TOP PICTURE





*Full list is shown in this page.

[Original articles]

M. Laird, P. Gaveau, P. Trens, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Post-synthesis modification of functionalised polyhedral oligomeric silsesquioxanes with encapsulated fluoride – enhancing reactivity of T8-F POSS for materials synthesis, New J. Chem., in press (2021). https://doi.org/10.1039/d0nj06008a

M. Laird, N. Herrmann, N. Ramsahye, C. Totée, C. Carcel, M. Unno, J. Bartlett, M. Wong Chi Man, Large polyhedral oligomeric silsesquioxane cages – the isolation of functionalized POSS with an unprecedented Si18O27 core, Angew. Chem. Int. Ed., 60, 3022–3027  (2020). https://doi.org/10.1002/anie.202010458

M. Laird, J. Yokoyama, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Sol–gel processing of polyhedral oligomeric silsesquioxanes: nanohybrid materials incorporating T8 and T10 cages, J. Sol-Gel Sci. Tech., 95, 760–770 (2020). https://doi.org/10.1007/s10971-020-05314-y

T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Synthesis of tricyclic laddersiloxane with various ring sizes (Bat siloxane), Macromol. Rapid Commun., 2000608 (2020). https://doi.org/10.1002/marc.202000608

T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Janus ring siloxane: a versatile precursor of the extended Janus ring and tricyclic laddersiloxanes, Dalton Trans., 49, 13533–13537 (2020). https://doi.org/10.1039/D0DT03045G

Y. Liu, M. Kigure, K. Koizumi, N. Takeda, M. Unno, A. Ouali, Synthesis of Tetrachloro, Tetraiodo, and Tetraazido Double-Decker Siloxanes, Inorg. Chem., 59, 15478–15486 (2020). https://doi.org/10.1021/acs.inorgchem.0c02515

M. Laird, A. van der Lee, D. Dumitrescu, C. Carcel, A. Ouali, J. Bartlett, M. Unno, M. Wong Chi Man, Styryl Functionalized Cage Silsesquioxanes as Nano Blocks for 3-D Assembly, Organometallics, 39, 1896–1906 (2020). https://dx.doi.org/10.1021/acs.organomet.0c00119

Y. Du, M. Unno, H. Liu, Hybrid Nanoporous Materials Derived from Ladder- and Cage-Type Silsesquioxanes for Water Treatment, ACS Appl. Nano Mater., 3, 1535–1541 (2020). https://doi.org/10.1021/acsanm.9b02325

Y. Liu, K. Onodera, N. Takeda, A. Ouali, and M. Unno, Synthesis and Characterization of Functionalizable Silsesquioxanes with Ladder-type Structures, Organometallics, 38, 4173–4176 (2019).  https://doi.org/10.1021/acs.organomet.9b00597

R. Kunthom, T. Adachi, Y. Liu, N. Takeda, M. Unno, and R. Tanaka, Synthesis of a "Butterfly Cage" Based on a Double-Decker Silsesquioxane, Chem. Asian J., 14, 4179–4182 (2019). https://doi.org/10.1002/asia.201901361

R. Kunthom, N. Takeda, M. Unno, Synthesis and Characterization of Unsymmetrical Double-decker Siloxane (Basket Cage), Molecules, 24, 4252 (2019). https://doi.org/10.3390/molecules24234252

Y. Liu, N. Takeda, A. Ouali, M. Unno, Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes, Inorg. Chem., 58, 4093–4098 (2019). https://doi.org/10.1021/acs.inorgchem.9b00416

T. Tanaka, Y. Hasegawa, T. Kawamori, R. Kunthom, N. Takeda, M. Unno, Synthesis of Double-Decker Silsesquioxanes from Substituted Difluorosilane, Organometallics, 38, 743-747 (2019). https://doi.org/10.1021/acs.organomet.8b00896

S. Kondo, Y. Nakadai, M. Unno, Recognition of dicarboxylates in aqueous acetonitrile by a dinuclear zinc(II) complex of 2,2'-binaphthalene-based receptor, Supramolecular Chem., 31, 9–18 (2019). https://doi.org/10.1080/10610278.2018.1522445

T. Uchida, Y. Egawa, T. Adachi, N. Oguri, M. Kobayashi, T. Kudo, N. Takeda, M. Unno, R. Tanaka, Synthesis, Structures, and Thermal Properties of Symmetric and Janus gLantern Cageh Siloxanes, Chem. Eur. J., 25, 1683 –1686 (2019). https://doi.org/10.1002/chem.201805200

