*Full list is shown in this page.
Y. Liu,
T. Chaiprasert, A.
Ouali, M. Unno, Well-defined cyclic silanol derivatives,
Dalton Trans.,
in press (2022). https://doi.org/10.1039/D1DT04270J
Y. Liu, K. Koizumi, N. Takeda, M. Unno, A.
Ouali,
Synthesis of octachloro and octaazido-functionalized T8
cages and
applications to recyclable palladium catalyst, Inorg.
Chem., in press (2022).
https://doi.org/10.1021/acs.inorgchem.1c03209
Y. Liu, M. Katano, P. Yingsukkamol, N.
Takeda, M.
Unno, A. Ouali, Tricyclic 6-8-6 laddersiloxanes derived
from all-cis-tetravinylcyclotetrasiloxanolate:
Synthesis, characterization and reactivity, J.
Organomet. Chem., in
press (2022).
https://doi.org/10.1016/j.jorganchem.2021.122213
Y. Egawa, C. Kobuna, N. Takeda, M. Unno,
Synthesis
of Janus cube containing Si–H moieties, Mendeleev
Commun., 32, 35–36 (2022).
Y. Liu, M.
Kigure, R. Okawa, N. Takeda, M. Unno, A.
Ouali, Synthesis and
characterization of tetrathiol-substituted double-decker
or ladder
silsesquioxane nano-cores, Dalton
Trans., 50,
3473–3478 (2021). https://doi.org/10.1039/D1DT00042J
M. Laird, C.
Totée, P.
Gaveau, G. Silly,@A. Van der
Lee, C. Carcel,
M. Unno, J. R. Bartlett, M. Wong Chi Man, Functionalised
polyhedral oligomeric
silsesquioxane with encapsulated fluoride – first
observation of fluxional Si⋯F interactions in POSS, Dalton
Trans., 50,
81–89 (2021). IF=4.17 https://doi.org/10.1039/D0DT03057K
Q. Wang, M.
Unno, H. Liu, Silsesquioxane-Based
Triphenylamine-Linked Fluorescent Porous Polymer for
Dyes Adsorption and
Nitro-Aromatics Detection, Materials, 14,
3851 (2021). IF=3.26 https://doi.org/10.3390/ma14143851
Y.
Liu, A, Endo, P. Zhang, A. Takizawa, N. Takeda, A.
Ouali, M. Unno, Synthesis,
Characterization, and Reaction of Divinyl-substituted
Laddersiloxanes, Silicon,
2021, in press. IF = 2.67 https://doi.org/10.1007/s12633-021-01068-6
T. Chaiprasert, Y. Liu, N. Takeda, M. Unno,
Vinyl-Functionalized Janus Ring Siloxane: Potential
Precursors to Hybrid
Functional Materials. Materials,14,
2014 (2021). IF=3.26 https://doi.org/10.3390/ma14082014
J. Guan, Z.
Sun, R.
Ansari, Y. Liu, A. Endo, M. Unno, A. Ouali, S. Mahbub,
J. C. Furgal, N. Yodsin,
S. Jungsuttiwong, D. Hashemi, J. Kieffer, and R. M.
Laine, Conjugated Copolymers
That Shouldnft Be, Angew. Chem. Int. Ed. 60,
11115–11119 (2021). IF=12.96
https://doi.org/10.1002/anie.202014932
M. Laird, P. Gaveau, P. Trens, C. Carcel,
M. Unno, J. R. Bartlett, M. Wong Chi Man, Post-synthesis
modification of
functionalised polyhedral oligomeric silsesquioxanes
with encapsulated fluoride
– enhancing reactivity of T8-F
POSS
for materials synthesis, New J. Chem., 45,@4227–4235 (2021). IF = 3.29 https://doi.org/10.1039/d0nj06008a
T. Chaiprasert, Y. Liu,
P. Intaraprecha, R. Kunthom, N. Takeda, M. Unno,
Synthesis of tricyclic
laddersiloxane with various ring sizes (Bat
siloxane), Macromol. Rapid
Commun., 42, 2000608 (2021). IF = 4.89 https://doi.org/10.1002/marc.202000608
M.
Laird, N. Herrmann, N. Ramsahye,
C. Totée, C. Carcel,
M. Unno, J. Bartlett, M. Wong Chi Man, Large polyhedral
oligomeric
silsesquioxane cages – the isolation of functionalized
POSS with an
unprecedented Si18O27 core, Angew.
Chem. Int. Ed.,
60, 3022–3027 (2021). IF=12.96
https://doi.org/10.1002/anie.202010458
M.
Laird, J. Yokoyama, C.
Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man,
Sol–gel processing of
polyhedral oligomeric silsesquioxanes: nanohybrid
materials incorporating T8
and T10 cages, J. Sol-Gel Sci. Tech., 95,
760–770 (2020). IF =
2.33 https://doi.org/10.1007/s10971-020-05314-y
T.
Chaiprasert, Y. Liu, N.
Takeda, M. Unno, Janus ring siloxane: a versatile
precursor of the extended
Janus ring and tricyclic laddersiloxanes, Dalton
Trans., 49,
13533–13537 (2020). IF = 4.17 https://doi.org/10.1039/D0DT03045G
Y.
Liu, M. Kigure, K. Koizumi,
N. Takeda, M. Unno, A. Ouali, Synthesis of Tetrachloro,
Tetraiodo, and Tetraazido
Double-Decker Siloxanes, Inorg. Chem., 59, 15478–15486
(2020). If = 4.83 https://doi.org/10.1021/acs.inorgchem.0c02515
M.
