2022).

(9)    Y. Egawa, C. Kobuna, N. Takeda, M. Unno, Synthesis of Janus cube containing Si–H moieties, Mendeleev Commun., 32, 35–36 (2022). 

(10) Y. Liu, A, Endo, P. Zhang, A. Takizawa, N. Takeda, A. Ouali, M. Unno, Synthesis, Characterization, and Reaction of Divinyl-substituted Laddersiloxanes, Silicon, 14, 2723-2730 (2022). IF = 2.67

(11) Y. Liu, M. Kigure, R. Okawa, N. Takeda, M. Unno, A. Ouali, Synthesis and characterization of tetrathiol-substituted double-decker or ladder silsesquioxane nano-cores, Dalton Trans., 50, 3473–3478 (2021).

(12) M. Laird, C. Totée, P. Gaveau, G. Silly, A. Van der Lee, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Functionalised polyhedral oligomeric silsesquioxane with encapsulated fluoride – first observation of fluxional SiF interactions in POSS, Dalton Trans., 50, 81–89 (2021). IF=4.17

(13) Q. Wang, M. Unno, H. Liu, Silsesquioxane-Based Triphenylamine-Linked Fluorescent Porous Polymer for Dyes Adsorption and Nitro-Aromatics Detection, Materials, 14, 3851 (2021). IF=3.26

(14) T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Vinyl-Functionalized Janus Ring Siloxane: Potential Precursors to Hybrid Functional Materials, Materials,14, 2014 (2021). IF=3.26

(15) J. Guan, Z. Sun, R. Ansari, Y. Liu, A. Endo, M. Unno, A. Ouali, S. Mahbub, J. C. Furgal, N. Yodsin, S. Jungsuttiwong, D. Hashemi, J. Kieffer, and R. M. Laine, Conjugated Copolymers That Shouldn’t Be, Angew. Chem. Int. Ed. 60, 11115–11119 (2021). IF=12.96

(16) M. Laird, P. Gaveau, P. Trens, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Post-synthesis modification of functionalised polyhedral oligomeric silsesquioxanes with encapsulated fluoride – enhancing reactivity of T8-F POSS for materials synthesis, New J. Chem., 45, 4227–4235 (2021). IF = 3.29

(17) T. Chaiprasert, Y. Liu, P. Intaraprecha, R. Kunthom, N. Takeda, M. Unno, Synthesis of tricyclic laddersiloxane with various ring sizes (Bat siloxane), Macromol. Rapid Commun., 42, 2000608 (2021). IF = 4.89

(18) M. Laird, N. Herrmann, N. Ramsahye, C. Totée, C. Carcel, M. Unno, J. Bartlett, M. Wong Chi Man, Large polyhedral oligomeric silsesquioxane cages – the isolation of functionalized POSS with an unprecedented Si18O27 core, Angew. Chem. Int. Ed., 60, 3022–3027 (2021). IF=12.96

(19) M. Laird, J. Yokoyama, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Sol–gel processing of polyhedral oligomeric silsesquioxanes: nanohybrid materials incorporating T8 and T10 cages, J. Sol-Gel Sci. Tech., 95, 760–770 (2020). IF = 2.33

(20) T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Janus ring siloxane: a versatile precursor of the extended Janus ring and tricyclic laddersiloxanes, Dalton Trans., 49, 13533–13537 (2020). IF = 4.17

(21) Y. Liu, M. Kigure, K. Koizumi, N. Takeda, M. Unno, A. Ouali, Synthesis of Tetrachloro, Tetraiodo, and Tetraazido Double-Decker Siloxanes, Inorg. Chem., 59, 15478–15486 (2020). If = 4.83

(22) M. Laird, A. van der Lee, D. Dumitrescu, C. Carcel, A. Ouali, J. Bartlett, M. Unno, M. Wong Chi Man, Styryl Functionalized Cage Silsesquioxanes as Nano Blocks for 3-D Assembly, Organometallics, 39, 1896–1906 (2020). IF = 3.80

(23) Y. Du, M. Unno, H. Liu, Hybrid Nanoporous Materials Derived from Ladder- and Cage-Type Silsesquioxanes for Water Treatment, ACS Appl. Nano Mater., 3, 1535–1541 (2020). IF = 3.94

(24) Y. Liu, K. Onodera, N. Takeda, A. Ouali, M. Unno, Synthesis and Characterization of Functionalizable Silsesquioxanes with Ladder-type Structures, Organometallics, 38, 4173–4176 (2019).  IF = 3.80

(25) N. Prigyai, S. Chanmungkalakul, V. Ervithayasuporn, N. Yodsin, S. Jungsuttiwong, N. Takeda, M. Unno, J. Boonmak, S. Kiatkamjornwong, Lithium-Templated Formation of Polyhedral Oligomeric Silsesquioxanes (POSS), Inorg. Chem. 58, 15110–15117 (2019). If = 4.83

(26) R. Kunthom, T. Adachi, Y. Liu, N. Takeda, M. Unno, R. Tanaka, Synthesis of a "Butterfly Cage" Based on a Double-Decker Silsesquioxane, Chem. Asian J., 14, 4179–4182 (2019). IF = 4.06

(27) R. Kunthom, N. Takeda, M. Unno, Synthesis and Characterization of Unsymmetrical Double-decker Siloxane (Basket Cage), Molecules, 24, 4252 (2019). IF = 3.31

(28) Y. Liu, N. Takeda, A. Ouali, M. Unno, Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes, Inorg. Chem., 58, 4093–4098 (2019). If = 4.83

(29) T. Tanaka, Y. Hasegawa, T. Kawamori, R. Kunthom, N. Takeda, M. Unno, Synthesis of Double-Decker Silsesquioxanes from Substituted Difluorosilane, Organometallics, 38, 743-747 (2019). IF = 3.80

