*Full list is shown in this page.

[Original articles]

M. Laird, P. Gaveau, P. Trens, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Post-synthesis modification of functionalised polyhedral oligomeric silsesquioxanes with encapsulated fluoride – enhancing reactivity of T8-F POSS for materials synthesis, New J. Chem., in press (2021).

M. Laird, N. Herrmann, N. Ramsahye, C. Totée, C. Carcel, M. Unno, J. Bartlett, M. Wong Chi Man, Large polyhedral oligomeric silsesquioxane cages – the isolation of functionalized POSS with an unprecedented Si18O27 core, Angew. Chem. Int. Ed., 60, 3022–3027  (2020).

M. Laird, J. Yokoyama, C. Carcel, M. Unno, J. R. Bartlett, M. Wong Chi Man, Sol–gel processing of polyhedral oligomeric silsesquioxanes: nanohybrid materials incorporating T8 and T10 cages, J. Sol-Gel Sci. Tech., 95, 760–770 (2020).

T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Synthesis of tricyclic laddersiloxane with various ring sizes (Bat siloxane), Macromol. Rapid Commun., 2000608 (2020).

T. Chaiprasert, Y. Liu, N. Takeda, M. Unno, Janus ring siloxane: a versatile precursor of the extended Janus ring and tricyclic laddersiloxanes, Dalton Trans., 49, 13533–13537 (2020).

Y. Liu, M. Kigure, K. Koizumi, N. Takeda, M. Unno, A. Ouali, Synthesis of Tetrachloro, Tetraiodo, and Tetraazido Double-Decker Siloxanes, Inorg. Chem., 59, 15478–15486 (2020).

M. Laird, A. van der Lee, D. Dumitrescu, C. Carcel, A. Ouali, J. Bartlett, M. Unno, M. Wong Chi Man, Styryl Functionalized Cage Silsesquioxanes as Nano Blocks for 3-D Assembly, Organometallics, 39, 1896–1906 (2020).

Y. Du, M. Unno, H. Liu, Hybrid Nanoporous Materials Derived from Ladder- and Cage-Type Silsesquioxanes for Water Treatment, ACS Appl. Nano Mater., 3, 1535–1541 (2020).

Y. Liu, K. Onodera, N. Takeda, A. Ouali, and M. Unno, Synthesis and Characterization of Functionalizable Silsesquioxanes with Ladder-type Structures, Organometallics, 38, 4173–4176 (2019).

R. Kunthom, T. Adachi, Y. Liu, N. Takeda, M. Unno, and R. Tanaka, Synthesis of a "Butterfly Cage" Based on a Double-Decker Silsesquioxane, Chem. Asian J., 14, 4179–4182 (2019).

R. Kunthom, N. Takeda, M. Unno, Synthesis and Characterization of Unsymmetrical Double-decker Siloxane (Basket Cage), Molecules, 24, 4252 (2019).

Y. Liu, N. Takeda, A. Ouali, M. Unno, Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes, Inorg. Chem., 58, 4093–4098 (2019).

T. Tanaka, Y. Hasegawa, T. Kawamori, R. Kunthom, N. Takeda, M. Unno, Synthesis of Double-Decker Silsesquioxanes from Substituted Difluorosilane, Organometallics, 38, 743-747 (2019).

S. Kondo, Y. Nakadai, M. Unno, Recognition of dicarboxylates in aqueous acetonitrile by a dinuclear zinc(II) complex of 2,2'-binaphthalene-based receptor, Supramolecular Chem., 31, 9–18 (2019).

T. Uchida, Y. Egawa, T. Adachi, N. Oguri, M. Kobayashi, T. Kudo, N. Takeda, M. Unno, R. Tanaka, Synthesis, Structures, and Thermal Properties of Symmetric and Janus gLantern Cageh Siloxanes, Chem. Eur. J., 25, 1683 –1686 (2019).

H. Endo, N. Takeda, and M. Unno, Single-step synthesis of disiloxanetetraols, J. Sol-Gel Sci. Technol., 89, 37–44 (2019).

Y. Egawa, C. Fukumoto, K. Mikami, N. Takeda, M. Unno, Synthesis and Characterizations of
The Germathioacid chloride Coordinated by an N-Heterocyclic carbene, Inorganics, 6, 76 (2018).

H. Endo, N. Takeda, and M. Unno, Stereoisomerization of Cyclic Silanols, Chem. Asian J., 12, 1224–1233 (2017).

N. Oguri, Y. Egawa, Y. Kawakami, C. Kobuna, N. Takeda, and M. Unno, Unusual Reactions of Cyclic Fluorosiloxanes, ChemistrySelect, 2, 2300–2304 (2017).

Y. Egawa, S. Murakami, N. Takeda, and M. Unno, Synthesis of Hydrosilyl-substituted Cyclic Siloxane: New Building Block for Materials, Chem. Lett., 45, 738–739 (2016).

N. Oguri, Y. Egawa, N. Takeda, and M. Unno, Janus-Cube Octasilsesquioxane: Facile Synthesis and Structure Elucidation, Angew. Chem. Int. Ed. 55, 9336-9339 (2016).

N. Takeda, Y. Tanaka, R. Oma, F. Sakakibara, M. Unno, Activation of C–S Bond by Group 10 Metal Complexes: Reaction of Phosphine Ligand Tethered with Three tert-Butylthiophenyl Groups with Group 10 Metal Compounds, Bull. Chem. Soc. Jpn.,  89, 922-930 (2016).

S. Murakami, Y. Egawa, C. Kuramochi, N. Takeda, and M. Unno, Cyclic Silanols with Long Alkyl Chains, Chem. Lett., 45, 309–311 (2016).

[Review, Proceedings] *English only

M. Unno, A. Suto, and T. Matsumoto, "Laddersiloxanes\ Silsesquioxanes with defined ladder structure", Russ. Chem. Rev., 82, 289–302 (2013).

M. Unno, Laddersiloxanes: silsesquioxanes with defined ladder structure. Materials Research Society Symposium Proceedings 1007-S01-05 (2007).

M. Unno, K. Takada, Y. Kawaguchi, and H. Matsumoto, Supramolecular aggregates of silanols and solid-state synthesis of siloxanes, Mol. Cryst. Liq. Cryst., 440, 259–264 (2005).

H. Matsumoto, S. Kyushin, M. Unno, and R. Tanaka, Synthesis, Structures, and Properties of Ladder Oligosilanes and Ladder Oligogermanes, J. Organomet. Chem. 611, 52–63 (2000).


mBooksn*English only

M. Unno and H. Endo, gSilanols as Building Blocks for Nanomaterialsh in Novel Nanoscale Hybrid Materials, Ed. Bhanu P. S. Chauhan, John Wiley & Sons, Inc., New York, pp. 1–31 (2018).

M. Unno and R. Tanaka, gSilanols and Silsesquioxanesh in Efficient Methods for Preparing Silicon Compounds, Ed. H. W. Roesky, Academic Press, London, pp. 399–440 (2016).

M. Unno, "Substituted Polyhedral Silicon and Germanium Clusters", in Functional Molecular Silicon Compounds II, Ed. D. Scheschkewitz, Springer, Heidelberg, pp.49-84 (2014).

M. Unno and H. Matsumoto, "Reactions of Octasilacubane", in Organosilicon Chemistry VICEds. N. Auner and J. Weis, WILEY-VCH Verlag, Weinheim, pp. 373–380 (2005).

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