Laird, A. van der Lee, D. Dumitrescu,
C. Carcel, A. Ouali, J. Bartlett, M. Unno, M. Wong Chi
Man, Styryl
Functionalized Cage Silsesquioxanes as Nano Blocks for
3-D Assembly, Organometallics,
39, 1896–1906 (2020). IF = 3.80 https://dx.doi.org/10.1021/acs.organomet.0c00119
Y.
Du, M. Unno, H. Liu, Hybrid
Nanoporous Materials Derived from Ladder- and Cage-Type
Silsesquioxanes for
Water Treatment, ACS Appl. Nano Mater., 3,
1535–1541 (2020). IF =
3.94 https://doi.org/10.1021/acsanm.9b02325
Y.
Liu, K. Onodera, N. Takeda,
A. Ouali, and M. Unno, Synthesis and Characterization of
Functionalizable
Silsesquioxanes with Ladder-type Structures, Organometallics, 38,
4173–4176 (2019). IF = 3.80
https://doi.org/10.1021/acs.organomet.9b00597
N.
Prigyai, S.
Chanmungkalakul, V. Ervithayasuporn, N. Yodsin, S.
Jungsuttiwong, N. Takeda, M.
Unno, J. Boonmak, S. Kiatkamjornwong, Lithium-Templated
Formation of Polyhedral
Oligomeric Silsesquioxanes (POSS), Inorg. Chem.
58, 15110–15117
(2019). If =
4.83 https://doi.org/10.1021/acs.inorgchem.9b01836
R.
Kunthom, T. Adachi, Y. Liu,
N. Takeda, M. Unno, and R. Tanaka, Synthesis of a
"Butterfly Cage"
Based on a Double-Decker Silsesquioxane, Chem. Asian
J., 14, 4179–4182
(2019). IF = 4.06 https://doi.org/10.1002/asia.201901361
R.
Kunthom, N. Takeda, M. Unno,
Synthesis and Characterization of Unsymmetrical
Double-decker Siloxane (Basket
Cage), Molecules, 24, 4252 (2019). IF =
3.31 https://doi.org/10.3390/molecules24234252
Y.
Liu, N. Takeda, A. Ouali, M. Unno, Synthesis,
Characterization, and Functionalization
of Tetrafunctional Double-Decker Siloxanes, Inorg.
Chem., 58, 4093–4098 (2019). If = 4.83 https://doi.org/10.1021/acs.inorgchem.9b00416
T.
Tanaka, Y. Hasegawa, T. Kawamori, R. Kunthom, N. Takeda,
M. Unno, Synthesis of
Double-Decker Silsesquioxanes from Substituted
Difluorosilane, Organometallics,
38, 743-747
(2019). IF
= 3.80 https://doi.org/10.1021/acs.organomet.8b00896
S.
Kondo, Y. Nakadai, M. Unno, Recognition of
dicarboxylates in aqueous
acetonitrile by a dinuclear zinc(II) complex of
2,2'-binaphthalene-based
receptor, Supramolecular
Chem., 31,
9–18 (2019). IF = 1.35 https://doi.org/10.1080/10610278.2018.1522445
T.
Uchida, Y. Egawa, T. Adachi, N. Oguri, M. Kobayashi, T.
Kudo, N. Takeda, M.
Unno, R. Tanaka, Synthesis, Structures, and Thermal
Properties of Symmetric and
Janus gLantern Cageh Siloxanes, Chem.
Eur. J., 25, 1683 –1686 (2019). IF = 4.86
https://doi.org/10.1002/chem.201805200
H.
Endo, N. Takeda, and M. Unno, Single-step synthesis of
disiloxanetetraols,
J. Sol-Gel Sci. Technol., 89,
37–44 (2019). IF =
2.33 https://doi.org/10.1007/s10971-018-4635-9
C. Weetman, N. Ito, M. Unno, F.
Hanusch, S. Inoue, NHI- and
NHC-Supported Al(III) Hydrides for Amine–Borane
Dehydrocoupling Catalysis,
Inorganics, 7, 92 (2019).
https://doi.org/10.3390/inorganics7080092
Y.
Egawa, C. Fukumoto, K. Mikami, N. Takeda, M. Unno,
Synthesis and Characterizations
of
The Germathioacid chloride Coordinated by an N-Heterocyclic
carbene,
Inorganics, 6, 76 (2018). IF =
2.15 https://doi.org/10.3390/inorganics6030076
H. Endo, N. Takeda, and M. Unno, Stereoisomerization of Cyclic Silanols, Chem. Asian J.,
12, 1224–1233
(2017). IF
= 4.06 https://doi.org/10.1002/asia.201700125
N. Oguri, Y. Egawa, Y. Kawakami,
C. Kobuna, N. Takeda, and M. Unno, Unusual Reactions of
Cyclic Fluorosiloxanes,
ChemistrySelect,
2, 2300–2304
(2017). IF = 2.00 https://doi.org/10.1002/slct.201700306
Y. Egawa, S. Murakami, N. Takeda,
and M. Unno, Synthesis of Hydrosilyl-substituted Cyclic
Siloxane: New Building
Block for Materials, Chem. Lett., 45,
738–739 (2016). IF = 1.36 https://doi.org/10.1246/cl.160272
N. Oguri, Y. Egawa, N. Takeda,
and M. Unno, Janus-Cube Octasilsesquioxane: Facile
Synthesis and Structure
Elucidation, Angew.