(30) S. Kondo, Y. Nakadai, M. Unno, Recognition of dicarboxylates in aqueous acetonitrile by a dinuclear zinc(II) complex of 2,2'-binaphthalene-based receptor, Supramolecular Chem., 31, 9–18 (2019). IF = 1.35

(31) T. Uchida, Y. Egawa, T. Adachi, N. Oguri, M. Kobayashi, T. Kudo, N. Takeda, M. Unno, R. Tanaka, Synthesis, Structures, and Thermal Properties of Symmetric and Janus “Lantern Cage” Siloxanes, Chem. Eur. J., 25, 1683 –1686 (2019). IF = 4.86

(32) H. Endo, N. Taked M. Unno, Single-step synthesis of disiloxanetetraols, J. Sol-Gel Sci. Technol., 89, 37–44 (2019).  IF = 2.33

(33) C. Weetman, N. Ito, M. Unno, F. Hanusch, S. Inoue, NHI- and NHC-Supported Al(III) Hydrides for Amine–Borane Dehydrocoupling Catalysis, Inorganics, 7, 92 (2019).                    

(34) Y. Egawa, C. Fukumoto, K. Mikami, N. Takeda, M. Unno, Synthesis and Characterizations of 
The Germathioacid chloride Coordinated by an N-Heterocyclic carbene, Inorganics, 6, 76 (2018). IF = 2.15

(35) H. Endo, N. Takeda, M. Unno, Stereoisomerization of Cyclic Silanols, Chem. Asian J., 12, 1224–1233 (2017). IF = 4.06

(36) N. Oguri, Y. Egawa, Y. Kawakami, C. Kobuna, N. Takeda, M. Unno, Unusual Reactions of Cyclic Fluorosiloxanes, ChemistrySelect, 2, 2300–2304 (2017). IF = 2.00

(37) Y. Egawa, S. Murakami, N. Takeda, and M. Unno, Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New Building Block for Materials, Chem. Lett., 45, 738–739 (2016). IF = 1.36

(38) N. Oguri, Y. Egawa, N. Takeda, and M. Unno, Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure Elucidation, Angew. Chem. Int. Ed. 55, 9336-9339 (2016). IF=12.96

(39) N. Takeda, Y. Tanaka, R. Oma, F. Sakakibara, M. Unno, Activation of C–S Bond by Group 10 Metal Complexes: Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl Groups with Group 10 Metal Compounds, Bull. Chem. Soc. Jpn., 89, 922-930 (2016). IF = 4.49

(40) S. Murakami, Y. Egawa, C. Kuramochi, N. Takeda, and M. Unno, Cyclic Silanols with Long Alkyl Chains, Chem. Lett., 45, 309–311 (2016).

(41)  K. Kakiage, T. Abe, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Effect of the introduction of a CF3 group to a silyl-anchor azobenzene dye on sensitization property in dye-sensitized solar cells, Key Eng. Mater., 698, 27–31 (2016).

(42) N. Oguri, N. Takeda, and M. Unno, Facile Synthesis of Cyclic Fluorosiloxanes, Chem. Lett., 44, 1506–1508 (2015).

(43) H. Endo, and N. Takeda, M. Takanashi, T. Imai, and M. Unno, Refractive Indices of Silsesquioxanes with Various Structures, Silicon, 7, 127–32 (2015).

(44) M. Unno, H. Endo, and N. Takeda, Synthesis and Structures of Extended Cyclic Siloxanes, Heteroatom Chem25, 525–532 (2014).

(45) N. Takeda, T. Tagawa, and M. Unno, Synthesis, Reactivities, and Coordination Chemistry of Tris(2-​isopropoxyphenyl)​phosphine, Heteroatom Chem25, 628–635 (2014).

(46) K. Kakiage, Y. Aoyama, T. Yano, T. Otsuka, T. Kyomen, M. Unno, and M. Hanaya, An achievement of over 12 percent efficiency in an organic dye-​sensitized solar cell, Chem. Commun., 50, 6379–6381 (2014).

(47) H. Endo, N. Takeda, and M. Unno, Synthesis and Properties of Phenylsilsesquioxanes with Ladder and Double-​Decker Structures, Organometallics, 33, 4148-4151 (2014).

(48) R. Yanagisawa, H. Endo, M. Unno, H. Morimoto, S. Tobishima, Effects of organic silicon compounds as additives on charge-​discharge cycling efficiencies of lithium in nonaqueous electrolytes for rechargeable lithium cells, J. Power Sources266, 232–240 (2014).

(49) S. Kondo, Y. Nakadai, and M. Unno, Pyrophosphate selective recognition by a Zn2+ complex of a 2,20-binaphthalene derivative bearing di(2-pyridylmethyl)aminomethyl groups in aqueous solution, RSC Adv., 4, 27140–27145 (2014).

(50) K. Kakiage, Y. Aoyama, M. Yamamura, T. Yano, M. Unno, T. Kyomen, and M. Hanaya, A Novel Alkoxysilyl Azobenzene Dye Photosensitizer with Alkylamino Group for Dye-Sensitized Solar Cells, Silicon, 6, 123–127 (2014).

(51) M. Yamamura, S. Kondo, and M. Unno, Ion Pair Recognition of Ditopic Receptor Bearing Silanol Groups as Anion Recognition Sites and a 2,2'-Bipyridine Moiety as a Metal-coordination Site, Tetrahedron Lett., 55, 646–649 (2014).

(52) S. Kondo, N. Watanabe, F. Takahashi, N. Takeda, and M. Unno, Synthesis and photophysical properties of 2,2’-binaphthalene-based receptor bearing trimethylsilyl groups to improve the solubility, J. Incl. Phenom. Macrocycl. Chem., 75, 31-38 (2013).

(53) H. Endo and M. Unno, Effective Synthesis and Isomerization of Cyclotetrasiloxanetetraol, Key Eng. Mater., 534, 66–70 (2013).