H. Endo, N. Takeda, and M. Unno, Single-step synthesis of disiloxanetetraols, J. Sol-Gel Sci. Technol., 89, 37–44 (2019). https://doi.org/10.1007/s10971-018-4635-9

Y. Egawa, C. Fukumoto, K. Mikami, N. Takeda, M. Unno, Synthesis and Characterizations of
The Germathioacid chloride Coordinated by an N-Heterocyclic carbene, Inorganics, 6, 76 (2018). https://doi.org/10.3390/inorganics6030076

H. Endo, N. Takeda, and M. Unno, Stereoisomerization of Cyclic Silanols, Chem. Asian J., 12, 1224–1233 (2017). https://doi.org/10.1002/asia.201700125

N. Oguri, Y. Egawa, Y. Kawakami, C. Kobuna, N. Takeda, and M. Unno, Unusual Reactions of Cyclic Fluorosiloxanes, ChemistrySelect, 2, 2300–2304 (2017). https://doi.org/10.1002/slct.201700306

Y. Egawa, S. Murakami, N. Takeda, and M. Unno, Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New Building Block for Materials, Chem. Lett., 45, 738–739 (2016). https://doi.org/10.1246/cl.160272

N. Oguri, Y. Egawa, N. Takeda, and M. Unno, Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure Elucidation, Angew. Chem. Int. Ed. 55, 9336-9339 (2016). https://doi.org/10.1002/anie.201602413

N. Takeda, Y. Tanaka, R. Oma, F. Sakakibara, M. Unno, Activation of C–S Bond by Group 10 Metal Complexes: Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl Groups with Group 10 Metal Compounds, Bull. Chem. Soc. Jpn.,  89, 922-930 (2016). https://doi.org/10.1246/bcsj.20160089

S. Murakami, Y. Egawa, C. Kuramochi, N. Takeda, and M. Unno, Cyclic Silanols with Long Alkyl Chains, Chem. Lett., 45, 309–311 (2016). https://doi.org/10.1246/cl.151143



[Review, Proceedings] *English only

M. Unno, A. Suto, and T. Matsumoto, "Laddersiloxanes\ Silsesquioxanes with defined ladder structure", Russ. Chem. Rev., 82, 289–302 (2013). https://doi.org/10.1070/RC2013v082n04ABEH004360

M. Unno, Laddersiloxanes: silsesquioxanes with defined ladder structure. Materials Research Society Symposium Proceedings 1007-S01-05 (2007). https://doi.org/10.1557/PROC-1007-S01-05

M. Unno, K. Takada, Y. Kawaguchi, and H. Matsumoto, Supramolecular aggregates of silanols and solid-state synthesis of siloxanes, Mol. Cryst. Liq. Cryst., 440, 259–264 (2005). https://doi.org/10.1080/15421400590958584

H. Matsumoto, S. Kyushin, M. Unno, and R. Tanaka, Synthesis, Structures, and Properties of Ladder Oligosilanes and Ladder Oligogermanes, J. Organomet. Chem. 611, 52–63 (2000). https://doi.org/10.1016/S0022-328X(00)00299-0

 

mBooksn*English only

M. Unno and H. Endo, gSilanols as Building Blocks for Nanomaterialsh in Novel Nanoscale Hybrid Materials, Ed. Bhanu P. S. Chauhan, John Wiley & Sons, Inc., New York, pp. 1–31 (2018). https://doi.org/10.1002/9781119156253.ch1

M. Unno and R. Tanaka, gSilanols and Silsesquioxanesh in Efficient Methods for Preparing Silicon Compounds, Ed. H. W. Roesky, Academic Press, London, pp. 399–440 (2016). https://doi.org/10.1016/B978-0-12-803530-6.00032-9

M. Unno, "Substituted Polyhedral Silicon and Germanium Clusters", in Functional Molecular Silicon Compounds II, Ed. D. Scheschkewitz, Springer, Heidelberg, pp.49-84 (2014). https://doi.org/10.1007/430_2013_99

M. Unno and H. Matsumoto, "Reactions of Octasilacubane", in Organosilicon Chemistry VICEds. N. Auner and J. Weis, WILEY-VCH Verlag, Weinheim, pp. 373–380 (2005). https://doi.org/10.1002/9783527618224.ch2c








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