Chem. Int. Ed. 55,
9336-9339 (2016). IF=12.96 https://doi.org/10.1002/anie.201602413
N. Takeda, Y. Tanaka, R. Oma, F.
Sakakibara, M. Unno, Activation of C–S Bond by Group 10
Metal Complexes:
Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl Groups with Group 10
Metal Compounds, Bull.
Chem. Soc. Jpn., 89, 922-930 (2016). IF =
4.49 https://doi.org/10.1246/bcsj.20160089
S. Murakami, Y. Egawa, C.
Kuramochi, N. Takeda, and M. Unno, Cyclic Silanols with
Long Alkyl Chains, Chem. Lett., 45,
309–311 (2016). https://doi.org/10.1246/cl.151143
K. Kakiage, T. Abe, M. Yamamura,
T. Kyomen, M. Unno, and M. Hanaya, Effect
of the introduction of
a CF3 group to a silyl-anchor azobenzene dye
on sensitization property
in dye-sensitized solar cells, Key Eng.
Mater., 698, 27–31 (2016). https://doi.org/10.4028/www.scientific.net/KEM.698.27
N. Oguri, N. Takeda, and M. Unno,
Facile Synthesis of Cyclic Fluorosiloxanes, Chem.
Lett., 44, 1506–1508 (2015). https://doi.org/10.1246/cl.150692
H. Endo, and
N. Takeda, M. Takanashi, T. Imai, and M. Unno,
Refractive Indices of Silsesquioxanes with Various
Structures,
Silicon, 7, 127–32 (2015). https://doi.org/10.1007/s12633-014-9239-6
M. Unno, H.
Endo, and N. Takeda, Synthesis and Structures of Extended Cyclic
Siloxanes, Heteroatom
Chem. 25, 525–532
(2014). https://doi.org/10.1002/hc.21198
N. Takeda, T. Tagawa, and M.
Unno, Synthesis, Reactivities, and Coordination
Chemistry of
Tris(2-isopropoxyphenyl)phosphine, Heteroatom
Chem. 25, 628–635 (2014). https://doi.org/10.1002/hc.21174
K. Kakiage, Y. Aoyama, T. Yano,
T. Otsuka, T. Kyomen, M. Unno, and M. Hanaya, An
achievement of over 12 percent
efficiency in an organic dye-sensitized solar cell, Chem. Commun., 50, 6379–6381
(2014). https://doi.org/10.1039/c4cc02192d
H. Endo, N. Takeda, and M. Unno,
Synthesis and
Properties of
Phenylsilsesquioxanes with Ladder and Double-Decker
Structures, Organometallics,
33, 4148-4151 (2014). https://doi.org/10.1021/om500010y
R. Yanagisawa, H. Endo, M. Unno,
H. Morimoto, S. Tobishima, Effects of organic
silicon compounds as
additives on charge-discharge cycling efficiencies of
lithium in nonaqueous
electrolytes for rechargeable lithium cells, J. Power Sources, 266, 232–240
(2014). https://doi.org/10.1016/j.jpowsour.2014.05.017
S. Kondo, Y.
Nakadai, and M. Unno, Pyrophosphate selective
recognition by a Zn2+ complex of a
2,20-binaphthalene derivative
bearing di(2-pyridylmethyl)aminomethyl groups in aqueous
solution, RSC
Adv., 4, 27140–27145 (2014). https://doi.org/10.1039/c4ra01941e
K. Kakiage, Y. Aoyama, M.
Yamamura, T. Yano, M. Unno, T. Kyomen, and M. Hanaya, A
Novel Alkoxysilyl
Azobenzene Dye Photosensitizer with Alkylamino Group for
Dye-Sensitized Solar
Cells, Silicon,
6, 123–127
(2014). https://doi.org/10.1007/s12633-013-9174-y
M. Yamamura,
S. Kondo, and M. Unno, Ion Pair Recognition of
Ditopic Receptor Bearing Silanol Groups as Anion
Recognition Sites and a 2,2'-Bipyridine
Moiety as a Metal-coordination Site, Tetrahedron
Lett., 55,
646–649 (2014). https://doi.org/10.1016/j.tetlet.2013.11.096
S. Kondo, N.
Watanabe, F. Takahashi, N. Takeda, and M. Unno,
Synthesis and
photophysical properties
of 2,2f-binaphthalene-based receptor bearing
trimethylsilyl groups to improve
the solubility,
J.
Incl. Phenom. Macrocycl. Chem., 75, 31-38
(2013). https://doi.org/10.1007/s10847-012-0142-8
H. Endo and
M. Unno, Effective Synthesis and Isomerization
of Cyclotetrasiloxanetetraol, Key Eng. Mater., 534,
66–70 (2013). https://doi.org/10.4028/www.scientific.net/KEM.534.66
K. Kakiage, C. Saito, M.
Yamamura, T. Kyomen, M. Unno, and M. Hanaya, Study of
the Chemical Adsorption
Property of Allylsilylazobenzene in the Surface
Modification of Nano-Porous
Alumina Membrane, Key
Eng. Mater., 534,
46–52 (2013). https://doi.org/10.4028/www.scientific.net/KEM.534.46
M. Unno, T.
Matsumoto, H. Matsumoto, Nonacyclic Ladder
Silsesquioxanes and
Spectral Features of Ladder Polysilsesquioxanes,
Int. J. Polym. Sci., 723892 (2012). https://doi.org/10.1155/2012/723892
K. Kakiage,
M. Yamamura, T. Kyomen, M. Unno, and M. Hanaya,
Adsorption and Sensitizing Properties of Azobenzenes
Having Different Numbers
of Silyl-anchor Groups in Dye-sensitized Solar Cells, Key Eng. Mater., 497,
61–66 (2012). https://doi.org/10.4028/www.scientific.net/KEM.497.61
K. Kakiage,
T. Tsukahara, T. Kyomen, M. Unno, and M.
Hanaya, Significant Improvement of Photovoltaic
Performance of Dye-sensitized
Solar Cells by Using 4-Trimethylsilylpyridine as Organic
Additive to
Electrolyte Solution, Chem. Lett., 41, 895-896
(2012). https://doi.org/10.1246/cl.2012.895
(Selected
Paper) S. Kondo, S. Nakajima, and M. Unno, Ratiometric
Fluorescence Detection of Anions by an Amide-Based
Receptor Bearing Pyrenyl
Groups, Bull.