(54) K. Kakiage, C. Saito, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Study of the Chemical Adsorption Property of Allylsilylazobenzene in the Surface Modification of Nano-Porous Alumina Membrane, Key Eng. Mater., 534, 46–52 (2013).

(55) M. Unno, T. Matsumoto, H. Matsumoto, Nonacyclic Ladder Silsesquioxanes and Spectral Features of Ladder Polysilsesquioxanes, Int. J. Polym. Sci., 723892 (2012).

(56) K. Kakiage, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Adsorption and Sensitizing Properties of Azobenzenes Having Different Numbers of Silyl-anchor Groups in Dye-sensitized Solar Cells, Key Eng. Mater., 497, 61–66 (2012).

(57) K. Kakiage, T. Tsukahara, T. Kyomen, M. Unno, and M. Hanaya, Significant Improvement of Photovoltaic Performance of Dye-sensitized Solar Cells by Using 4-Trimethylsilylpyridine as Organic Additive to Electrolyte Solution, Chem. Lett., 41, 895-896 (2012).

(58) (Selected Paper) S. Kondo, S. Nakajima, and M. Unno, Ratiometric Fluorescence Detection of Anions by an Amide-Based Receptor Bearing Pyrenyl Groups, Bull. Chem. Soc. Jpn., 85, 698-700 (2012).

(59) S. Kondo, H. Sonoda, T. Katsu, and M. Unno, Improvement of solubility of 2,2-binaphthalene derivatives bearing urea groups as anion receptors and their application to a chloride selective electrode, Sensors and Actuators B, 160, 684–690 (2011).

(60) V. Ervithayasuporn, T. Tomeechai, N. Takeda, M. Unno, A. Chaiyanurakkul, R. Hamkool, and T. Osotchan, Synthesis and Characterization of Octakis(3-propyl ethanethioate)octasilsesquioxane, Organometallics, 30, 4475–4478 (2011).

(61) M. Unno, N. Yamashita, and H. Matsumoto, Thermal Reaction of Octasilacubane with Sulfur, Selenium, and Tellurium: Formation of Novel Cage Systems, Phosphorus, Sulfur, Silicon Relat. Elem., 186, 1259–1262 (2011).

(62) Y. Egawa and M. Unno, Solvent-free Synthesis of Functional Siloxanes Bearing 4-Trifluoromethylphenyl Group, Key Eng. Mater., 497, 51–54 (2011).

(63) K. Kakiage, M. Yamamura, E. Ido, T. Kyomen, M. Unno, and M. Hanaya, Reactivity of Alkoxysilyl Compounds: Chemical Surface Modification of Nano-porous Alumina Membrane Using Alkoxysilylazobenzenes, Appl. Organomet. Chem., 25, 98–104 (2011).

(64) S. Kondo, T. Takahashi, Y. Takiguchi, and M. Unno, Synthesis and photophysical properties of a 2,2’-bianthracene-based receptor bearing two aza-15-crown-5 ethers for naked-eye detection of barium ion, Tetrahedron Lett., 52, 453–457 (2011).

(65) S. Kondo, M. Nagamine, S. Karasawa, M. Ishihara, M. Unno, and Y. Yano, Anion recognition by 2,2’-binaphthalene derivatives bearing urea and thiourea groups at 8- and 8’-positions by UV-vis and fluorescence spectroscopies, Tetrahedron, 67, 943-950 (2011).

(66) N. Takeda, T. Nakamura, A. Imamura, and M. Unno, Synthesis and reactivities of dihydrosilanes tethered with two thioether moieties, Heteroatom Chem22, 438–445 (2011).

(67) M. Unno, R. Tanaka, D. Obinata, M. Endo, T. Sakurai, S. Ojima, T. Katayama, K. Fugami, Solvent-​free synthesis of siloxanes and their usage as potential cross-​coupling reagents, Key Eng. Mater., 459, 43–47 (2011).

(68) R. Tanaka, S. Kowase, and M. Unno, Chiral Cyclotrisiloxanes, Dalton Trans., 39, 9235–9237 (2010).

(69) N. Takeda, D. Watanabe, T. Nakamura, and M. Unno, Synthesis and Complexation of New Tripodal Tetradentate Ligand, Silyl Ligand Tethered with Three Thioether Moieties, Organometallics, 29, 2839-2841 (2010).

(70) S. Kondo, Y. Kobayashi, and M. Unno, Anion Recognition by D-Ribose-based Receptors, Tetrahedron Lett., 51, 2512–2514 (2010).

(71) M. Unno, R. Tanaka, D. Obinata, M. Endo, T. Sakurai, S. Ojima, T. Katayama, and K. Fugami, Solvent-free Synthesis of Siloxanes and Their Usage as Potential Cross-Coupling Reagents, Key. Eng. Mater., 459, 43–47 (2010).

(72) N. Takeda, Y. Tanaka, F. Sakakibara, and M. Unno, Synthesis and Structure of Group 10 Metal Complexes with New Tripodal Tetradentate Ligand Bearing One Phosphine and Three Thioether Moieties, Bull. Chem. Soc. Jpn., 83, 157–164 (2010).

(73) K. Kakiage, M. Yamamura, E. Fujimura, T. Kyomen, M. Unno and M. Hanaya, High Performance of Si–OTi Bonds for Anchoring Sensitizing Dyes on TiO2 Electrodes in Dye-sensitized Solar Cells Evidenced by Using Alkoxysilylazobenzenes, Chem. Lett., 39, 260–262 (2010).

(74) K. Kakiage, T. Kyomen, M. Unno, and M. Hanaya, Molecular-selective Adsorption Property of Chemically Surface Modified Nanoporous Alumina Membrane by Di(1-naphthyl)silanediol to Anthracenes, Appl. Organomet. Chem., 24, 198–200 (2010).

(75) S. Chang, T. Matsumoto, H. Matsumoto, and M. Unno, Synthesis and Characterization of Heptacyclic Laddersiloxanes and Ladder Polysilsesquioxane, Appl. Organomet. Chem., 24, 241–246 (2010).

(76) M. Unno, K. Kakiage, M. Yamamura, T. Kogure, T. Kyomen, and M. Hanaya, Silanol Dyes for Solar Cells: Higher Efficiency and Significant Durability, Appl. Organomet. Chem., 24, 247–250 (2010).

(77) K. Kakiage, T. Kyomen, M. Unno, and M. Hanaya, The Chemical Adsorption Properties of Silanol to Metal-Oxide Surface Studied by Using Di(1-naphthyl)silanediol and Nano-porous Alumina Membranes, Silicon, 1, 191–197 (2009).

(78) S. Kondo, N. Okada, R. Tanaka, M. Yamamura, and M. Unno, Anion Recognition by 1,3-Disiloxane-1,1,3,3-tetraols in Organic Solvents, Tetrahedron Lett., 50, 2754–2757 (2009).

(79) H. Liu, S. Kondo, N. Takeda, and M. Unno, An Efficient Approach to Monophenyl-Functionalized Octasilsesquioxanes, Eur. J. Inorg. Chem., 5, 1317-1319 (2009).

(80) H. Liu, S. Kondo, N. Takeda, and M. Unno, Synthesis of Octacarboxy Spherosilicate, J. Am. Chem. Soc., 130, 10074–10075 (2008).

(81) K. Kakiage, Y. Nakada, T. Kogure, M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Applicability of Silanol to Sensitizing Dye for Dye-sensitized Solar Cell, Silicon Chem., 3, 303–305 (2008).

(82) H. Liu, S. Kondo, R. Tanaka, H. Oku, and M. Unno, A spectroscopic investigation of incompletely condensed polyhedral oligomeric silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol): Hydrogen-bonded interaction and host–guest complex, J. Organomet. Chem., 693 1301–1308 (2008).

(83) 金澤貴之,味澤俊介,海野雅史,上田浩,"遠隔通信技術を 活用した聴覚障害学生支援―キャンパス間連携入力方式の導入事例から―",メディ ア教育研究 (Journal of Multimedia Aided Education Research), 5, 55-61 (2008).

(84) S. Kondo, A. Fukuda, T. Yamamura, R. Tanaka, and M. Unno, Anion Recognition by a Disiloxane-1,3-diol in Organic Solvents, Tetrahedron. Lett., 48, 7946–7949 (2007).

(85) S. Kondo, T. Hayashi, Y. Sakuno, Y. Takezawa, T. Yokoyama, M. Unno, and Y. Yano, Synthesis of cyclic bis- and Trismelamine Derivatives and Their Complexation properties with Barbiturates, Org. Biomol. Chem., 5, 907–916 (2007).

(86) M. Endo, T. Sakurai, S. Ojima, T. Katayama, M. Unno, H. Matsumoto, S. Kowase, H. Sano, M. Kosugi, and K. Fugami, Novel Pd-Catalyzed Atom-Efficient Cross-Coupling Reaction by Means of Hexaarylcyclotrisiloxane, SynLett, 5, 749-752 (2007).

(87) M. Unno, T. Matsumoto, and H. Matsumoto, Synthesis of Laddersiloxanes by Novel Stereocontrolled Approach, J. Organomet. Chem., 692, 307–312 (2007).

(88) S. Kondo, T. Harada, R. Tanaka, and M. Unno, Anion Recognition by a Silanediol-Based Receptor, Org. Lett., 8, 4621–4624 (2006).

(89) M. Unno, H. Murakami, S. Kagawa and H. Matsumoto, Borderline of Hydrogen Bonding by Silanols, Silicon Chem., 3, 195–198 (2005).

(90) M. Hirotsu, S. Taruno, T. Yoshimura, K. Ueno, M. Unno, and H. Matsumoto, Synthesis and Structures of the First Titanium(IV) Complexes with Cyclic Tetrasiloxide Ligands: Incomplete and Complete Cage Titanosiloxanes, Chem. Lett., 34, 1542–1543 (2005).

(91) M. Unno, S. Chang, and H. Matsumoto, cis-trans-cis-Tetrabromotetramethylcyclotetrasiloxane: a Versatile Precursor of Ladder Silsesquioxanes, Bull. Chem. Soc. Jpn., 78, 1105–1109 (2005).

(92) M. Unno, R. Tanaka, S. Tanaka, T. Takeuchi, S. Kyushin, and H. Matsumoto, Oligocyclic Laddersiloxanes: Alternative Synthesis by Oxidation, Organometallics, 24, 765–768 (2005).

(93) M. Unno, Y. Kawaguchi, Y. Kishimoto, and H. Matsumoto, Stereoisomers of 1,3,5,7-Tetrahydroxy-1,3,5,7-tetaisopropylcyclotetrasiloxane: Synthesis and Structures in the Crystal, J. Am. Chem. Soc., 127, 2256–2263 (2005).

(94) T. Okutsu, K. Isomura, N. Kakinuma, H. Horiuchi, M. Unno, H. Matsumoto, and H. Hiratsuka, Laser-induced morphology control and liquid phase epitaxy of dipara-anthracene produced from photochemical reaction of anthracene, Cryst. Growth Des., 5, 461–465 (2005).

(95) M. Unno, Y. Kishimoto, and H. Matsumoto, Triisopropylcyclotrisiloxanetriol: An Unprecedented Cyclic Siloxanetriol with Relatively Small Substituents, Organometallics, 23, 6221–6224 (2004).