Chem. Soc. Jpn., 85, 698-700
(2012). https://doi.org/10.1246/bcsj.20120054
S. Kondo, H.
Sonoda, T. Katsu, and M. Unno, Improvement of solubility of
2,2-binaphthalene derivatives
bearing urea groups as anion receptors and their
application to a chloride
selective electrode, Sensors and
Actuators B, 160, 684–690
(2011). https://doi.org/10.1016/j.snb.2011.08.048
V.
Ervithayasuporn, T. Tomeechai, N. Takeda, M. Unno, A.
Chaiyanurakkul, R. Hamkool, and T. Osotchan, Synthesis
and Characterization of
Octakis(3-propyl ethanethioate)octasilsesquioxane, Organometallics, 30, 4475–4478
(2011). https://doi.org/10.1021/om200477a
M. Unno, N.
Yamashita, and H. Matsumoto, Thermal Reaction
of Octasilacubane with Sulfur, Selenium, and Tellurium:
Formation of Novel Cage
Systems, Phosphorus, Sulfur, Silicon Relat. Elem., 186,
1259–1262 (2011). https://doi.org/10.1080/10426507.2010.525769
Y. Egawa and M. Unno, Solvent-free Synthesis of
Functional Siloxanes
Bearing 4-Trifluoromethylphenyl Group, Key
Eng. Mater., 497, 51–54 (2011). https://doi.org/10.4028/www.scientific.net/KEM.497.51
K. Kakiage,
M. Yamamura, E. Ido, T. Kyomen, M. Unno, and M.
Hanaya, Reactivity of Alkoxysilyl Compounds: Chemical
Surface Modification of
Nano-porous Alumina Membrane Using
Alkoxysilylazobenzenes, Appl. Organomet. Chem., 25,
98–104 (2011). https://doi.org/0.1002/aoc.1722
S. Kondo, T.
Takahashi, Y. Takiguchi, and M. Unno,
Synthesis and photophysical properties of a
2,2f-bianthracene-based receptor
bearing two aza-15-crown-5 ethers for naked-eye
detection of barium ion, Tetrahedron Lett.,
52, 453–457 (2011). https://doi.org/10.1016/j.tetlet.2010.11.091
S. Kondo, M.
Nagamine, S. Karasawa, M. Ishihara, M. Unno,
and Y. Yano, Anion recognition by 2,2f-binaphthalene
derivatives bearing urea and
thiourea groups at 8- and 8f-positions by UV-vis and
fluorescence
spectroscopies, Tetrahedron,
67, 943-950
(2011). https://doi.org/10.1016/j.tet.2010.12.004
N. Takeda, T. Nakamura, A.
Imamura, and M. Unno, Synthesis and reactivities of
dihydrosilanes tethered
with two thioether moieties, Heteroatom
Chem. 22, 438–445 (2011). https://doi.org/10.1002/hc.20706
M. Unno, R. Tanaka, D. Obinata,
M. Endo, T. Sakurai, S. Ojima, T. Katayama, K. Fugami,
Solvent-free synthesis
of siloxanes and their usage as potential
cross-coupling reagents, Key Eng. Mater.,
459, 43–47
(2011). https://doi.org/10.4028/www.scientific.net/KEM.459.43
R. Tanaka, S.
Kowase,
and M. Unno, Chiral Cyclotrisiloxanes, Dalton
Trans., 39,
9235–9237 (2010). https://doi.org/10.1039/C0DT00135J
N.
Takeda, D. Watanabe, T. Nakamura, and M. Unno, Synthesis
and Complexation of
New Tripodal Tetradentate Ligand, Silyl Ligand Tethered
with Three Thioether
Moieties, Organometallics,
29, 2839-2841
(2010). https://doi.org/10.1021/om100255p
S. Kondo, Y.
Kobayashi, and M. Unno, Anion Recognition by
D-Ribose-based Receptors, Tetrahedron
Lett., 51,
2512–2514 (2010). https://doi.org/10.1016/j.tetlet.2010.03.001
M.
Unno, R. Tanaka, D. Obinata, M. Endo, T. Sakurai,
S. Ojima, T. Katayama,
and K. Fugami, Solvent-free
Synthesis
of Siloxanes and Their Usage as Potential
Cross-Coupling Reagents, Key. Eng. Mater.,
459, 43–47
(2010). https://doi.org/10.4028/www.scientific.net/KEM.459.43
N.
Takeda, Y. Tanaka, F. Sakakibara, and M. Unno, Synthesis and Structure of Group 10 Metal
Complexes with New Tripodal
Tetradentate Ligand Bearing One Phosphine and Three
Thioether Moieties, Bull. Chem. Soc.
Jpn., 83,
157–164 (2010). https://doi.org/10.1246/bcsj.20090187
K.