(96) K. Negishi, M. Unno, and H. Matsumoto, The Cyclo[(disilanylene)(butadiyne)]s [(i-Pr)2Si(i-Pr)2SiCºCCºC]n (n = 2–4), Chem. Lett., 33, 430–431 (2004).

(97) M. Unno, Y. Imai, and H. Matsumoto, Hexakis(2,4,6-triisopropylphenylsilsesquioxane), Silicon Chem., 2, 175–178 (2003).

(98) M. Unno, T. Tanaka, and H. Matsumoto, Tip-substituted Cage and Cyclic Silanols, J. Organomet. Chem., 686, 175–182 (2003).

(99) M. Unno, T. Matsumoto, K. Mochizuki, K. Higuchi, M. Goto, and H. Matsumoto, Structure and Oxidation of Octakis(tert-butyldimethylsilyl)octasilacubane, J. Organomet. Chem., 685, 156–161 (2003).

(100)        M. Unno, H. Masuda, and H. Matsumoto, Photo-initiated Bromination of Octakis(1,1,2-trimethylpropyl)octasilacubane with Tetrabromomethane, Silicon Chem., 1, 377–381 (2002).

(101)        K. Yamada, M. Unno, K. Kobayashi, H. Oku, H. Yamamura, S. Araki, H. Matsumoto, R. Katakai, and M. Kawai, Stereochemistry of Protected Ornithine Side Chains of Gramicidin S Derivatives: X-ray Crystal Structure of the Bis-Boc-tetra-N-methyl Derivatives of Gramicidin S, J. Am. Chem. Soc., 124, 12684–12688 (2002).

(102)     R. Tanaka, S. Kyushin, M. Unno, and H. Matsumoto, Chiral crystallization of anti-dodecaisopropyltricyclo[,5]octasilane, Enantiomer, 7, 157–159 (2002).

(103)        M. Unno, A. Suto, and H. Matsumoto, Pentacyclic Laddersiloxane, J. Am. Chem. Soc., 124, 1574–1575 (2002).

(104)        M. Unno, Y. Kawai, and H. Matsumoto, Synthesis and Crystal Structures of 2,4,6-Tri-tert-butylphenyltrichlorogermane and 2,4,6-Tri-tert-butylphenylgermane, Heteroatom Chem., 12, 238–243 (2001).

(105)        M. Unno, T. Saito, and H. Matsumoto, Synthesis and Crystal Structures of Silapericyclynes, Bull. Chem. Soc. Jpn., 74, 2407–2413 (2001).

(106)        M. Unno, K. Negishi, and H. Matsumoto, Extended Silapericyclynes, Chem. Lett., 30, 340–341 (2001).

(107)        M. Unno, K. Higuchi, K. Furuya, H. Shioyama, S. Kyushin, M. Goto, and H. Matsumoto, Synthesis, Structure, and Reactions of Octakis(1,1,2-trimethylpropyl)octagermacubane, Bull. Chem. Soc. Jpn., 73, 2093–2097 (2000).

(108)     S. Kyushin, A. Meguro, M. Unno, and H. Matsumoto, Photolysis of anti-Dodecaalkyltricyclo[,5]octasilane: Generation and Reactions of Cyclotetrasilene, Chem. Lett., 29, 494–495 (2000).

(109)     H. Horiuchi, Y. Nakano, T. Matsumoto, M. Unno, H. Matsumoto, and H. Hiratsuka, Electronic Structure and Photochemical Reaction Intermediates of Octakis(1,1,2-trimethylpropyl)octasilacubane, Chem. Phys. Lett., 322, 33–40 (2000).

(110)     M. Unno, K. Takada, and H. Matsumoto, Formation of Supramolecule by Assembling of Two Different Silanols, Chem. Lett., 29, 242–243 (2000).

(111)     M. Unno, A. Suto, K. Takada, and H. Matsumoto, Synthesis of Ladder and Cage Silsesquioxanes from 1,2,3,4-Tetrahydroxycyclotetrasiloxane, Bull. Chem. Soc. Jpn., 73, 215–220 (2000).

(112)     M. Unno, D. Ishii, and H. Matsumoto, Kinetic Study of Thermal Isomerization of the “Double-decker”-type Sesquichalcogenides, (Thex2M2E2)2E2 (M=Si, Ge; E=S, Se), Bull. Chem. Soc. Jpn, 72, 2469–2473 (1999).

(113)     M. Unno, T. Saito, and H. Matsumoto, Silapericyclyne, (Ph2SiCºC)6: Spontaneous Conformational Resolution of Boat- and Chair-'Exploded' Cyclohexane, Chem. Lett., 28, 1235–1236 (1999).

(114)     R. Tanaka, M. Unno, and H. Matsumoto, Synthesis and Molecular Structures of Novel Isopropyl-substituted Oligosilanes, Chem. Lett., 28, 595–596 (1999).

(115)     M. Unno, R. Tanaka, S. Kyushin, and H. Matsumoto, Synthesis and Reactions of Hepta-t-butylcyclotetragermane, Phosphorus, Sulfur, Silicon Relat. Elem., 150/151, 167–176 (1999).

(116)     M. Unno, B. A. Shamsul, M. Arai, K. Takada, R. Tanaka and H. Matsumoto, Synthesis and Characterization of Cage and Bicyclic Silsesquioxanes via Dehydration of Silanols, Appl. Organomet. Chem., 13, 303-310 (1999).

(117)     M. Unno, K. Takada, and H. Matsumoto, Synthesis, Structure, and Reaction of the Tetrahydroxycyclotetrasiloxane [(i-Pr)(OH)SiO]4, Chem. Lett., 27, 489–490 (1998).

(118)     M. Unno, H. Masuda, and H. Matsumoto, 1,2,3-Triphenyl-1,2,3-trithexylcyclotrisilanes: Synthesis and Ring-Opening by Halogens, Bull. Chem. Soc. Jpn, 70, 2449–2458 (1997).

(119)     M. Unno, R. Tanaka, T. Kuribara, M. Saito, and H. Matsumoto, Synthesis, Structures, and Reactions of 1,2,3-Tris(diethylamino)-1,2,3,4-tetrakis-(1,1,2-trimethylpropyl)cyclotetrasilanes, Bull. Chem. Soc. Jpn, 70, 2749–2756 (1997).

(120)     K. Kobayashi, T. Kato, M. Unno, and S. Masuda, Asymmetric Synthesis of Organosilicon Compounds Using a C2 Chiral Auxiliary, Bull. Chem. Soc. Jpn, 70, 1393–1401 (1997).

(121)     M. Unno, Y. Kawai, H. Shioyama, and H. Matsumoto, Syntheses, Structures, and Properties of Tricyclo[,5]tetrasilachalcogenanes (Thex2Si2E2)2E2 (E = S, Se) and Tricyclo[,5]tetragermachalcogenanes (Thex2Ge2E2)2E2 (E = S, Se), Organometallics, 16, 4428–4434 (1997).

(122)     M. Unno, H. Shioyama, and H. Matsumoto, Synthesis and Structures of Tetrasilsesquisulfides, Phosphorus, Sulfur, Silicon Relat. Elem., 120/121, 377–378 (1997).

(123)     M. Unno, T. Yokota, and H. Matsumoto, Oxaoctasilahomocubane and Dioxaoctasilabishomocubane: Novel Silicon Ring System, J. Organomet. Chem., 521, 409–411 (1996).

(124)     M. Unno, B. A. Shamsul, H. Saito, and H. Matsumoto, Synthesis of Hexasilsesquioxanes Bearing Bulky Substituents: Hexakis(1,1,2-trimethylpropylsilsesquioxane) and Hexakis(tert-butylsilsesquioxane), Organometallics, 15, 2413–2414 (1996).

(125)     M. Unno, H. Shioyama, M. Ida, and H. Matsumoto, Reductive dehalogenation of 4,8-Dihalooctakis(1,1,2-trimethylpropyl)tetracyclo-[,7.03,6]octasilanes with Sodium, Organometallics, 14, 4004–4009 (1995).

(126)     M. Unno, M. Saito, and H. Matsumoto, Synthesis, Structure, and Properties of Novel Aminodisilanes Bearing Bulky Substituents: 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane and 1,2-di-(tert-butyl)1,1,2,2-tetrakis(diethylamino)disilane, J. Organomet. Chem., 499, 221–228 (1995).

(127)     M. Unno, K. Higuchi, M. Ida, H. Shioyama, S. Kyushin, M. Goto, and H. Matsumoto, Ring-Opening Reaction of Octakis(1,1,2-trimethylpropyl)octasilacubane, Organometallics, 13, 4633–4635 (1994).

(128)     B. Imperiali, K. L. Shannon, M. Unno, and K. W. Rickert, A Mechanistic Proposal for Asparagine-Linked Glycosylation, J. Am. Chem. Soc., 114, 7944–7945 (1992).

(129)     L. T. Scott and M. Unno, Novel Heterocycles Comprising Alternating Phosphorus Atoms and Alkyne Units, J. Am. Chem. Soc., 112, 7823–7825 (1990).

(130)     R. Okazaki, M. Unno, and N. Inamoto, Estimation of Bulkiness of a Highly Sterically Demanding 2,4,6-Tris[bis(trimethylsilyl)methyl]-phenyl Group, Chem. Lett., 18, 791–792 (1989).

(131)     R. Okazaki, M. Unno, G. Yamamoto, and N. Inamoto, A Conformational Study on Highly Crowded 1,3,5-Tris[bis(trimethylsilyl)methyl]benzene Derivatives. Chem. Lett. 18, 493–496 (1989).

(132)     R. Okazaki, M. Unno, and N. Inamoto, 2,4,6-Tris[bis(Trimethylsilyl)methyl]phenyl, a New Sterically Demanding Group for Kinetic Stabilization of Unstable Compounds, Chem. Lett., 16, 2293–2294 (1987).

(133)     R. Okazaki, M. Unno, and N. Inamoto, A New Synthesis of 1,3-Thiazine Derivatives Bearing a Dithiolane Ring and Their Reductive Cleavage with Sodium Cyanoborohydride, Heterocycles, 25, 183–190 (1987).


[Review, Proceedings]

(1) 刘雨佳, 海野雅史, ヤヌス型シロキサン開発物語, 有機合成化学協会誌, 80, 12, 1126–1135 (2022).

(2) 海野雅史, 刘雨佳,  シランカップリング剤の歴史, New Glass, 37, 2, 7–10 (2022).

(3) 海野雅史, シランカプリング剤の基礎とメカニズム, 塗装工学, 57, 4, 138–145 (2022).

(4) 海野雅史, ヤヌスキューブ(ヤヌス分子)の合成と応用展開,ファインケミカル, 48, 3, 38–48 (2019).

(5) 海野雅史,シランカップリング剤のメカニズムと将来展開,色材協会誌,885143–147 (2015).

(6) M. Unno, A. Suto, and T. Matsumoto, "Laddersiloxanes— Silsesquioxanes with defined ladder structure", Russ. Chem. Rev., 82, 289–302 (2013).

(7) 海野雅史, 超分子から構造規制次世代材料までシラノールが築く新しい化学—, 有機合成化学協会誌, 69, 413–425 (2011).

(8) 海野雅史,近未来材料のシルセスキオキサン, 化学, 65, 10, 68–69 (2010).

(9) 海野雅史, ケイ素化合物の優れた結合能を利用した表面処理ならびに増感色素への応用, ファインケミカル, 39, 3, 5–12 (2010).

(10) 海野雅史, 花屋実, ケイ素を利用した新規色素増感太陽電池の設計, ケミカルエンジニヤリング, 53, 9, 687–693 (2008).