Kakiage, M. Yamamura, E. Fujimura, T. Kyomen, M. Unno
and M. Hanaya, High
Performance of Si–O–Ti Bonds for
Anchoring Sensitizing Dyes on TiO2
Electrodes in Dye-sensitized Solar Cells Evidenced by
Using
Alkoxysilylazobenzenes,
Chem. Lett., 39,
260–262 (2010). https://doi.org/10.1246/cl.2010.260
K.
Kakiage, T. Kyomen, M. Unno, and M. Hanaya,
Molecular-selective Adsorption
Property of Chemically Surface Modified Nanoporous
Alumina Membrane by
Di(1-naphthyl)silanediol to Anthracenes, Appl.
Organomet. Chem., 24, 198–200
(2010). https://doi.org/10.1002/aoc.1586
S.
Chang, T. Matsumoto, H. Matsumoto, and M. Unno,
Synthesis and Characterization
of Heptacyclic Laddersiloxanes and Ladder
Polysilsesquioxane, Appl. Organomet.
Chem., 24,
241–246 (2010). https://doi.org/10.1002/aoc.1607
M.
Unno, K. Kakiage, M. Yamamura, T. Kogure, T. Kyomen, and
M. Hanaya, Silanol
Dyes for Solar Cells: Higher Efficiency and Significant
Durability, Appl.
Organomet. Chem., 24, 247–250
(2010). https://doi.org/10.1002/aoc.1612
K.
Kakiage, T. Kyomen, M. Unno, and M. Hanaya, The Chemical
Adsorption Properties
of Silanol to Metal-Oxide Surface Studied by Using
Di(1-naphthyl)silanediol and
Nano-porous Alumina Membranes, Silicon,
1, 191–197
(2009). https://doi.org/10.1007/s12633-009-9027-x
S.
Kondo, N. Okada, R. Tanaka, M. Yamamura, and M. Unno,
Anion recognition
by 1,3-disiloxane-1,1,3,3-tetraols
in organic
solvents, Tetrahedron
Lett., 50,
2754–2757 (2009). https://doi.org/10.1016/j.tetlet.2009.03.134
H.
Liu, S. Kondo, N. Takeda, and M. Unno, An Efficient Approach to
Monophenyl-Functionalized
Octasilsesquioxanes,
Eur. J. Inorg. Chem.,
5, 1317-1319 (2009). https://doi.org/10.1002/ejic.200900012
H.
Liu, S. Kondo, N. Takeda, and M. Unno, Synthesis of
Octacarboxy Spherosilicate,
J. Am. Chem. Soc.,
130,
10074–10075 (2008). https://doi.org/10.1021/ja803513n
K.
Kakiage, Y. Nakada, T. Kogure, M. Yamamura, T. Kyomen,
M. Unno, and M. Hanaya,
Applicability of Silanol to Sensitizing Dye for
Dye-sensitized Solar Cell, Silicon Chem., 3, 303–305 (2008). https://doi.org/10.1007/s11201-008-9032-8
H.
Liu, S. Kondo, R. Tanaka, H. Oku, and M. Unno, A
spectroscopic investigation of
incompletely condensed polyhedral oligomeric
silsesquioxanes (POSS-mono-ol,
POSS-diol and POSS-triol): Hydrogen-bonded interaction
and host–guest complex, J. Organomet.
Chem., 693
1301–1308 (2008). https://doi.org/10.1016/j.jorganchem.2008.01.027
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(Journal of Multimedia Aided Education
Research), 5, 55-61 (2008). http://www.code.ouj.ac.jp/media/pdf5-2-10/No.10-07tokusyuu06.pdf
S.
Kondo, A. Fukuda, T. Yamamura, R. Tanaka, and M. Unno,
Anion Recognition by a
Disiloxane-1,3-diol in Organic Solvents, Tetrahedron.
Lett., 48,
7946–7949 (2007). https://doi.org/10.1016/j.tetlet.2007.09.067
S.
Kondo, T. Hayashi, Y. Sakuno, Y. Takezawa, T. Yokoyama,
M. Unno, and Y. Yano,
Synthesis of cyclic bis- and Trismelamine Derivatives
and Their Complexation
properties with Barbiturates, Org.
Biomol. Chem., 5, 907–916
(2007). https://doi.org/10.1039/B615537E
M.
Endo, T. Sakurai, S. Ojima, T. Katayama, M. Unno, H.
Matsumoto, S. Kowase, H.
Sano, M. Kosugi, and K. Fugami, Novel Pd-Catalyzed
Atom-Efficient
Cross-Coupling Reaction by Means of
Hexaarylcyclotrisiloxane, SynLett, 5, 749-752 (2007). https://doi.org/10.1055/s-2007-970773
M.
Unno, T. Matsumoto, and H. Matsumoto, Synthesis of
Laddersiloxanes by Novel
Stereocontrolled Approach, J. Organomet.
Chem., 692,
307–312 (2007). https://doi.org/10.1016/j.jorganchem.2006.08.068
S.
Kondo, T. Harada, R. Tanaka, and M. Unno, Anion
Recognition by a
Silanediol-Based Receptor, Org. Lett.,
8, 4621–4624
(2006). https://doi.org/10.1021/ol061822p
M. Unno, H. Murakami, S. Kagawa and H.
Matsumoto,
Borderline of Hydrogen Bonding by Silanols, Silicon
Chem., 3,
195–198 (2005). https://doi.org/10.1007/s11201-006-9021-8
M.