(11) M. Unno, Laddersiloxanes: silsesquioxanes with defined ladder structure. Materials Research Society Symposium Proceedings 1007-S01-05 (2007),.

(12) 海野雅史, シラノールの水素結合を利用したナノサイズ超分子の形成, ナノ学会会報, 5, 47–51 (2007).

(13) M. Unno, K. Takada, Y. Kawaguchi, and H. Matsumoto, Supramolecular aggregates of silanols and solid-state synthesis of siloxanes, Mol. Cryst. Liq. Cryst., 440, 259–264 (2005).

(14) 海野雅史, 松本英之, オクタシラキュバンの化学, 有機合成化学協会誌, 62, 107–115 (2004).

(15) K. Yamada, M. Unno, K. Kobayashi, H. Oku, H. Yamamura, H. Matsumoto, R. Katakai, and K. Masao, Stereochemistry of protected ornithine side chains of gramicidin S derivatives: X-ray crystal structure of N-methylated derivative of gramicidin, Peptide Science, 2002, 39th, 305–308 (2003).

(16) 海野雅史, フラーレン化学合成12年の歩み〜L. T. Scott研究室, ケイ素化学協会誌, No.16, pp.12-15 (2002).

(17) H. Matsumoto, S. Kyushin, M. Unno, and R. Tanaka, Synthesis, Structures, and Properties of Ladder Oligosilanes and Ladder Oligogermanes, J. Organomet. Chem. 611, 52–63 (2000).

(18) 海野雅史, 松本英之, ケイ素原子を持つ超分子,科学と工業 (大阪), 74, 489–494 (2000).

(19) 海野雅史, ヘテロ原子化学+有機金属化学, ケイ素化学協会誌, No.12, pp.11-14 (2000).

(20) 海野雅史, Tbt基が生まれた頃−When Tbt was born, ケイ素化学協会誌, No.11, pp.45-46 (1999).

(21) 海野雅史, 松本英之, シルセスキオキサン類の化学−かご状化合物を中心に, ケイ素化学協会誌, No.8, pp.16-22 (1997).



(1) 海野雅史(分担), シランカップリング剤 の最新技術動向(第6章第1節)次世代シランカップリング剤,シーエムシー出版,pp.216–223 (2020). ISBN 978-4-7813-1520-1

(2) 海野雅史(分担), シランカップリング剤 の使い方と応用事例(第9章第1節)シルセスキオキサンの種類・構造,合成方法,サ イエンス&テクノロジー,pp.313–321 (2020). ISBN 978-4-86428-218-5

(3) 海野雅史(分担), 添加剤の最適使用法 (第8節 シランカップリング剤の種類,反応,使用方法),R&Dリサー チセンター,pp.129–135 (2020). ISBN 978-4-905507-42-0

(4)   M. Unno and H. Endo, “Silanols as Building Blocks for Nanomaterials” in Novel Nanoscale Hybrid Materials, Ed. Bhanu P. S. Chauhan, John Wiley & Sons, Inc., New York, pp. 1–31 (2018).

(5)   M. Unno and R. Tanaka, “Silanols and Silsesquioxanes” in Efficient Methods for Preparing Silicon Compounds, Ed. H. W. Roesky, Academic Press, London, pp. 399–440 (2016).

(6) シランカップリング剤の使いこなし ノウハウ集, 第1章「シランカップリング剤の反応メカニズム」,技術情報協会 (2016). ISBN 978-4-86104-610-0

(7)   M. Unno, "Substituted Polyhedral Silicon and Germanium Clusters", in Functional Molecular Silicon Compounds II, Ed. D. Scheschkewitz, Springer, Heidelberg, pp.49-84 (2014).

(8) 現代ケイ素化学(分担),第22章「シリコーンの応用」,吉良満夫,玉尾皓平編,化学同人 pp.349-3602013.

(9) シルセスキオキサン材料の化学と応用展開, 伊藤真樹監修, 第 4章「かご型および精密合成ラダーシルセスキオキサン」, シーエムシー出版 pp. 37-48 (2013).

(10)    最強エレメント ケイ素の不思議(分担) , 海 野雅史編, 海 野雅史他著, 上 毛新聞社,pp.9-11, 19-21 (2011).

(11)    シランカップリング剤の反応メカニズムと処理条件の最適化, 第1章「シランカップ リング剤の基本的メカニズム」, 第5章「シランカップ リング剤への新規機能性の付与」, 技術情報協会pp.1-20, 88-105 (2010).

(12)    シルセスキオキサン材料の最新技術と応用, 伊藤真樹監修, 第 4章「かご型および精密合成ラダーシルセスキオキサン」, シーエムシー出版 (2007).

(13)    新時代への視点 −群馬大学研究室から−(分担),群馬大学地域連携推進室編,上毛新聞社,pp. 186-188 (2006).

(14)         M. Unno and H. Matsumoto, "Reactions of Octasilacubane", in Organosilicon Chemistry VIEds. N. Auner and J. Weis, WILEY-VCH Verlag, Weinheim, pp. 373–380 (2005).

(15)    10年使える有機スペクトル解析(分担),新津隆士,海野雅史,鍵裕之著,三共出版,第1章,第2章 (2005).

(16)    21世紀の有機ケイ素化学機能性物質科学の宝庫(分 担),玉尾皓平監修,シーエムシー(2004.

(17)    プロフェショナル英和辞典スペッドテラ 物質・工学編(分担),堀内克明、蟹江幸博編,小学館 (2004).

(18)    キラキラわくわく化学(分担)上毛新聞社,pp.50-53 (2003).

(19)    有機ケイ素材料科学の新展開 (分担),櫻井英樹監修,シーエム シー,pp.146-156 (2001)

(20)    化合物の辞典 (分担), 稲 本直樹ら編, 朝 倉書店 (1998).

(21)    気軽に化学 (分担), 上 毛新聞社,pp.168-169,172-173 (1996).



(1)   特願2016-232998、海野雅史、江川泰暢、島田 茂、佐藤一彦、「反応性置換基を有するシルセスキオキサンの製造方法」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成281130.

(2)   特願2015-204578、海野雅史、江川泰暢、島田 茂、佐藤一彦、「異なる置換基を対面に4つずつ有するかご型シルセスキオキサ ン」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成271016.

(3)   特開2014-093158、神谷正人齋藤平、寺島純平、鳶島真一森本英行、海野雅史、「リチウムイオン二 次電池」、トヨタ自動車株式会社、国立大学法人群馬大学、平成26519.

(4)   特開2014-053097神谷正人齋 藤平、鳶島真一、森本英行、海野雅史、「リチウム二次電池およびその製造方法」、国立大学法人群馬大学、トヨタ自動車 株式会社、平成26320.

(5)   特願2014-76446、海野雅史、佐藤一彦、島田茂、 五十嵐正安、「シロキサン化合物の製造方法」、国立大学法人群馬大学、独立行政法人産業技術総合研究所、平成2642.

(6)   特開2013-241497、小熊武美、渡辺淳、海野雅 史、「ポリシルセスキオキサン化合物、光素子封止材及びその用途」、国立大学法人群馬大学、電気化学工業株式会社、平成25125.

(7)        WO 2012137568, M. Hanaya, K. Kakiage, M. Unno, Y. Aoyama, T. Yano, D. Sawamoto, H. Osada, “Aromatic amines bearing hydrocarbyloxysilyl groups, supports containing supported them, and photoelectric converters”, Adeka Corporation, Oct. 11, 2012.

(8)   WO 2012036010, M. Hanaya, K. Kakiage, M. Unno, T. Yano, K. Akimoto, K. Sakamaki, “Production of pyridine derivative additive for electrolytic composition of dye-​sensitized solar cell”, Adeka Corporation, Sep. 5, 2011.

(9)   特開2011-202057、海野雅史、小熊武美、村田 弘、「ポリシルセスキオキサン化合物、光素子封止材及びその用途」、電化化学工業株式会社、国立大学法人群馬大学,平成22326日.

(10)  特開2009-249455(特願2008-097235)、濱田光祥、永井晃、海野雅史、山村正樹、「封止用エポキシ樹脂 成形材料及び電子部品装置」、日立化成工業株式会社、平成211029.

(11)  特開2009-249312(特願2008-097236)、濱田光祥、永井晃、加藤木茂樹、杜暁黎、海野雅史、「シラン化 合物」、日立化成工業株式会社、平成211029.

(12)  特開2007-197723(特願2006-356289)、濱田光祥、永井晃、松本英之、海野雅史、「封止用エポキシ樹脂 成形材料及び電子部品装置」、日立化成工業株式会社、平成1989.

(13)  特開2008-63390(特願2006-240428)、海野雅史,花屋実,「色素増感太陽電池用色素及びこの色素を用 いた光電変換素子並びに色素増感太陽電池」,国立大学法人群馬大学,平成1895日.

(14)  特開2006-016580(特願2004-198515)、濱田光祥、永井晃、松本英之、海野雅史、「接着剤組成物、それ を用いたフィルム状接着剤及び回路接続材料、並びに回路部材の接続構造及びその製造方法」、日立化成工業株式会社、平成18119.

(15)  特開2006-016370(特願2004-198509)、佐藤和也、湯佐正己、小林隆伸、藤縄貢、塚越功、松本英之、海 野雅史、「シラン化合物」、日立化成工業株式会社、平成18119.

(16)  特開2006-016369(特願2004-198508)、佐藤和也、湯佐正己、小林隆伸、藤縄貢、塚越功、松本英之、海 野雅史、「シラン化合物の製造方法及びシラン化合物」、日立化成工業株式会社、平成18119.

(17)  特開2004-315428(特願2003-111608)、松本英之、海野雅史、田中陵二、「ハロゲン化アリール置換環状 テトラシロキサンの製法」、独立行政法人 科学技術振興機構、20041111.



1)  新物質「ヤヌスキューブ」群馬大大学院が新合成法, 日本経済新聞, 2016/05/28.

2)  群馬大が新合成法 新物質「ヤヌスキューブ」, 日本経済新聞, 電 子版, 2016/05/28.

3)  エコタイヤの性能向上 化合物の合成法開発, 産 経新聞, 2016/05/28.

4)  エコタイヤの性能向上に期待 群大院が「ヤヌスキューブ」合成, 産経新聞電子版, 2016/05/28.

5)  エコタイヤの性能向上に期待 群大院が「ヤヌスキューブ」合成法開発, Yahooニュース, 2016/05/28.

6)  ヤヌスキューブ簡便合成法 産総研群馬大 有機ケイ素部材に有用, 化学工業日報, 2016/05/30.

7)  ヤヌスキューブの簡易合成法を発見 エコタイヤ性能向上期待,     上 毛新聞, 2016/05/30.

8)  ヤヌスキューブ効率的に合成 群馬大と産総研, 日刊工業新聞, 2016/06/02.

9)  ヤヌスキューブ 簡便な合成法開発 詳細な分子構造も解明, 桐生タイムス, 2016/06/02.

10) 「究極のエコタイヤ」へ新手法 ヤヌスキューブ材料の化合物合成効率化, 読売新聞, 2016/06/03

11) ヤヌスの立方体, 有機化学美術館・分館, 2016/06/06.

12) カゴ型シルセスキオキサン「ヤヌスキューブ」合成と構造決定, Chem-Stationスポットライトサーチ, 2016/06/10.

13) ヤヌスキューブ合成     科 学新聞社電子版, 2016/06/17.