Hirotsu, S. Taruno, T. Yoshimura, K. Ueno, M. Unno, and
H. Matsumoto, Synthesis
and Structures of the First Titanium(IV) Complexes with
Cyclic Tetrasiloxide
Ligands: Incomplete and Complete Cage Titanosiloxanes, Chem. Lett., 34,
1542–1543 (2005). https://doi.org/10.1246/cl.2005.1542
M.
Unno, S. Chang, and H. Matsumoto, cis-trans-cis-Tetrabromotetramethylcyclotetrasiloxane:
a
Versatile Precursor of Ladder Silsesquioxanes, Bull. Chem. Soc. Jpn., 78,
1105–1109 (2005). https://doi.org/10.1246/bcsj.78.1105
M.
Unno, R. Tanaka, S. Tanaka, T. Takeuchi, S.
Kyushin, and H. Matsumoto, Oligocyclic Laddersiloxanes:
Alternative Synthesis
by Oxidation, Organometallics,
24,
765–768 (2005). https://doi.org/10.1021/om049324c
M.
Unno, Y. Kawaguchi, Y. Kishimoto, and H.
Matsumoto, Stereoisomers of
1,3,5,7-Tetrahydroxy-1,3,5,7-tetaisopropylcyclotetrasiloxane:
Synthesis and
Structures in the Crystal, J. Am. Chem.
Soc., 127,
2256–2263 (2005). https://doi.org/10.1021/ja043894m
T.
Okutsu, K. Isomura, N. Kakinuma, H.
Horiuchi, M. Unno, H. Matsumoto, and H. Hiratsuka,
Laser-induced morphology
control and liquid phase epitaxy of dipara-anthracene
produced from
photochemical reaction of anthracene, Cryst. Growth Des., 5,
461–465 (2005). https://doi.org/10.1021/cg049816s
M.
Unno, Y. Kishimoto, and H.
Matsumoto, Triisopropylcyclotrisiloxanetriol: An
Unprecedented Cyclic
Siloxanetriol with Relatively Small Substituents, Organometallics, 23, 6221–6224
(2004). https://doi.org/10.1021/om0494972
K.
Negishi, M. Unno, and H.
Matsumoto, The Cyclo[(disilanylene)(butadiyne)]s [(i-Pr)2Si(i-Pr)2SiCOCCOC]n
(n =
2–4), Chem. Lett., 33, 430–431
(2004). https://doi.org/10.1246/cl.2004.430
M.
Unno, Y. Imai, and H. Matsumoto,
Hexakis(2,4,6-triisopropylphenylsilsesquioxane), Silicon Chem., 2,
175–178 (2003). https://doi.org/10.1023/B:SILC.0000046726.90699.41
M.
Unno, T. Tanaka, and H.
Matsumoto, Tip-substituted Cage and Cyclic Silanols, J. Organomet. Chem., 686,
175–182 (2003). https://doi.org/10.1016/S0022-328X(03)00541-2
M.
Unno, T. Matsumoto, K.
Mochizuki, K. Higuchi, M. Goto, and H. Matsumoto,
Structure and Oxidation of Octakis(tert-butyldimethylsilyl)octasilacubane,
J. Organomet.
Chem., 685,
156–161 (2003). https://doi.org/10.1016/S0022-328X(03)00288-2
M.
Unno, H. Masuda,
and H. Matsumoto, Photo-initiated Bromination of
Octakis(1,1,2-trimethylpropyl)octasilacubane with
Tetrabromomethane, Silicon Chem.,
1, 377–381 (2002). https://doi.org/10.1023/B:SILC.0000025578.17683.2a
K.
Yamada, M. Unno, K.
Kobayashi, H. Oku, H. Yamamura, S. Araki, H. Matsumoto,
R. Katakai, and M.
Kawai, Stereochemistry of Protected Ornithine Side
Chains of Gramicidin S
Derivatives: X-ray Crystal Structure of the
Bis-Boc-tetra-N-methyl Derivatives of Gramicidin S, J. Am. Chem. Soc., 124,
12684–12688
(2002). https://doi.org/10.1021/ja020307t
R.
Tanaka, S. Kyushin, M. Unno, and H. Matsumoto, Chiral
crystallization of anti-dodecaisopropyltricyclo[4.2.0.02,5]octasilane,
Enantiomer, 7, 157–159 (2002). https://doi.org/10.1080/10242430212882
M.
Unno, A. Suto, and H.
Matsumoto, Pentacyclic Laddersiloxane, J.
Am. Chem. Soc., 124, 1574–1575
(2002). https://doi.org/10.1021/ja0173876
M.
Unno, Y. Kawai, and H.
Matsumoto, Synthesis and Crystal Structures of
2,4,6-Tri-tert-butylphenyltrichlorogermane and
2,4,6-Tri-tert-butylphenylgermane, Heteroatom
Chem., 12,
238–243 (2001). https://doi.org/10.1002/hc.1038
M.
Unno, T. Saito, and H.
Matsumoto, Synthesis and Crystal Structures of
Silapericyclynes, Bull.
Chem. Soc. Jpn., 74, 2407–2413
(2001). https://doi.org/10.1246/bcsj.74.2407
M.
Unno, K. Negishi, and H.
Matsumoto, Extended Silapericyclynes, Chem.
Lett., 30,
340–341 (2001). https://doi.org/10.1246/cl.2001.340
M.
Unno, K. Higuchi, K.
Furuya, H. Shioyama, S. Kyushin, M. Goto, and H.
Matsumoto, Synthesis, Structure, and Reactions of
Octakis(1,1,2-trimethylpropyl)octagermacubane, Bull. Chem.
Soc. Jpn., 73,
2093–2097 (2000). https://doi.org/10.1246/bcsj.73.2093
S. Kyushin, A. Meguro, M.
Unno, and H. Matsumoto, Photolysis of anti-Dodecaalkyltricyclo[4.2.0.02,5]octasilane:
Generation
and Reactions of Cyclotetrasilene, Chem. Lett., 29, 494–495 (2000). https://doi.org/10.1246/cl.2000.494
H. Horiuchi, Y. Nakano, T.
Matsumoto, M. Unno, H. Matsumoto, and H. Hiratsuka,
Electronic Structure and
Photochemical Reaction Intermediates of
Octakis(1,1,2-trimethylpropyl)octasilacubane, Chem. Phys. Lett., 322,
33–40 (2000). https://doi.org/10.1016/S0009-2614(00)00357-2
M. Unno, K. Takada, and H.
Matsumoto, Formation of Supramolecule by Assembling of
Two Different Silanols, Chem. Lett., 29, 242–243 (2000). https://doi.org/10.1246/cl.2000.242
M. Unno, A. Suto, K. Takada,
and H. Matsumoto,
Synthesis of Ladder
and Cage Silsesquioxanes from
1,2,3,4-Tetrahydroxycyclotetrasiloxane, Bull. Chem. Soc.
Jpn., 73, 215–220 (2000). https://doi.org/10.1246/bcsj.73.215
M. Unno, D. Ishii,
and H. Matsumoto,
Kinetic Study
of Thermal Isomerization of the gDouble-deckerh-type
Sesquichalcogenides, (Thex2M2E2)2E2
(M=Si, Ge; E=S, Se), Bull. Chem. Soc. Jpn, 72, 2469–2473 (1999). https://doi.org/10.1246/bcsj.72.2469
M.
Unno, T. Saito, and H. Matsumoto, Silapericyclyne, (Ph2SiCC)6:
Spontaneous Conformational Resolution of Boat- and
Chair-'Exploded' Cyclohexane,
Chem. Lett., 28, 1235–1236
(1999). https://doi.org/10.1246/cl.1999.1235
R.
Tanaka, M. Unno, and H. Matsumoto, Synthesis and
Molecular Structures of Novel
Isopropyl-substituted Oligosilanes, Chem.
Lett., 28,
595–596 (1999). https://doi.org/10.1246/cl.1999.595
M. Unno, R. Tanaka, S. Kyushin, and H.
Matsumoto, Synthesis
and Reactions of Hepta-t-butylcyclotetragermane,
Phosphorus,
Sulfur, Silicon Relat. Elem., 150/151, 167–176 (1999). https://doi.org/10.1080/10426509908546382
M. Unno, B. A. Shamsul, M. Arai, K. Takada,
R. Tanaka
and H. Matsumoto, Synthesis and Characterization of Cage
and Bicyclic
Silsesquioxanes via Dehydration of Silanols, Appl. Organomet. Chem., 13,
303-310 (1999). https://onlinelibrary.wiley.com/doi/10.1002/%28SICI%291099-0739%28199904%2913%3A4%3C303%3A%3AAID-AOC846%3E3.0.CO%3B2-%23
M. Unno, K. Takada, and H. Matsumoto,
Synthesis,
Structure, and Reaction of the
Tetrahydroxycyclotetrasiloxane [(i-Pr)(OH)SiO]4,
Chem. Lett., 27, 489–490 (1998). https://doi.org/10.1246/cl.1998.489
M.
Unno, H. Masuda, and H. Matsumoto,
1,2,3-Triphenyl-1,2,3-trithexylcyclotrisilanes:
Synthesis and Ring-Opening by
Halogens, Bull. Chem. Soc. Jpn, 70,
2449–2458 (1997). https://doi.org/10.1246/bcsj.71.2449
M. Unno, R. Tanaka, T. Kuribara, M. Saito,
and H.
Matsumoto, Synthesis, Structures, and Reactions of
1,2,3-Tris(diethylamino)-1,2,3,4-tetrakis-(1,1,2-trimethylpropyl)cyclotetrasilanes,
Bull. Chem. Soc.
Jpn, 70,
2749–2756 (1997). https://doi.org/10.1246/bcsj.70.2749
K. Kobayashi, T. Kato, M. Unno, and S.
Masuda,
Asymmetric Synthesis of Organosilicon Compounds Using a
C2 Chiral Auxiliary, Bull.
Chem. Soc. Jpn, 70, 1393–1401
(1997). https://doi.org/10.1246/bcsj.70.1393
M. Unno, Y. Kawai, H. Shioyama, and H.
Matsumoto,
Syntheses, Structures, and Properties of
Tricyclo[5.1.1.13,5]tetrasilachalcogenanes
(Thex2Si2E2)2E2
(E = S,
Se) and Tricyclo[5.1.1.13,5]tetragermachalcogenanes
(Thex2Ge2E2)2E2
(E = S, Se), Organometallics,
16, 4428–4434
(1997). https://doi.org/10.1021/om970432r
M. Unno, H. Shioyama, and H. Matsumoto,
Synthesis and
Structures of Tetrasilsesquisulfides, Phosphorus,
Sulfur, Silicon Relat. Elem., 120/121, 377–378
(1997). https://doi.org/10.1080/10426509708545556
M. Unno, T. Yokota, and H. Matsumoto,
Oxaoctasilahomocubane and Dioxaoctasilabishomocubane:
Novel Silicon Ring
System, J.
Organomet. Chem., 521, 409–411
(1996). https://doi.org/10.1016/0022-328X(96)06421-2
M. Unno, B. A. Shamsul, H. Saito, and H.
Matsumoto,
Synthesis of Hexasilsesquioxanes Bearing Bulky
Substituents:
Hexakis(1,1,2-trimethylpropylsilsesquioxane)
and Hexakis(tert-butylsilsesquioxane),
Organometallics,
15, 2413–2414 (1996). https://doi.org/10.1021/om950737a
M. Unno, H. Shioyama, M. Ida, and H.
Matsumoto, Reductive
dehalogenation of
4,8-Dihalooctakis(1,1,2-trimethylpropyl)tetracyclo-[3.3.0.02,7.03,6]octasilanes
with
Sodium, Organometallics,
14, 4004–4009
(1995). https://doi.org/10.1021/om00008a054
M. Unno, M. Saito, and H. Matsumoto,
Synthesis,
Structure, and Properties of Novel Aminodisilanes
Bearing Bulky Substituents:
1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane
and
1,2-di-(tert-butyl)1,1,2,2-tetrakis(diethylamino)disilane,
J. Organomet.
Chem., 499,
221–228 (1995). https://doi.org/10.1016/0022-328X(95)00314-G
M. Unno, K. Higuchi, M. Ida, H. Shioyama,
S. Kyushin,
M. Goto, and H. Matsumoto, Ring-Opening Reaction of
Octakis(1,1,2-trimethylpropyl)octasilacubane,
Organometallics,
13, 4633–4635 (1994). https://doi.org/10.1021/om00023a075
B. Imperiali, K. L. Shannon, M. Unno, and
K. W.
Rickert, A Mechanistic Proposal for Asparagine-Linked
Glycosylation, J.
Am. Chem. Soc., 114, 7944–7945 (1992). https://doi.org/10.1021/ja00046a069
L.
T. Scott and M. Unno, Novel Heterocycles Comprising
Alternating Phosphorus
Atoms and Alkyne Units, J. Am. Chem. Soc., 112,
7823–7825 (1990). https://doi.org/10.1021/ja00177a069
R.
Okazaki, M. Unno, and N. Inamoto, Estimation of
Bulkiness of a Highly
Sterically Demanding
2,4,6-Tris[bis(trimethylsilyl)methyl]-phenyl Group, Chem. Lett., 18, 791–792 (1989). https://doi.org/10.1246/cl.1989.791
R.
Okazaki, M. Unno, G. Yamamoto, and N. Inamoto, A
Conformational Study on Highly
Crowded 1,3,5-Tris[bis(trimethylsilyl)methyl]benzene
Derivatives. Chem.
Lett. 18, 493–496 (1989). https://doi.org/10.1246/cl.1989.493
R.
Okazaki, M. Unno, and N. Inamoto,
2,4,6-Tris[bis(Trimethylsilyl)methyl]phenyl,
a New Sterically Demanding Group for Kinetic
Stabilization of Unstable
Compounds, Chem.
Lett., 16,
2293–2294 (1987). https://doi.org/10.1246/cl.1987.2293
R.
Okazaki, M. Unno, and N. Inamoto, A New synthesis
of 1,3-thiazine
derivatives
bearing a dithiolane
ring and their reductive
cleavage
with sodium
cyanoborohydride, Heterocycles,
25, 183–190
(1987). https://doi.org/10.3987/S-1987-01-0183
[Review, Proceedings] *English
only
M. Unno, A. Suto, and T. Matsumoto, "Laddersiloxanes\ Silsesquioxanes with defined ladder structure", Russ. Chem. Rev., 82, 289–302 (2013). https://doi.org/10.1070/RC2013v082n04ABEH004360
M. Unno, Laddersiloxanes: silsesquioxanes with defined ladder structure. Materials Research Society Symposium Proceedings 1007-S01-05 (2007). https://doi.org/10.1557/PROC-1007-S01-05
M. Unno, K. Takada, Y. Kawaguchi, and H. Matsumoto, Supramolecular aggregates of silanols and solid-state synthesis of siloxanes, Mol. Cryst. Liq. Cryst., 440, 259–264 (2005). https://doi.org/10.1080/15421400590958584
H. Matsumoto, S. Kyushin, M. Unno, and R. Tanaka, Synthesis, Structures, and Properties of Ladder Oligosilanes and Ladder Oligogermanes, J. Organomet. Chem. 611, 52–63 (2000). https://doi.org/10.1016/S0022-328X(00)00299-0
mBooksn*English only
M. Unno and H. Endo, gSilanols as Building Blocks for Nanomaterialsh in Novel Nanoscale Hybrid Materials, Ed. Bhanu P. S. Chauhan, John Wiley & Sons, Inc., New York, pp. 1–31 (2018). https://doi.org/10.1002/9781119156253.ch1
M. Unno and R. Tanaka, gSilanols and Silsesquioxanesh in Efficient Methods for Preparing Silicon Compounds, Ed. H. W. Roesky, Academic Press, London, pp. 399–440 (2016). https://doi.org/10.1016/B978-0-12-803530-6.00032-9
M. Unno, "Substituted Polyhedral Silicon and Germanium Clusters", in Functional Molecular Silicon Compounds II, Ed. D. Scheschkewitz, Springer, Heidelberg, pp.49-84 (2014). https://doi.org/10.1007/430_2013_99
M. Unno and H. Matsumoto, "Reactions of
Octasilacubane", in Organosilicon Chemistry VICEds. N.
Auner and J. Weis, WILEY-VCH Verlag, Weinheim, pp.
373–380 (2005). https://doi.org/10.1002/9783527618224.ch2c